Removing the ambiguity of data processing methods: Optimizing the location of peak boundaries for accurate moment calculations

The calculation of the first few moments of elution peaks is necessary to determine: the amount of component in the sample (peak area or zeroth moment), the retention factor (first moment), and the column efficiency (second moment). It is a time consuming and tedious task for the analyst to perform these calculations, thus data analysis is generally completed by data stations associated to modern chromatographs. However, data acquisition software is a black box which provides no information to chromatographers on how their data are treated. These results are too important to be accepted on blind faith. The location of the peak integration boundaries is most important. In this manuscript, we explore the relationships between the size of the integration area, the relative position of the peak maximum within this area, and the accuracy of the calculated moments. We found that relationships between these parameters do exist and that computers can be programmed with relatively simple routines to automatize the extraction of key peak parameters and to select acceptable integration boundaries. It was also found that the most accurate results are obtained when the S/N exceeds 200.

Knowledge on road information in sub-urban lane detection via multiple cue integration

Detection of lane boundaries of a road based on the images or video taken by a video capturing device in a suburban environment is a challenging task. In this paper, a novel lane detection algorithm is proposed without considering camera parameters; which robustly detects lane boundaries in real-time especially for sub-urban roads. Initially, the proposed method fits the CIE L*a*b* transformed road chromaticity values (that is a* and b* values) to a bi-variate Gaussian model followed by the classification of road area based on Mahalanobis distance. Secondly, the classified road area acts as an arbitrary shaped region of interest (AROI) in order to extract blobs resulting from the filtered image by a two dimensional Gabor filter. This is considered as the first cue of images. Thirdly, another cue of images was employed in order to obtain an entropy image. Moreover, results from the color based image cue and entropy image cue were integrated following an outlier removing process. Finally, the correct road lane points are fitted with Bezier splines which act as control points that can form arbitrary shapes. The algorithm was implemented and experiments were carried out on sub-urban roads. The results show the effectiveness of the algorithm in producing more accurate lane boundaries on curvatures and other objects on the road.

Real-time lane detection on suburban streets using visual cue integration

The detection of lane boundaries on suburban streets using images obtained from video constitutes a challenging task. This is mainly due to the difficulties associated with estimating the complex geometric structure of lane boundaries, the quality of lane markings as a result of wear, occlusions by traffic, and shadows caused by road-side trees and structures. Most of the existing techniques for lane boundary detection employ a single visual cue and will only work under certain conditions and where there are clear lane markings. Also, better results are achieved when there are no other onroad objects present. This paper extends our previous work and discusses a novel lane boundary detection algorithm specifically addressing the abovementioned issues through the integration of two visual cues. The first visual cue is based on stripe-like features found on lane lines extracted using a two-dimensional symmetric Gabor filter. The second visual cue is based on a texture characteristic determined using the entropy measure of the predefined neighbourhood around a lane boundary line. The visual cues are then integrated using a rulebased classifier which incorporates a modified sequential covering algorithm to improve robustness. To separate lane boundary lines from other similar features, a road mask is generated using road chromaticity values estimated from CIE L*a*b* colour transformation. Extraneous points around lane boundary lines are then removed by an outlier removal procedure based on studentized residuals. The lane boundary lines are then modelled with Bezier spline curves. To validate the algorithm, extensive experimental evaluation was carried out on suburban streets and the results are presented.