Emulsions and microcapsules with substances having low interfacial tension, methods of making and using thereof

Disclosed are emulsions and microcapsules that comprise one or more substances with a low interfacial tension. Methods of making the emulsions and microcapsules as well as methods of using them are also disclosed. In some embodiments microbial oil is used. In some embodiments marine oil is used. In some embodiments the emulsion has a pH of greater than 6,0. In some embodiments the emulsion has a pH of less than 5,0.

Electrowetting measurements with mercury showing mercury/mica interfacial energy depends on charging

We demonstrate that the interfacial energy between mercury and mica is a function of charge on the mercury surface, decreasing with increasing positive charge. The contact angle of mercury on mica has been measured as a function of potential applied to the mercury, which forms the working electrode of a cell containing either KC1 or NaF electrolyte solution. At high negative applied potentials, a stable aqueous film exists between the mercury and mica surface. As potential is made less negative, the film collapses and mercury partial1 wets the mica at a critical potential, close to the electrocapillary maximum. Upon increasing the potential further (making the Hg surface more and more positive), the contact angle measured within the mercury continually decreases. Electrowetting with mercury is not unexpected since its interfacial tension with the aqueous phase is known to be a function of applied potential. However, the observed decrease goes against the trend expected from the Young equation if only this effect is considered. To explain the data we must allow the mercury/mica interfacial tension also to vary with applied potential. This variation indicates that the mercury surface is positively charged by contact with mica, consistent with known contact electrification between these two materials. The inherent charges at the mercury interfaces with mica and electrolyte solution result in contact angle changes of some tens of degrees with a change in applied potential of half a volt orders of magnitude less than the potentials required to effect comparable changes in other electrowetting systems.

Self-assembly behavior of colistin and its prodrug colistin methanesulfonate : implications for solution stability and solubilization

Colistin is an amphiphilic antibiotic that has re-emerged into clinical use due to the increasing prevalence of difficult-to-treat Gram-negative infections. The existence of self-assembling colloids in solutions of colistin and its derivative prodrug, colistin methanesulfonate (CMS), was investigated. Colistin and CMS reduced the air−water interfacial tension, and dynamic light scattering (DLS) studies showed the existence of 2.07 ± 0.3 nm aggregates above 1.5 mM for colistin and of 1.98 ± 0.36 nm aggregates for CMS above 3.5 mM (mean ± SD). Above the respective critical micelle concentrations (CMC) the solubility of azithromycin, a hydrophobic antibiotic, increased approximately linearly with increasing surfactant concentration (5:1 mol ratio colistin:azithromycin), suggestive of hydrophobic domains within the micellar cores. Rapid conversion of CMS to colistin occurred below the CMC (60% over 48 h), while conversion above the CMC was less than 1%. The formation of colistin and CMS micelles demonstrated in this study is the proposed mechanism for solubilization of azithromycin and the concentration-dependent stability of CMS.

Colloidal interaction between a rigid solid and a fluid drop

We present results of a theoretical study of the effect of surface deformation on a macroscopic system composed of a solid surface interacting with a fluid drop through electrostatic double-layer forces. The analysis involves numerically solving a Laplace equation suitably modified to describe the shape of a liquid drop subjected to a repulsive double-layer force. The latter is evaluated in nonlinear mean-field theory. Some analytical results are also given. The results indicate that although deformation need not be significant on the macroscopic scale, its effect on the interaction is significant and modifies the picture usually presented in DLVO theory. The decay length of the exponential repulsion deviates marginally from the Debye length, dependent on the interfacial tension of the drop. More significantly, at separations where the double-layer force becomes comparable to the internal pressure of the drop, the net force between the two bodies, the local radius of curvature of the drop, and the amount of deformation grow abruptly. The results of this work are relevant to emulsion stability, micelle, vesicle, and cell interactions, and recent experiments on bubble-particle interaction.

Stability of aqueous films between bubbles. Part 2. Effects of trace impurities and evaporation

The stability of water films has been investigated with a Mysels-Scheludko type film balance. Minor trace impurities in water do not affect the lifetime of water films under vapor saturation, but significantly influence the stability in free evaporation. Trace amounts of positively adsorbed contaminants induce Marangoni-driven flow that destabilizes films under evaporation conditions whereas negatively adsorbed electrolytes actually prolong stability by reversing interfacial tension gradients and driving a steady circulation within the film. At high thinning rates, pure-water films develop exotic-appearing flow patterns and break due to a strong coupling between hydrodynamic and interfacial tensiongradient adsorption stresses. The most dominant factor of transient film stabilization in dynamic conditions under evaporation is a surface tension gradient created in the film. We discuss surface tension gradients in transient films created by temperature differences, impurity concentration, and expansion of the films.

Water-soluble complexes of hydrophobically modified polymer and surface active imidazolium-based ionic liquids for enhancing oil recovery

The current study introduces the water-soluble complexes containing hydrophobically associating copolymer and a series of surface activity imidazolium-based ionic liquids (CnmimBr, n=6, 8, 10, 12, 14 and 16). The polymer, denoted as PAAD, was prepared with acrylamide (AM), acrylic acid (AA) and N,N-diallyl-2-dodecylbenzenesulfonamide (DBDAP). And the hydrophobic associative behavior of PAAD was studied by a combination of the pyrene fluorescence probe and viscosimetry. Incorporation of CnmimBr (n=10, 12, 14 and 16) in PAAD leaded to the white thick gel, while the pellucid solutions were obtained in complexes of PAAD and CnmimBr (n=6 and 8); addition of C6mimBr around critical micelle concentration resulted in a large decrease in viscosity of solution. Therefore, we particularly investigated the performance of PAAD/C8mimBr complex. The interfacial tension of PAAD/C8mimBr complex solution and crude oil under different conditions was examined. Moreover, PAAD/C8mimBr complex exhibited superior temperature resistance and shear reversible performance for enhancing oil recovery (EOR) by rheological test. The promising EOR of 21.65% can be obtained by PAAD/C8mimBr complex showing high potential to utilize this kind of new complex in EOR processes.

Simulation of oleuropein structural conformation in vacuum, water and triolein-water systems using molecular dynamics

Oleuropein, the main phenolic compound of olive leaves, exhibits a unique blend of biological activities and has been shown to locate itself at the oil-water (O/W) interface. This behavior could influence the physico-chemical properties of dispersed systems such as emulsions. In this work, we study the effect of the microenvironment (vacuum, water, and triolein-water) on the conformational preferences of oleuropein using molecular dynamics (MD) simulations at 300K for at least 30ns. The seven torsions that describe the flexible skeleton of oleuropein were monitored together with the distance between the glucose (Glu) and hydroxytyrosol (Hyd) moieties (dglu-hyd) of the molecule. The obtained trajectories demonstrated that oleuropein adopts different conformations that depend on the environment. The preferential conformers in each system were analyzed for their molecular geometry and internal energy. In vacuum, the oleuropein preferential conformation is tight with the glucose moiety in close proximity with the hydroxytyrosol moiety. In water, oleuropein preferential conformers presented large differences in their structural properties, varying from a close like U form, and a semi-opened form, to an opened form characterized by high fluctuations in dglu-hyd values. In a triolein-water system, oleuropein tends to adopt a more open form where the glucose moiety could be approximately aligned with the hydroxytyrosol and elenolic acid moieties. Based on a calculation at the HF/6-31G* level, these flexibilities of oleuropein required energy of 19.14kcal/mol in order to adopt the conformation between water and triolein-water system. A radial distribution function (RDF) analysis showed that specific hydroxyl groups of Hyd and Glu interact with water molecules, enabling us to understand the amphiphilic character of oleuropein at the triolein-water interface. MD calculations together with interfacial tension measurements revealed that the oleuropein binding at O/W interface is an enthalpy driven mechanism.

An experimental investigation of yarn tension in simulated ring spinning

Yarn tension is a key factor that affects the efficiency of a ring spinning system. In this paper, a specially constructed rig, which can rotate a yarn at a high speed without inserting any real twist into the yarn, was used to simulate a ring spinning process. Yarn tension was measured at the guide-eye during the simulated spinning of different yarns at various balloon heights and with varying yarn length in the balloon. The effect of balloon shape, yarn hairiness and thickness, and yarn rotating speed, on the measured yarn tension, was examined. The results indicate that the collapse of balloon shape from single loop to double loop, or from double loop to triple etc, lead to sudden reduction in yarn tension. Under otherwise identical conditions, a longer length of yarn in the balloon gives a lower yarn tension at the guide-eye. In addition, thicker yarns and/or more hairy yarns generate a higher tension in the yarn, due to the increased air drag acting on the thicker or more hairy yarns.

Application of bending under tension test to determine the effect of tool radius and the contact pressure on the coefficient of friction in sheet metal forming

To quantify the frictional behaviour in sheet forming operations, several laboratory experiments which simulate the real forming conditions are performed. The Bending Under Tension Test is one such experiment which is often used to represent the frictional flow of sheet material around a die or a punch radius. Different mathematical representations are used to determine the coefficient of friction in the Bending Under Tension Test. In general the change in the strip thickness in passing over the die radius is neglected and the radius of curvature to thickness ratio is assumed to be constant in these equations. However, the effect of roller radius, sheet thickness and the surface pressure are also omitted in some of these equations. This work quantitatively determined the effect of roller radius and the tooling pressure on the coefficient of friction. The Bending Under Tension Test was performed using rollers with different radii and also lubricants with different properties. The tool radii were found to have a direct influence in the contact pressure. The effect of roller radius on friction was considerable and it was observed that there is a clear relationship between the contact pressure and the coefficient of friction.

Recent studies on yarn tension and energy consumption in ring spinning

High energy consumption remains a key challenge for the widely used ring spinning system. Tackling this challenge requires a full understanding of the various factors that contribute to yarn tension and energy consumption during ring spinning. In this paper, we report our recent experimental and theoretical research on air drag, yarn tension and energy consumption in ring spinning. A specially constructed rig was used to simulate the ring spinning process; and yarn tension at the guide-eye was measured for different yarns under different conditions. The effect of yarn hairiness on the air drag acting on a rotating yarn package and on a ballooning yarn was examined. Models of the power requirements for overcoming the air drag, increasing the kinetic energy of the yarn package (bobbin and wound yarn) and overcoming the yarn wind-on tension were developed. The ratio of energy-consumption to yarn-production over a full yarn package was discussed. A program to simulate yarn winding in ring spinning was implemented, which can generate the balloon shape and predict yarn tension under a given spinning condition. The simulation results were verified with experimental results obtained from spinning cotton and wool yarns.

Twinning and the ductility of magnesium alloys Part I: “Tension” twins

Magnesium and its alloys do not in general undergo the same extended range of plasticity as their competitor structural metals. The present work is part I of a study that examines some of the roles deformation twinning might play in the phenomenon. A series of tensile test results are reported for the common wrought alloy AZ31. These data are employed in conjunction with a simple constitutive model to argue that View the MathML source twinning (which gives extension along the c-axis) can increase the uniform elongation in tensile tests. This effect appears to be similar to that seen in Ti, Zr and Cu–Si and in the so called TWIP phenomenon in steel.

Effect of susceptibility to interfacial fracture on fatigue properties of spot-welded high strength sheet steel

While advanced high strength steels (AHSS) have numerous advantages for the automotive industry, they can be susceptible to interfacial fracture when spot-welded. In this study, the susceptibility of interfacial fracture to spot-weld microstructure and hardness is examined, as well as the corresponding relationships between fatigue, overload performance, and interfacial fracture for a TRIP (transformation induced plasticity) steel. Simple post-weld heat-treatments were used to alter the weld microstructure. The effect on interfacial fracture of diluting the weld pool by welding the TRIP material to non-TRIP steel was examined, along with the effect of altering the base material microstructure. Results show that weld hardness is not a good indicator of either the susceptibility to interfacial fracture, or the strength of the joint, and that interfacial fracture does not necessarily lead to a decrease in strength compared to conventional weld-failure mechanisms, i.e. button pullout. It was also found that while interfacial fracture does affect low cycle to failure behavior, there was no effect on high cycle fatigue.