Gas flow unified measurement system for sequential measurement of gas diffusion and gas permeability of partially hydrated geosynthetic clay liners

A gas flow unified measurement system (UMS-G) for sequential measurement of gas diffusion and gas permeability of geosynthetic clay liners (GCLs) under applied stress conditions (2 to 20 kPa) is described. Measurements made with the UMS-G are compared with measurements made with conventional experimental devices and are found to give similar results. The UMS-G removes the need to rely on two separate systems and increases further the reliability of the gas properties’ measurements. This study also shows that the gas diffusion and gas permeability reduce greatly with the increase of both gravimetric water content and apparent degree of saturation. The effect of applied stress on gas diffusion and gas permeability is found to be more pronounced at gravimetric water content greater than 60%. These findings suggest that at a nominal overburden stress of 20 kPa, the GCL used in the present investigation needs to be hydrated to 134% gravimetric water content (65% apparent degree of saturation) before gas diffusion and gas permeability drop to 5.5 × 10−11 m2·s−1 and 8.0 × 10−13 m·s−1, respectively, and to an even higher gravimetric water content (apparent degrees of saturation) at lower stress.

Geosynthetics in Antarctica: performance of a composite barrier system to contain hydrocarbon-contaminated soil after three years in the field

An overview of the design and performance of geosynthetics in composite barrier systems for biopiles used to remediate hydrocarbon-contaminated soil at Casey Station, Antarctica, is presented. Seven instrumented biopiles were constructed over three field seasons. To minimize the risk of hydrocarbon migration to groundwater, composite barrier systems were used (each using different combinations of geosynthetic clay liners (GCLs), high density polyethylene (HDPE) geomembranes (GMB), and geotextiles (GTXs)). One biopile used a co-extruded geomembrane (HDPE with an ethylene vinyl alcohol (EVOH) core). The liner system was subject to a combination of coupled phenomena that could interact and affect the GMB-GCL composite barrier performance. The exposure conditions involved potential freeze-thaw cycling, hydration-desiccation cycles, cation exchange, direct and diffusive exposure to hydrocarbons. The effect of these phenomena was investigated by monitoring GCL and GMB sacrificial coupons. GCL coupons were placed between the main GCL component and the main geomembrane component of the composite liner and GMB coupons placed between the main GMB sheet and the GTX protection layer. Coupons were exhumed from the biopiles each year. The exhumed GCL field moisture content values ranged from 162% to 22%. After three (3) years in the field, GCL coupons that had undergone at least one hydration/desiccation cycle showed no significant change in swell index values or fluid loss values. The measured hydraulic conductivity of exhumed GCL coupons from Biopiles 1 and 2 (3 × 10-11 m s-1) was within the expected range and not significantly different from the values for virgin GCL. GMB coupons exhumed after three years from Biopiles 1 and 2 showed no significant change in oxidative induction time (OIT), melt flow index or tensile properties. Diffusion tests were performed as an index test for establishing the performance of the GMBs as a diffusive barrier to hydrocarbons, with permeation parameters for BTEX contaminants ranging from P g = 0.9-9.2 × 10-13 m2 s-1 for the exhumed GMB (with values depending on the contaminant and GMB). These values were similar to the parameters obtained for virgin GMBs and there was no significant change with field exposure, with GMBs appearing to be performing well.

Gas permeability of partially hydrated geosynthetic clay liner under two stress conditions

The results of a series of gas permeability tests, with monitoring of gravimetric/volumetric moisture content and total suction, on a commercially available needle-punched geosynthetic clay liner (GCL) are presented. GCL specimens were partially hydrated with deionised water under 2 and 20 kPa confinement prior to testing. The tests were conducted at differential pressures ranging from 1 to 10 kPa. Gas permeability was found to decrease with an increase in gravimetric/volumetric moisture content and a decrease of suction. The effect of the preconditioning stress was found to be more pronounced at gravimetric moisture contents greater than 40% (25% apparent degree of saturation, 0·30 m3/m3 volumetric moisture content), and suctions less than 1·6 MPa.