Visualising dynamic passivation and localised corrosion processes occurring on buried steel surfaces under the effect of anodic transients

A new method of visualising dynamically changing electrode processes has been demonstrated by mapping localised corrosion processes occurring on buried steel surfaces under the effect of anodic transients. Dynamically shifting external electrical interferences such as anodic transients are known to affect the efficiency of cathodic protection (CP) of underground pipelines; however unfortunately conventional techniques including electrochemical methods have difficulties in measuring such effects. In this paper we report that the wire beam electrode has necessary temporal and spatial resolutions required for measuring and visualising the dynamic effects of anodic transients on CP, passivation and localised corrosion processes occurring on buried steel surfaces. For the first time a critical anodic transient duration has been observed and explained as the incubation period for the breakdown of passivity and the initiation of localised corrosion.

New forms of organising : changing structures, processes and boundaries in a public sector institution

Globalisation, deregulation, privatisation, and advances in communications technologies have intensified competition and impacted on the structures, processes and boundaries that define organisations. Increased competition at both the local and global level calls for increased responsiveness and flexibility, and continuous improvement and innovation. As organisations endeavour to become more attentive and responsive to environmental trends, and customer needs and expectations, they are experimenting with different forms of organising. This has included flattening structures, devolving decision-making responsibility and encouraging greater collaboration and knowledge transfer across functional areas.

The William Angliss Institute of TAFE operates in the post-secondary sector which has experienced significant changes over the past decade as a result of: wide-ranging public sector reforms imposed by successive governments; budgetary cutbacks; accountability and performance improvement pressures; increased national and international competition, industrial relations changes and more demanding, sophisticated customers. This paper draws on the INNFORM Study's three organisational design dimensions of structure, process, and boundaries to examine the nature and degree of change that has taken place at the Institute. Case study findings indicate that while William Angliss has implemetted changes across the three design dimensions, the depth and breadth of these vary and this has impacted on overall performance outcomes. Its experience suggests that even when an organisation adopts a systemic approach and implements changes simultaneously across structure, process and boundaries, optimal performance benefits will not accrue unless these elemental changes are mutually reinforcing and complementary. It also suggests that improvement to processes, particularly communications and human resources practices must be an overarching consideration, as complementary change across all three design dimensions depends ultimately on the contribution and commitment organisational members are prepared to make.

Heterogeneous electrode processes and localized corrosion

This book covers the areas of electrochemical heterogeneity and electrode inhomogeneity and their effects on nonuniform electrode processes, in particular, localized corrosion. It covers the fundamentals, experimental methods, and engineering aspects of electrochemical heterogeneity.

Recent developments in characterising electrodeposition of anti-corrosion coatings using the wire beam electrode method

New progresses have been made during recent years in the application of the wire beam electrode (WBE, a coupled multielectrode array) for studying electroplating of metallic coatings, for monitoring the electrodeposition of polymer coatings, and for evaluating the performance of anti-corrosion coatings. The WBE allows localized electrode processes to occur over different locations of its surface under external anodic or cathodic polarization and permits monitoring of nonuniform electrodeposition processes. Several typical experiments are presented in this paper. One sample experiment is the characterization of nonuniform electroplating of nickel coating, which was achieved by mapping the distributions of currents over a WBE surface that was under cathodic polarization. Various characteristic current distribution patterns, which indicate different electrodeposition mechanisms or low covering-power, have been observed. These patterns were found to correlate with the effects of several affecting factors such as electrolyte concentration, temperature and agitation flow. Another sample experiment is the investigation of nonuniform anodic electrodeposition of polyaniline (PANI) coatings and the understanding of their anti-corrosion performance and mechanisms. Anodic polarization currents were measured from various locations over the WBE surface in order to produce anodic polarization current maps under PANI deposition.

Fault detection service architecture for grid computing systems

The ability to tolerate failures while effectively exploiting the grid computing resources in an scalable and transparent manner must be an integral part of grid computing infrastructure. Hence, fault-detection service is a necessary prerequisite to fault tolerance and fault recovery in grid computing. To this end, we present an scalable fault detection service architecture. The proposed fault-detection system provides services that monitors user applications, grid middlewares and the dynamically changing state of a collection of distributed resources. It reports summaries of this information to the appropriate agents on demand or instantaneously in the event of failures.

I think, therefore I print

Deakin University has for all of its existence supplied its distance education students with packs of printed course material. Despite the growth of online education the demand for printed material continues to grow. Faced with the challenge of improving processes Deakin University has turned to a process mapping model and ithink software to help it dynamically model internal processes allowing for the monitoring of demand shifts to see when and where tension is occurring in the system. The software allows the user to modify resource allocations to graphically observe where and when the ‘bottle-necks’ and capacity gaps are occurring and to perform a series of ‘what-if’ scenarios to address these capacity issues. These results are then allowing the University to work out where the ‘sticking points’ are and to improve resource allocation and processes. While the printing part of the course materials development process has been the pilot, the University expects to model all course material development processes, including hard copy, multimedia and online, using the ithink software.

Position estimation and tracking of an autonomous mobile sensor using received signal strength

In this paper, an algorithm for approximating the path of a moving autonomous mobile sensor with an unknown position location using Received Signal Strength (RSS) measurements is proposed. Using a Least Squares (LS) estimation method as an input, a Maximum-Likelihood (ML) approach is used to determine the location of the unknown mobile sensor. For the mobile sensor case, as the sensor changes position the characteristics of the RSS measurements also change; therefore the proposed method adapts the RSS measurement model by dynamically changing the pass loss value alpha to aid in position estimation. Secondly, a Recursive Least-Squares (RLS) algorithm is used to estimate the path of a moving mobile sensor using the Maximum-Likelihood position estimation as an input. The performance of the proposed algorithm is evaluated via simulation and it is shown that this method can accurately determine the position of the mobile sensor, and can efficiently track the position of the mobile sensor during motion.

Wireless broadcast encryption based on smart cards

Wireless broadcasting is an efficient way to broadcast data to a large number of users. Some commercial applications of wireless broadcasting, such as satellite pay-TV, desire that only those users who have paid for the service can retrieve broadcast data. This is often achieved by broadcast encryption, which allows a station securely to broadcast data to a dynamically changing set of privileged users through open air. Most existing broadcast encryption schemes can only revoke a pre-specified number of users before system re-setup or require high computation, communication and storage overheads in receivers. In this paper, we propose a new broadcast encryption scheme based on smart cards. In our scheme, smart cards are used to prevent users from leaking secret keys. Additionally, once an illegally cloned smart card is captured, our scheme also allows tracing of the compromised smart card by which illegal smart cards are cloned, and can then revoke all cloned smart cards. The new features of our scheme include minimal computation needs of only a few modular multiplications in the smart card, and the capability to revoke up to any number of users in one revocation. Furthermore, our scheme is secure against both passive and active attacks and has better performance than other schemes.

Determination of anabolic steroids by differential pulse polarography

Determination of anabolic steroids often requires the use of elaborate techniques such as gas chromatography - mass spectrometry (GC-MS), gas liquid chromatography (GLC) and more recently high performance liquid chromatography (HPLC). Most of these methods employ derivatisation techniques prior to detection which makes them tedious and relatively time consuming. Other methods demand a great deal of skill. A simple and rapid analytical method, based on differential pulse polarography at a dropping mercury electrode has been developed for the determination of various anabolic steroids in a range of commercially available pharmaceutical preparations. Detailed investigation of the electrochemical behaviour of these steroids was made in order to elucidate the electrode processes involved, in addition to optimising the method. Several other analytical methods such as GC-MS, NMR, ultraviolet (UV), infrared (IR) spectroscopy were also used to confirm the products of the chemical and electrochemical reactions. Possible reactions are suggested. Various extraction procedures were examined for separation of selected steroids from the oil-based or pill matrix and their suitability for polarographic determination is discussed.

Ionic liquid electrolytes as a platform for rechargeable metal–air batteries: a perspective

Metal-air batteries are a well-established technology that can offer high energy densities, low cost and environmental responsibility. Despite these favourable characteristics and utilisation of oxygen as the cathode reactant, these devices have been limited to primary applications, due to a number of problems that occur when the cell is recharged, including electrolyte loss and poor efficiency. Overcoming these obstacles is essential to creating a rechargeable metal-air battery that can be utilised for efficiently capturing renewable energy. Despite the first metal-air battery being created over 100 years ago, the emergence of reactive metals such as lithium has reinvigorated interest in this field. However the reactivity of some of these metals has generated a number of different philosophies regarding the electrolyte of the metal-air battery. Whilst much is already known about the anode and cathode processes in aqueous and organic electrolytes, the shortcomings of these electrolytes (i.e. volatility, instability, flammability etc.) have led some of the metal-air battery community to study room temperature ionic liquids (RTILs) as non-volatile, highly stable electrolytes that have the potential to support rechargeable metal-air battery processes. In this perspective, we discuss how some of these initial studies have demonstrated the capabilities of RTILs as metal-air battery electrolytes. We will also show that much of the long-held mechanistic knowledge of the oxygen electrode processes might not be applicable in RTIL based electrolytes, allowing for creative new solutions to the traditional irreversibility of the oxygen reduction reaction. Our understanding of key factors such as the effect of catalyst chemistry and surface structure, proton activity and interfacial reactions is still in its infancy in these novel electrolytes. In this perspective we highlight the key areas that need the attention of electrochemists and battery engineers, in order to progress the understanding of the physical and electrochemical processes in RTILs as electrolytes for the various forms of rechargeable metal-air batteries.

Detection of dynamic background due to swaying movements from motion features

Dynamically changing background (dynamic background) still presents a great challenge to many motion-based video surveillance systems. In the context of event detection, it is a major source of false alarms. There is a strong need from the security industry either to detect and suppress these false alarms, or dampen the effects of background changes, so as to increase the sensitivity to meaningful events of interest. In this paper, we restrict our focus to one of the most common causes of dynamic background changes: 1) that of swaying tree branches and 2) their shadows under windy conditions. Considering the ultimate goal in a video analytics pipeline, we formulate a new dynamic background detection problem as a signal processing alternative to the previously described but unreliable computer vision-based approaches. Within this new framework, we directly reduce the number of false alarms by testing if the detected events are due to characteristic background motions. In addition, we introduce a new data set suitable for the evaluation of dynamic background detection. It consists of real-world events detected by a commercial surveillance system from two static surveillance cameras. The research question we address is whether dynamic background can be detected reliably and efficiently using simple motion features and in the presence of similar but meaningful events, such as loitering. Inspired by the tree aerodynamics theory, we propose a novel method named local variation persistence (LVP), that captures the key characteristics of swaying motions. The method is posed as a convex optimization problem, whose variable is the local variation. We derive a computationally efficient algorithm for solving the optimization problem, the solution of which is then used to form a powerful detection statistic. On our newly collected data set, we demonstrate that the proposed LVP achieves excellent detection results and outperforms the best alternative adapted from existing art in the dynamic background literature.

Communication - an approach to measuring local electrochemical impedance for monitoring cathodic disbondment of coatings

An electrochemically integrated multi-electrode array has been used for monitoring and visualizing the cathodic disbondment of
defective coatings by measuring local electrochemical impedance. Compared with the conventional electrochemical impedance and
local current measurement approaches, this new approach significantly enhances the sensitivity of detecting the propagation of
coating disbondment by eliminating the effects of the dominating low impedance regions, such as those that arise at coating defects,
and thus increases the visibility of higher impedance regions deep in the disbonded coating. Furthermore, it facilitates the probing
of electrode processes and mechanisms in selected local electrode regions.