Freehand 3D Scanning in a Mobile Environment using Video

This work is motivated by two important trends in consumer computing: (i) the growing pervasiveness of mobile computing devices, and (ii) the users’ desire for increasingly complex but readily acquired and manipulated information content. Specifically, we develop and describe a system for 3D model creation of an object, using only a standard mobile device such as a smart phone. Our approach applies the structured light projection methodology and exploits multiple image input such as frames from a video sequence. In comparison with previous work, a significant further challenge addressed here is that of lower quality input data and limited hardware (processing power and memory, camera and projector quality). Novelties include: (i) a comparison of projection pattern detection approaches in the context of a mobile environment – a robust method combining colour detection and a phase congruency descriptor is evaluated, (ii) a model for single view reconstruction which exploits epipolar, coplanarity and topological constraints, (iii) the use of mobile device sensor data in the iterative closest point algorithm used to register multiple partial 3D reconstructions, and (iv) two heuristics for determining the order in which buffered single view based reconstructions are merged. Our experiments demonstrate that visually appealing results are obtained in a speedy manner which does not require specialist knowledge or expertise from the user.

Perceptive variation of carboxylate ligand and probing the influence of substitution pattern on the structure of mono- and di-butylstannoxane complexes

By reacting 2- and 3-aminobenzoic acids (HL1 and HL2, respectively), as well as 2-, 3- and 4-((E)-2-[4-(dimethylamino)phenyl]diazenyl)benzoic acids (HL3, HL4 and HL5, in this order) with a n-butyltin(IV) source [ n BuSn(O)OH or n Bu2SnO], the drum-type butylstannoxane complexes of general composition [ n Bu6Sn6O6(L n )6] [L n =L1 (1), L2 (2) and L3 (3)] and the ladder-type compounds [ n Bu8Sn4O2(L n )4] [L n =L3 (5), L4 (6) and L5 (7)] were obtained and fully characterized. By reacting 1 with 2-((E)-[4-(dimethylamino)benzylidene]amino)benzoic acid (HL6), a co-crystal (4) was achieved which comprises the metal complex aggregate found in 1 and the neutral HL6 molecule. The solution properties of the compounds were assessed from 1H and 13C NMR studies and, for the metal complexes, also from 119Sn NMR. The molecular structures of 1, 2, 4-7 were confirmed by single-crystal X-ray diffraction. Compounds 1-3 and the complex moiety of 4 display hexameric Sn6O6 clusters with drum-like structures, but 5-7 reveal Sn4O2 cores with ladder-type structural motifs. Besides the observed relationship between the ligand N-functional group and obtained (drum- or ladder-type) assemblies, the relative position of the carboxylate group in the ligand itself influences its coplanarity.