2 resultados para Carboreto de Boro
em Deakin Research Online - Australia
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Resumo:
Terpene alcohols (−)-menthol and [(1S)-endo]-(−)-borneol react with SiCl4 in the presence of base to give (MenO)3SiCl (1) and (BorO)3SiCl (2) in high yields. Hydrolysis of 1 yields (MenO)3SiOH (4) and (MenO)4Si (3). Hydrolysis of 2 yields only (BorO)3SiOH (5). The crystal structures of 3 and 5 are reported.