A solar collector with the absorber divided by rectangular slots

A new solar absorber structure has been proposed and studied in this paper. The metal tubes running perpendicular to a set of parallel rectangular metal fins make the solar absorber with rectangular slots. Studies on the collector were theoretically carried out in the aspects of heat transfer, thermodynamics and . hydrodynamics. The calculating methods for calculating fin efficiency F and efficiency factors of the collector F' were obtained. The results showed that the new solar collector would have the higher efficiency and better performance at higher fluid temperature than that of the traditional flat-plate collectors. A collector prototype with the new structure was built and tested. The testing results agree with our theoretical results.

Nano titanium dioxide on wool keratin as UV absorber stabilized by butane tetra carboxylic acid (BTCA): a statistical prospect

Photo yellowing of wool is one of the most important problems which have negative impacts on various aspects of wool prompting scientists to find a solution over the past decades. In this research the protective features of nano-titanium dioxide particles against UV on wool fabric were discussed and the color variations of wool samples after UV irradiation were measured and reported. It was shown that nano TiO2 is a suitable UV absorber and its effect depends on the concentration. Also, it was assumed that butane tetracarboxylic acid plays a prominent role as a cross-linking agent to stabilize the nano-titanium dioxide as well as a polyanion to maintain negative charges on the wool surface for higher nano particles absorption. Also the variables conditions were optimized using response surface methodology (RSM).

The photostability of wool doped with photocatalytic titanium dioxide

Photoyellowing of wool is a serious problem for the wool industry. This study assessed the role of photocatalytic nanocrystalline titanium dioxide (P-25) as a potential antagonist or catalyst in the photoyellowing of wool. Untreated, bleached and bleached and fluorescent-whitened wool slivers were processed into fine wool powders for the purpose of even and intimate mixing with the TiO2 nanoparticles in the solid state. Pure wool and wool/TiO2 mixtures were then compressed into solid discs for a photoyellowing study under simulated sunlight and under UVB and UVC radiations. Yellowness and photo-induced chemiluminescence (PICL) measurements showed that nanocrystalline TiO2 could effectively reduce the rate of photoyellowing by inhibiting free radical generation in doped wool, and that a higher concentration of TiO2 contributed to a lower rate of photooxidation and reduced photoyellowing. Hence nanocrystalline TiO2 acts primarily as a UV absorber on wool in dry conditions and not as a photocatalyst.

The effect of colour on the thermal performance of building integrated solar collectors

The use of solar collectors with coloured absorbers for water heating is an area of particular interest when considering their integration with buildings. By matching the absorber colour with that of the roof or façade of the building, it is possible to achieve an architecturally and visually pleasing result. Despite the potential for the use of coloured absorbers, very little work has been undertaken in the field.

In this study, the thermal performance of a series of coloured (ranging from white to black), building integrated solar collectors for water heating was examined both theoretically and experimentally. Subsequently, the annual solar fraction for typical water heating systems with coloured absorbers was calculated. The results showed that coloured solar collector absorbers can make noticeable contributions to heating loads. Furthermore, although their thermal efficiency is lower than highly developed selective coating absorbers, they offer the advantage of improved aesthetic integration with buildings.

Polymer coatings containing nano particles of zinc oxide for the UV protection of dyed polyester fabrics

The useful life of many outdoor textile products is limited by degradation caused by exposure to sunlight, in particular by the ultra violet component (below 400 nm). The degradation results in fading of colours and also loss of physical properties, such as tear strength and abrasion resistance. Degradation can be decreased with UV absorbers, often used in conjunction with antioxidants or free radical quenchers. The protection afforded by these organic compounds is, however, limited as they are ultimately destroyed by the UV radiation they absorb.
An alternative approach is to coat fabrics with a polymer containing an inorganic UV absorber, such as zinc oxide. The inherent stability of zinc oxide would be expected to provide a protective effect over a much longer period than can be achieved with an organic UV absorber. A possible disadvantage of zinc oxide when applied in a polymer film is that absorption and scattering of visible light can produce hazy films and, hence, an unacceptable change in fabric appearance.
This poster paper examines the possibility of using nano particles of zinc oxide dispersed in acrylic polymers for protecting dyed polyester fabrics against sunlight fading. Factors affecting both UV absorbance and film clarity will be discussed. The possibility will also be examined that the protective effect may be reduced in some circumstances by reactive oxygen species, generated by the interaction of UV with zinc oxide in the presence of air and water.

Visible transparent, UV-blocking polymer nanocomposite films containing nano-sized organic-LDH (Layered Double Hydroxide) hybrid

A nano-sized Mg2Al layered double hydroxide (LDH) was used for encapsulating an organic UV absorber, 2-hydroxy-4- methoxybenzeophenone-5-sulfonic acid (HMBS), to produce HMBS@LDH hybrid nano-platelets. Upon dispersing this organic-inorganic hybrid LDH into ethylene-vinyl alcohol copolymer (EVOH) for film casting, a thin polymer
nanocomposite film that is UV opaque but highly transparent to visible light (higher than 90%) was formed. Thermogravimetry (TG) analysis confirmed that the intercalation of HMBS into LDH considerably increased the thermal stability of HMBS. Such an improvement was attributed to the strong guest-host interaction between the HMBS anions and the LDH layers. Also, the nanocomposite films were flexible and had good mechanical properties.

Reducing photoyellowing of wool fabrics with silica coated ZnO nanoparticles

Though ZnO nanoparticles (NPs) are an excellent UV absorber, their photocatalytic activity greatly limits the application areas of these particles. Under sunlight exposure, ZnO NPs used as a UV absorber can accelerate the wool yellowing process by generating free radicals. To reduce this photocatalysis effect, a physical barrier has been fabricated by coating the ZnO NPs with a silica layer (ZnO@SiO2), hence providing good UV-shielding with low photocatalytic activity. The structure and optical properties of ZnO and ZnO@SiO2 NPs were characterized by transmission electron microscope (TEM) and UV–Vis spectrum. The photocatalytic activity of ZnO and ZnO@SiO2 NPs was evaluated by photo-degradation of Rhodamine B. The ZnO and ZnO@SiO2 NPs were applied to knitted wool fabrics using the dip coating method. The treated wool fabrics were characterized by a scanning electron microscope (SEM) and the photoyellowing level of treated fabrics after exposure under simulated sunlight was evaluated by a Datacolor Spectraflash spectrophotometer. The ZnO@SiO2 NPs demonstrated excellent protection of wool against photoyellowing.

Improving the photostability of bleached wool without increasing its yellowness

Bleached wool is rapidly yellowed by exposure to the UV radiation present in sunlight. The conventional application of a water-soluble hydroxyphenyl benzotriazole UV absorber (such as UVFast W) to bleached wool reduces its rate of photoyellowing but has a negative impact on the whiteness of the bleached wool, largely cancelling out the improvements in whiteness achieved during bleaching. However, if the UV absorber is applied to peroxide-bleached wool from a reductive bleach bath, white wool with improved photostability to sunlight and UV radiation can be obtained.

The photostability of wool doped with photocatalytic titanium dioxide nanoparticles

Photoyellowing of wool is a serious problem for the wool industry. This study assessed the role of photocatalytic nanocrystalline titanium dioxide (P-25) as a potential antagonist or catalyst in the photoyellowing of wool. Untreated, bleached and bleached and fluorescent-whitened wool slivers were processed into fine wool powders for the purpose of even and intimate mixing with the TiO2 nanoparticles in the solid state. Pure wool and wool/TiO2 mixtures were then compressed into solid discs for a photoyellowing study under simulated sunlight and under UVB and UVC radiations. Yellowness and photo-induced chemiluminescence (PICL) measurements showed that nanocrystalline TiO2 could effectively reduce the rate of photoyellowing by inhibiting free radical generation in doped wool, and that a higher concentration of TiO2 contributed to a lower rate of photooxidation and reduced photoyellowing. Hence nanocrystalline TiO2 acts primarily as a UV absorber on wool in dry conditions and not as a photocatalyst.

Reducing photoyellowing of wool using nano TiO2

Wool is the most important animal fiber used in textile industries, but its photostability is very low. Scientists have searched for new ways to increase the photostability of wool. As TiO2 nano particles have features suitable for new applications, the UV-blocking power of nano TiO2 may be used for protecting fabrics against UV rays. Treatment of wool with TiO 2 can be effective for controlling photodegradation. This study focused on protecting wool fabric against UV rays using nano TiO2. To this end, oxidized and raw wool were treated with citric acid as the cross-linking agent and different concentrations of nano TiO2. The whiteness and yellowness of wool fabric samples were reported. XRD patterns proved the existence of TiO2 nano-particles on the wool surface. Finally, the results revealed that nano TiO2 is a suitable UV absorber on wool fabric and its effect depends on concentration.

Protection of silica-coated ZnO nanoparticles on pre-dyed polyester fabrics against photofading

This work was designed to investigate the ability of silica-coated ZnO (ZnO&SiO2) nanoparticles (NPs) as ultraviolet (UV) absorbers for protecting pre-dyed polyester fabrics against photofading. Despite that ZnO NPs are excellent UV absorbers, their strong photocatalytic activity limits the application in UV protection. In this study, a silica layer was coated onto ZnO NPs to form a physical barrier between the ZnO and a polyester substrate, which allowed effective UV shielding while minimising the harmful effects of photocatalytic activity on the substrate. The structure and optical proprieties of ZnO&SiO2 NPs were observed. The bare ZnO and ZnO&SiO2 NPs were, respectively, applied to polyester fabrics coloured with three kinds of dyes by a dip coating method. The photofading level of treated fabrics after exposure under simulated sunlight was evaluated. The ZnO&SiO2 NPs exhibited excellent protection on pre-dyed polyester fabrics against photofading.

Optimizing time delay feedback for active vibration control of a cantilever beam using a genetic algorithm

Active vibration control using time delay for a cantilever beam is developed in this paper. The equation of motion of the system is developed using the discrete standard formulation, and the discrete quadratic function is used to design the controller. The original contribution in this paper is using a genetic algorithm to determine the optimal time delay feedback for active vibration control of a cantilever beam. Simulations of the beam demonstrated that the genetic algorithm correctly identified the time delay which produced the quickest attenuation of unwanted vibrations for both mode one and mode two. In terms of frequency response, the optimal time delay for both modes reduced the resonant amplitude. In a mixed mode situation, the simulation demonstrated that an optimal time delay could be identified.