Tariff and environmental policies with product standards

For a small open economy with consumption-based pollution emissions, the first-best optimal policy prescription is free trade along with a Pigouvian tax on emissions. Therefore, a package of coordinated tax reform by replacing tariffs with emission taxes can lower pollution emissions and increase market access and hence improve residents’ welfare and government revenue, as long as the initial tariffs are relatively high. Numerical simulations confirm the results obtained.

Predicting comfort properties of knitted fabrics by assessing yarns with the Wool ComfortMeter

This study examined the feasibility of assessing yarns with the Wool ComfortMeter (WCM) to predict the comfort properties of the corresponding single jersey-knitted fabrics. The optimum yarn arrangement to predict the comfort value of a corresponding control fabric was determined using nine wool and wool/nylon-blended yarns (mean fibre diameter range 16.5–24.9 μm) knitted into 34 different fabrics. Using a notched template, yarn winding frequencies of 1, 3, 6, 12, 25 and 50 parallel yarns were tested on the WCM. The best predictor of fabric WCM values was using 25 parallel yarns. Inclusion of knitting gauge and cover factor slightly improved predictions. This indicates that evaluation at the yarn stage would be a reliable predictor of knitted fabric comfort, and thus yarn testing would avoid the time and expense of fabric construction.

Fibre properties affecting the softness of wool and other keratins

The emerging market for next-to-skin knitwear requires wool to satisfy the consumer’s tactile requirements for softness. The role of the fibre’s surface and physical properties on fibre and fabric softness was examined. The fibre’s cuticle properties were found to have a greater influence on softness than the fibre’s mechanical properties.

Effects of different nutritional regimens on the productivity of Australian Cashmere goats and the partitioning of nutrients between cashmere and hair growth

The influence of energy or protein supplementation or energy restriction on cashmere growth was studied in 35 highly productive cashmere wether goats. The goats were shorn on 3 December and randomly allocated to 3 levels of energy intake: M, goats fed to maintain liveweight; 0.8M, goats fed to lose 5 kg liveweight from December to April and then fed ad libitum; and >M, goats fed to gain liveweight. Nested within >M were ADLIB (goats offered feed ad libitum), and 1.25M and l.5M (goats fed M plus 25 or 50% of the difference in mean intake between M and ADLIB). The metabolisable energy requirement to maintain liveweight was 250 kJ kg-0.75 day-1 but to maintain body condition (l.25M) it was 3 12 kJ kg-0.75 day-1. Goats fed 0.8M had a mean intake of 0.68M and lost 26 g day-1 liveweight until April, but when fed ad libitum consumed 2.15M in June and grew rapidly in late autumn and winter at 93 g day-1. Goats fed ADLIB consumed 2.30M in February and gained 87 g day-1 from December to February, but intake declined to 1.61 M in June and they gained 20 g day-1 from April to June. Cashmere growth and fibre diameters of fleeces shorn on 17 June of goats fed >M (221g, 17.69 pm) were significantly greater (P< 0.02) than those of goats fed 0.8M (146 g, 16.67 ¦m), with levels of M-fed goats being intermediate. Within >M, there were no significant differences in cashmere growth. Protein supplementation within M (27 or 54 g day -1 formaldehyde- treated casein) resulted in 40% more wool growth in sheep (P<0.001), but no increase in cashmere or hair growth in goats. Goats fed ADLIB had significantly reduced cashmere yields (P < 0.05) and grew more hair (P<0.05) than did goats in other treatments. About 4 weeks after energy supplementation, fibre diameter of previously energy-deprived goats increased (P< 0.01). Midside patches indicated that energy-deprived goats, which lost liveweight, diverted nutrients preferentially to cashmere growth, while goats fed ADLIB partitioned nutrients towards hair growth. To maximise cashmere growth, supplementary energy should be supplied to avoid liveweight loss from December to April. Goats that had small (1-2 kg) liveweight gains and maintained body condition achieved near maximal levels of cashmere growth.

The influence of yarn parameters on the ultraviolet protection of yarns

 Improving ultraviolet (UV) protection of textiles is essential to protect wearers against UV radiation induced risks. In addition to fabric parameters, yarn parameters are important factors affecting UV protection of textiles. This work is to examine the influence of yarn parameters on UV protection in order to set up a statistical model for predicting the UV protection of yarns. Wool yarns with different variables were used to test the ultraviolet protection factor (UPF) values for data analysis and the model verification. The model provides the optimized parameters for the UV protective fabric design. This work is helpful as a pre-cursor to the development of a more advanced optical model, which will look at understanding the penetration of UV light through fibres, yarns and fabrics.

Visible and UV functionality of TiO2 ternary nanocomposites on cotton

This research intends to increase the photocatalytic efficiency of cotton fabrics coated with TiO2-based nanocomposites under illumination particularly visible light. The fabrics were functionalized using a low-temperature sol-gel method of TiO2/Metal/SiO2 nanocomposite systems. Integrating silica and noble metals into TiO2 sol was put forth for boosting its functionality. Three noble metals (gold (Au), platinum (Pt) and silver (Ag)) with four different concentrations were employed. The photocatalytic activity of the functionalized fabrics was assessed through coffee stain-removal test and photodecomposition of methylene blue (MB) under UV and visible light. The impact of coating layers on fabrics' hydrophilicity was analyzed through measuring the water contact angle as well as the water absorption time. The fabrics were characterized using XRD, SEM and EDS. It was corroborated that the presence of silica enhanced the self-stain-removal capability of fabrics under UV. Moreover, the self-cleaning property of fabrics improved under both UV and visible light after integrating the metals into the colloids. In the same line, the self-cleaning activity threshold of fabrics was shifted to visible region.

Photostability of wool fabrics coated with pure and modified TiO2 colloids

The surface of wool fabrics was coated with TiO2 and TiO2-based nanocomposite colloids and the impact of this coating on the photostability of wool was investigated. TiO2 along with TiO2/Metal and TiO2/Metal/SiO2 sols were synthesized through a low-temperature sol-gel method and applied to fabrics. Composite colloids were synthesized through integrating the silica and three noble metals of silver (Ag), gold (Au) and platinum (Pt) into the synthesis process of sols. Four different molar ratios of Metal to TiO2 (0.01%, 0.1%, 0.5% and 1%) were used to elucidate the role of metal type and amount on the obtained features. Photostability and UV protection features of fabrics were evaluated through measuring the photo-induced chemiluminescence (PICL), photoyellowing rate and ultraviolet protection factor (UPF) of fabrics. PICL and photoyellowing tests were carried out under UVA and UVC light sources, respectively. PICL profiles demonstrated that the presence of pure and modified TiO2 nanoparticles on fabrics reduced the intensity of PICL peak indicating a lower amount of polymer free radicals in coated wool, compared to that of pristine fabric. Moreover, a higher PICL peak intensity as well as photoyellowing rate was observed on fabrics coated with modified colloids in comparison with pure TiO2. The surface morphology of fabrics was further characterized using FESEM images.

Review on fabrication and applications of ultrafine particles from animal protein fibres

Protein fibre wastes from animal hairs, feathers and insect secreted filaments can be aptly utilized by converting them into ultra-fine particles. Particles from animal protein fibres present large surface-to-weight ratio and significantly enhanced surface reactivity, that have opened up novel applications in both textile and non-textile fields. This review article summarizes the state-of-the-art routes to fabricate ultrafine particles from animal protein fibres, including direct route of mechanical milling of fibres and indirect route from fibre proteins. Ongoing research trends in novel applications of protein fibre particles in various fields, such as biomedical science, environmental protection and composite structures are presented. © 2014 The Korean Fiber Society and Springer Science+Business Media Dordrecht.

Improving the photostability of bleached wool without increasing its yellowness

Bleached wool is rapidly yellowed by exposure to the UV radiation present in sunlight. The conventional application of a water-soluble hydroxyphenyl benzotriazole UV absorber (such as UVFast W) to bleached wool reduces its rate of photoyellowing but has a negative impact on the whiteness of the bleached wool, largely cancelling out the improvements in whiteness achieved during bleaching. However, if the UV absorber is applied to peroxide-bleached wool from a reductive bleach bath, white wool with improved photostability to sunlight and UV radiation can be obtained.

Environmental impacts of tariff and tax reforms under origin and destination principles

The impacts of a point-by-point tariff/tax reform on the environment under the origin-based or destination-based tax principle are examined. The policy reform under the origin-based principle can raise the optimal pollution tax and, hence, improve the environment when the consumption demand and pollution are strongly substitutable, whereas the reform under the destination-based principle lowers the optimal pollution tax and, hence, worsens the environment. Nonetheless, when the consumption demand and pollution exhibit weak substitutes or even complements, the tariff/tax reform results in less environmental deterioration under the destination-based principle.

The influence of fiber diameter, fabric attributes and environmental conditions on wetness sensations of next-to-skin knitwear

This study investigated the relationships between the sensations of sweaty, damp, muggy and clingy, as assessed by human response from wearer trial garment assessment, and fiber type, fiber, yarn and fabric properties and instrumental fabric measurements of next-to-skin knitwear. Wearer trial assessment of 48 fabrics followed a strict 60 minute protocol including a range of environmental conditions and levels of exercise. Adjusted mean weighted scores were determined using linked garments. Instrumental fabric handle measurements were determined with the Wool HandleMeter (WHM) and Wool ComfortMeter. Data were analyzed using forward stepwise general linear modeling. Mean fiber diameter (MFD) affected the sweaty, damp, muggy and clingy sensation responses accounting for between 23.5% and 56.2% of the variance of these sensations. In all cases, finer fibers were associated with lower sensation scores (preferred). There were also effects of fiber type upon sweaty, muggy and clingy scores, with polyester fiber fabrics having higher scores (less preferred) compared with fabrics composed of wool, particularly for peak sweaty scores in hot and active environments. Attributes such as fabric density, yarn linear density, knitting structure and finishing treatments, but not fabric thickness, accounted for some further variance in these attributes once MFD had been taken into account. This is explained as finer fibers have a greater surface area for any given mass of fiber and so finer fibers can act as a more effective sink for moisture compared with coarser fibers. No fabric handle parameter or other attribute of fiber diameter distribution was significant in affecting these sensation scores.

A study of the feasibility of wool bonded polyurethane for sportswear applications

This study investigates if surface modification, in conjunction with thermal transfer, will improve the adhesion of polyurethane films onto a wool fabric surface for sportswear application. Atmospheric pressure plasma and hydrogen peroxide treatments were used to enhance the surface energy of the wool fabric. Polyurethane polymer films were transferred onto the surface of treated fabrics using a hot press method. The effectiveness of different treatments to improve the adhesion of the film onto the wool surface was tested by washing fastness and the stretch recovery of polyurethane bonded fabrics. The results confirmed improvement on adhesion properties of wool bonded fabrics after different treatments.

Reprint of: photostability of wool fabrics coated with pure and modified TiO2 colloids

The surface of wool fabrics was coated with TiO2 and TiO2-based nanocomposite colloids and the impact of this coating on the photostability of wool was investigated. TiO2 along with TiO2/Metal and TiO2/Metal/SiO2 sols were synthesized through a low-temperature sol-gel method and applied to fabrics. Composite colloids were synthesized through integrating the silica and three noble metals of silver (Ag), gold (Au) and platinum (Pt) into the synthesis process of sols. Four different molar ratios of Metal to TiO2 (0.01%, 0.1%, 0.5% and 1%) were used to elucidate the role of metal type and amount on the obtained features. Photostability and UV protection features of fabrics were evaluated through measuring the photo-induced chemiluminescence (PICL), photoyellowing rate and ultraviolet protection factor (UPF) of fabrics. PICL and photoyellowing tests were carried out under UVA and UVC light sources, respectively. PICL profiles demonstrated that the presence of pure and modified TiO2 nanoparticles on fabrics reduced the intensity of PICL peak indicating a lower amount of polymer free radicals in coated wool, compared to that of pristine fabric. Moreover, a higher PICL peak intensity as well as photoyellowing rate was observed on fabrics coated with modified colloids in comparison with pure TiO2. The surface morphology of fabrics was further characterized using FESEM images.

Extended studies on fibre diameter measurement with OFDA instrument

OFDA 2000 is a widely used fibre diameter measurement instrument. The instrument can provide improved statistical accuracy measurements in comparison with traditional technology. In this paper, a new technique has been developed to enable fibre diameters to be measured in an aqueous environment using the OFDA 2000 instrument. This new technique was utilised to assess the effects of pH and temperature on the diameters of Merino wool fibres in aqueous environments. Significant changes in fibre diameter under aqueous conditions were found as a function of pH and temperature. It is also demonstrated in this paper that the fibre diameter measurement results can be affected by fibre colour. In both dry and aqueous conditions, variation in fibre diameter was observed on fibres with different colours. This could be due to an optical effect or more likely due to physical changes in the dyed fibres as a result of the presence of dyes. Apart from their physical bulk, dyes may also affect the water content of fibres and hence have an influence on the swelling of fibres when they are measured under ambient regain and wet conditions.

Colour effect on fibre diameter measurement with OFDA 2000

In this study, wool samples from Merino, Corriedale and Lincoln sheep with a wide range of fibre diameters have been dyed and measured for fibre diameter using OFDA 2000 in both dry and conditioned states. Variation in fibre diameter is observed on fibres with different colours in both dry and aqueous conditions. This could be due to an optical effect or more likely due to physical changes in the dyed fibres owing to the presence of dyes. Apart from their physical bulk, dyes may also affect the owing water content of fibres and hence have an influence on the swelling of fibres when they are measured under ambient regain and wet conditions.