Direct electrospinning of nanofibre yarns using a rotating ring collector

Nanofibres prepared by electrospinning typically have randomly oriented fibrous structure. They have large surface-to-volume (or weight) ratio and excellent porous characteristic, which have shown enormous potential in diverse applications. However, electrospun nanofibres are often prepared in the form of randomly orientated fibrous web, which are fragile and difficult to be tailored in fibrous structures. Herein, we demonstrate a novel yarn electrospinning method which uses a rotating ring collector to convert newly electrospun nanofibres directly into a continuous yarn. The use of ring collector separates the yarn formation from the electrospinning zone. The deposition of later-spun nanofibres to the inner surface of fibrous cone eliminates hooked or curled nanofibres in the final yarn. The effects of polymer concentration and operating parameters on nanofibre and yarn morphology, diameter and the ring collector on yarn twist feature were examined. The nanofibre yarns had a surface twist angle up to 54.4°, and tensile strength as high as 93.6 MPa (elongation at break 242.6%). Increasing twist levels improves tensile strength and strain values.

Nerve guidance conduits from aligned nanofibers: improvement of nerve regeneration through longitudinal nanogrooves on a fiber surface

A novel fibrous conduit consisting of well-aligned nanofibers with longitudinal nanogrooves on the fiber surface was prepared by electrospinning and was subjected to an in vivo nerve regeneration study on rats using a sciatic nerve injury model. For comparison, a fibrous conduit having a similar fiber alignment structure without surface groove and an autograft were also conducted in the same test. The electrophysiological, walking track, gastrocnemius muscle, triple-immunofluorescence, and immunohistological analyses indicated that grooved fibers effectively improved sciatic nerve regeneration. This is mainly attributed to the highly ordered secondary structure formed by surface grooves and an increase in the specific surface area. Fibrous conduits made of longitudinally aligned nanofibers with longitudinal nanogrooves on the fiber surface may offer a new nerve guidance conduit for peripheral nerve repair and regeneration.

Effect of electrospinning parameters and polymer concentrations on mechanical-to-electrical energy conversion of randomly-oriented electrospun poly(vinylidene fluoride) nanofiber mats

Poly(vinylidene fluoride) (PVDF) nanofiber mats prepared by an electrospinning technique were used as an active layer for making mechanical-to-electric energy conversion devices. The effects of PVDF concentration and electrospinning parameters (e.g. applied voltage, spinning distance), as well as nanofiber mat thickness on the fiber diameter, PVDF β crystal phase content, and mechanical-to-electrical energy conversion properties of the electrospun PVDF nanofiber mats were examined. It was interesting to find that finer uniform PVDF fibers showed higher β crystal phase content and hence, the energy harvesting devices had higher electrical outputs, regardless of changing the electrospinning parameters and PVDF concentration. The voltage output always changed in the same trend to the change of current output whatever the change trend was caused by the operating parameters or polymer concentration. Both voltage and current output changes followed a similar trend to the change of the β crystal phase content in the nanofibers. The nanofiber mat thickness influenced the device electrical output, and the maximum output was found on the 70 μm thick nanofiber mat. These results suggest that uniform PVDF nanofibers with smaller diameters and high β crystal phase content facilitate mechanical-to-electric energy conversion. The understanding obtained from this study may benefit the development of novel piezoelectric nanofibrous materials and devices for various energy uses.

Robust mechanical-to-electrical energy conversion from short-distance electrospun poly(vinylidene fluoride) fiber webs

Electrospun polyvinylidene fluoride (PVDF) nanofiber webs have shown great potential in making mechanical-to-electrical energy conversion devices. Previously, polyvinylidene fluoride (PVDF) nanofibers were produced either using near-field electrospinning (spinning distance < 1 cm) or conventional electrospinning (spinning distance > 8 cm). PVDF fibers produced by an electrospinning at a spinning distance between 1 and 8 cm (referred to as "short-distance" electrospinning in this paper) has received little attention. In this study, we have found that PVDF electrospun in such a distance range can still be fibers, although interfiber connection is formed throughout the web. The interconnected PVDF fibers can have a comparable β crystal phase content and mechanical-to-electrical energy conversion property to those produced by conventional electrospinning. However, the interfiber connection was found to considerably stabilize the fibrous structure during repeated compression and decompression for electrical conversion. More interestingly, the short-distance electrospun PVDF fiber webs have higher delamination resistance and tensile strength than those of PVDF nanofiber webs produced by conventional electrospinning. Short-distance electrospun PVDF nanofibers could be more suitable for the development of robust energy harvesters than conventionally electrospun PVDF nanofibers.

Highly-twisted, continuous nanofibre yarns prepared by a hybrid needle-needleless electrospinning technique

Nanofibres prepared by electrospinning have shown enormous potential for various applications. They are obtained predominantly in the form of nonwoven fibre webs. The 2-dimensional nonwoven feature and fragility have considerably confined their further processing into fabrics through knitting or weaving. Nanofibre yarns, which are nanofibre bundles with continuous length and a twist feature, show improved tensile strength, offering opportunities for making 3-dimensional fibrous materials with precisely controlled fibrous architecture, porous features and fabric dimensions. Despite a few techniques having been developed for electrospinning nanofibre yarns, they are chiefly based on the needle electrospinning technique, which often has low nanofibre productivity. In this study, we for the first time report a nanofibre yarn electrospinning technique which combines both needle and needleless electrospinning. A rotating intermediate ring collector was employed to directly collect freshly-electrospun nanofibres into a fibrous cone, which was further drawn and twisted into a nanofibre yarn. This novel system was able to produce high tenacity yarn (tensile strength 128.9 MPa and max strain 222.1%) at a production rate of 240 m h^-1, with a twist level up to 4700 twists per metre. The effects of various parameters, e.g. position of the electrospinning units, operating conditions and polymer concentration, on nanofibre and yarn production were examined.

Effect of vapor-phase glutaraldehyde crosslinking on electrospun starch fibers

In this work, we have proven that starch nanofibrous membranes with high tensile strength, water stability and non-cytotoxicity can be produced by electrospinning of starch solution and post-treatment with GTA in vapor phase. GTA vapor phase crosslinking plays a key role in forming water-stable nanofiber membrane and improving the mechanical properties. Comparing with non-crosslinked starch fibers, the crosslinked fibers are increased by nearly 10 times in tensile strength. The crosslinked starch fibrous membranes are non-cytotoxic. They may find applications in the fields of tissue engineering, pharmaceutical therapy and medical.

Online stretching of directly electrospun nanofiber yarns

Nanofiber yarns are important building blocks for making three-dimensional nanostructures, e.g. through a knitting or weaving process, with better mechanical properties than nanofiber nonwovens and well-controlled fibrous construction. However, it still remains challenging to produce quality nanofiber yarns in a sufficient rate. In this study, we have proven that online stretching during electrospinning of nanofiber yarns can considerably improve fiber alignment and molecular orientation within the yarn and increase yarn tensile strength, but reduce fiber/yarn diameters. By compensating twist during online stretching, the device can prepare nanofiber yarns with different stretch levels, but maintaining the same twist multiplier. This allows us to examine the effect of stretching on fiber and yarn morphology. It was interesting to find that on increasing the stretching ratio from 0% to 95%, the yarn diameter reduced from 135.1 ± 20.3 μm to 46.2 ± 10.2 μm, and the fiber diameter reduced from 998 ± 141 nm to 631 ± 98 nm, whereas the yarn tensile strength increased from 48.2 ± 5.6 MPa to 127.7 ± 5.4 MPa. Such an advanced yarn electrospinning technique can produce nanofiber yarn with an overall yarn production rate as high as 10 m min−1. This may be useful for production of nanofiber yarns for various applications.

Effect of solvent treatment on morphology, crystallinity and tensile properties of cellulose acetate nanofiber mats

Aligned nanofiber mats were prepared from cellulose acetate using an electrospinning technique. The nanofiber mats were then immersed in an ethanol/acetone mixture. The solvent treatment led to denser, more compact fibrous structure and slight decrease in fiber alignment. It increased fiber diameter and polymer crystallinity within fibers. These effects resulted in increase in the tensile strength of fibrous mats. Solvent treatment may offer a simple, efficient approach to improve the mechanical strength of nanofibrous mats.

High-performance supercapacitor electrode from cellulose-derived, inter-bonded carbon nanofibers

Carbon nanofibers with inter-bonded fibrous structure show high supercapacitor performance when being used as electrode materials. Their preparation is highly desirable from cellulose through a pyrolysis technique, because cellulose is an abundant, low cost natural material and its carbonization does not emit toxic substance. However, interconnected carbon nanofibers prepared from electrospun cellulose nanofibers and their capacitive behaviors have not been reported in the research literature. Here we report a facile one-step strategy to prepare inter-bonded carbon nanofibers from partially hydrolyzed cellulose acetate nanofibers, for making high-performance supercapacitors as electrode materials. The inter-fiber connection shows considerable improvement in electrode electrochemical performances. The supercapacitor electrode has a specific capacitance of ∼241.4 F g-1 at 1 A g-1 current density. It maintains high cycling stability (negligible 0.1% capacitance reduction after 10,000 cycles) with a maximum power density of ∼84.1 kW kg-1. They may find applications in the development of efficient supercapacitor electrodes for energy storage applications.

Hydrangea-like multi-scale carbon hollow submicron spheres with hierarchical pores for high performance supercapacitor electrodes

Uniform hydrangea-like multi-scale carbon hollow submicron spheres (HCSSg) are fabricated by a simple hydrothermal method using glucose as carbon source and fibrous silicon dioxides spheres as shape guide. Structure characterization suggests that petal-like partially graphitized carbon nanosheets with the thickness of about 10 nm arranged in three dimensions (3D) to form the hydrangea-like hollow spheres (size ranging from 250 to 500 nm) with mesoporous channels, which can be conducive to be a high specific surface area (934 m2 g-1) and bulk density (0.87 cm g-3), hierarchical pores structure with good conductivity. As a result, the HCSSg has been demonstrated to be a supercapacitor electrode material with high gravimetric (386 F g-1 at 0.2 A g-1) and outstanding volumetric (335 F cm-3) capacitance, good rate capability and cycling stability with 94% capacitance retention after 5000 cycles in aqueous electrolytes, thus suggesting its application potential.

One-way water-transport cotton fabrics with enhanced cooling effect

Two types of directional water transport fabrics are prepared by using cotton fabric as substrate and an electrospraying technique to apply a hydrophobic coating on one side of the fabric. The main difference between the two electrosprayed fabrics is that one of them was precoated with a hydrophilic thermoconductive resin over the fiber surface prior to electrospraying. As a result, the precoated fabric has a much higher thermoconductivity than the other, while they are similar in water transport and fibrous structure. In the wet state, the directional water-transport fabrics generate a temperature difference between the two fabric sides while drying naturally. The fabric with higher thermal conductivity shows smaller temperature difference, better thermal transfer within the fabric, stronger evaporation cooling effect, and accelerated moisture evaporation. Directional water transport fabrics with high thermal conductivity may be used to mitigate thermal burden in sportswear, summer clothing, medical fabrics, and workwear.