109 resultados para magic-angle spinning


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The crystallographic rotation field for deformation in torsion is such that it is possible for orientations close to stable orientations to rotate away from the stable orientation. A Taylor type model was used to demonstrate that this phenomenon has the potential to transform randomly generated low-angle boundaries into high-angle boundaries. After imposing an equivalent strain of 1.2, up to 40% of the simulated boundaries displayed a disorientation in excess of 15°. These high-angle boundaries were characterised by a disorientation axis close to parallel with the sample radial direction. A series of hot torsion tests was carried out on 1050 aluminium to seek evidence for boundaries formed by this mechanism. A number of deformation-induced high-angle boundaries were identified. Many of these boundaries showed disorientation axes and rotation senses similar to those seen in the simulations. Between 10% and 25% of all the high-angle boundary present in samples twisted to equivalent strains between 2 and 7 could be attributed to the present mechanism.

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The theory of abstract convexity provides us with the necessary tools for building accurate one-sided approximations of functions. Cutting angle methods have recently emerged as a tool for global optimization of families of abstract convex functions. Their applicability have been subsequently extended to other problems, such as scattered data interpolation. This paper reviews three different applications of cutting angle methods, namely global optimization, generation of nonuniform random variates and multivatiate interpolation.

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Methods of Lipschitz optimization allow one to find and confirm the global minimum of multivariate Lipschitz functions using a finite number of function evaluations. This paper extends the Cutting Angle method, in which the optimization problem is solved by building a sequence of piecewise linear underestimates of the objective function. We use a more flexible set of support functions, which yields a better underestimate of a Lipschitz objective function. An efficient algorithm for enumeration of all local minima of the underestimate is presented, along with the results of numerical experiments. One dimensional Pijavski-Shubert method arises as a special case of the proposed approach.

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It is widely known that the so-called Cooks' Cottage in Fitzroy Gardens, relocated from Yorkshire to Melbourne in 1934, was never inhabited by Captain James Cook. Yet a subliminal nationalism, sustained by the ancient traditions of contagious magic, feeds the conviction that the dwelling must be directly connected to Australia's foundation hero — a relic that the great man touched — or else it is meaningless. This paper tracks a sequence of managerial–interpretive strategies derived from a chronology of knowledge systems to make meanings at the cottage. It introduces evidence of the original shape of the building in its Great Ayton location, and observes the consequences on management and interpretation of an older demolition and consequent rebuilding of only half the cottage in Melbourne. Much turns on changing ideas about authenticity, as management strategies fail to engage the popular taste for a hero via the magic of faith. The result is a set of opposing principles in presenting the cottage: the role of the historical record as it has enlarged, and the desires of visitors who expect a simple connection between myth and materiality.

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The ring spinning process has been used to produce fine and high quality staple fibre yarns. The stability of the rotating yarn loop (i.e. balloon) between the yarn-guide and the traveller-ring is crucial to the success and economics of this process. Balloon control rings are used to contain the yarn-loop, by reducing the yarn tension and decreasing the balloon flutter instability. Flutter instability here refers to the uncontrolled changes in a ballooning yarn under dynamic forces, including the air drag. Due to the significant variation in the length and radius of the balloon during the bobbin filling process, the optimal location for the balloon control ring is not easily determined. In order to address this difficulty, this study investigates the variation in the radius of a free balloon and examines the effect of balloon control rings of various diameters at different locations on yarn tension and balloon flutter stability. The results indicate that the maximum radius of a free balloon and its corresponding position depend not only on the yarn-length to balloon-height ratio, but also on yarn type and count. A control ring of suitable radius and position can significantly reduce yarn tension and decrease flutter instability of free single-loop balloons. While the balloon control rings are usually fixed to, and move in sinc with, the ring frame, results reported in this study suggest that theoretically, a balloon control ring that always remains approximately half way between the yarn-guide and the ring rail during spinning can lead to significant reduction in yarn tension.

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Objective
The patellofemoral joint is an example of an incongruent articulation commonly affected by osteoarthritis (OA). The relationship between femoral sulcus angle and the development and progression of patellofemoral OA is unclear. The aim of this study was to examine the relationship between the femoral sulcus angle at baseline and patella cartilage volume at baseline and at 2-year follow-up among community based adults with established knee OA.

Methods
One hundred subjects had magnetic resonance imaging of their symptomatic knee at baseline and at 2-year follow-up. From these images, patella cartilage volume was determined. Radiographic skyline views of the patellofemoral joint were taken at baseline to measure the femoral sulcus angle.

Results
For every 1° increase in the femoral sulcus angle (i.e., as the sulcus angle became more shallow) there was an associated 9.1 mm3 (95% CI 3.1, 15.0) increase in medial patella cartilage volume at baseline (P = 0.003). There was a similar trend that approached statistical significance between the femoral sulcus angle and the lateral patella facet cartilage volume at baseline (P = 0.09). There was no association between the femoral sulcus angle at baseline and the change in patella cartilage volume over 2 years in either patellofemoral compartment.

Conclusion
These results infer that the femoral sulcus angle is a cross-sectional determinant of the amount of patella cartilage, but is not a major determinant of the annual change of patella cartilage volume among people with knee OA. These data suggest that a shallower sulcus in the context of established OA may be an advantageous anatomical variant. Further longitudinal studies are required to determine the role of the femoral sulcus angle in OA.

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The adsorption of DNA on the Langmuir film of a cationic surfactant, dioctadecyldimethylammonium bromide (DODA·Br), and the change of the aggregation morphology of the composite monolayer with respect to surface pressure have been investigated by Brewster angle microscopy (BAM). In contrast with the case of DODA·Br on pure water subphase, when DNA was dispersed into subphase, its adsorption to the interface monolayer through electrostatic interaction decreases the charge density and therefore promotes the formation of domain at low surface pressure. In addition, the electrostatic interaction changed the phase morphology of DODA·Br Langmuir monolayer under different surface pressure, that is, from flower-shaped crystalline domain on the pure water subphase to circular domain on the subphase dispersed with DNA. The result also shows that the monolayer of the composite at air/water interface under the high pressure is not homogeneous, but consists of incompletely fused domains. For the Langmuir film of the surfactant with shorter alkyl-chains, similar morphology can be observed both under the high and low surface pressure. But the tight-stacked circular domain is no longer observed.

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Investigates a novel post-spinning yarn engineering technique, using the original concept of drafting-against-untwisting, to produce fine yarns with improved properties such as hairiness. With this concept, a "parent" staple yarn is simultaneously "false" untwisted and drafted to make a much finer yarn, in a continuous process.

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Review of Lehrich Christopher's "The occult mind: magic theory and practice".

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Time-of-flight secondary ion mass spectrometry (ToF-SIMS) was used to investigate correlations between the molecular changes and postcuring reaction on the surface of a diglycidyl ether of bisphenol A and diglycidylether of bisphenol F based epoxy resin cured with two different amine-based hardeners. The aim of this work was to present a proof of concept that ToF-SIMS has the ability to provide information regarding the reaction steps, path, and mechanism for organic reactions in general and for epoxy resin curing and postcuring reactions in particular. Contact-angle measurements were taken for the cured and postcured epoxy resins to correlate changes in the surface energy with the molecular structure of the surface. Principal components analysis (PCA) of the ToFSIMS positive spectra explained the variance in the molecular information, which was related to the resin curing and postcuring reactions with different hardeners and to the surface energy values. The first principal component captured information related to the chemical phenomena of the curing reaction path, branching, and network density based on changes in the relative ion density of the aliphatic hydrocarbon and the C7H7O+ positive ions. The second principal component captured information related to the difference in the surface energy, which was correlated to the difference in the relative intensity of the CxHyNz+ ions of the samples. PCA of the negative spectra provided insight into the extent of consumption of the hardener molecules in the curing and postcuring reactions of both systems based on the relative ion intensity of the nitrogen-containing negative ions and showed molecular correlations with the sample surface energy.

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A spinneret for producing nanofibres from a viscous liquid using electrostatic spinning in an electric field is described. The spinneret includes one or more narrow annular bodies radially centred about and axially spaced along a central axis. The annular bodies may be discs, rings, or coils.