Photochromic wool fabrics from a hybrid silica coating

In this work, a photochromic wool fabric has been prepared by applying a photochromic-dye hybrid silica sol-gel onto the surface of fabric. The photochromic fabric was found to have a very quick optical response. Two types of silica were used as the matrix material, and the type of silica had a small effect only on the photochromic performance, the fabric washing fastness, and water contact angle, but affected the fabric handle property considerably. The silica from a precursor containing a long alkyl chain showed very little influence on the fabric handle and better photochromic performance than that containing a phenyl group.

Conductive poly(α,ω-bis(3-pyrrolyl)alkanes)-coated wool fabrics

Cross-linked poly(α,ω-bis(3-pyrrolyl)alkanes) were directly applied to woven wool substrates by either chemical, vapour or mist polymerization methods. Choice of dopant could greatly improve the surface resistance. The optimum coating on textiles with the lowest surface resistance, highest colour-fastness and stability was achieved using a mist polymerization method with 1,8-bis(pyrrolyl)octane, iron(III) chloride (FeCl₃) as the oxidant and p-toluene sulfonic acid sodium salt (pTSA) as the dopant.

Surface modification and bleaching of pigmented wool

We treat naturally pigmented karakul wool with a surface modification system of chlorination and catalytic bleaching, then examine its structure and properties. SEM photos reveal the surface morphology of karakul wool, and the Allworden reaction shows the extent of damage to the epicuticle. The results show that the surface modification removes the bulk of the fiber scales and bleaching increases fiber whiteness. After bleaching, the felting propensity of karakul wool improves slightly and its dye uptake decreases. For modified and bleached karakul wool, the felting propensity decreases, the dyeing rate increases, and equilibrium exhaustion decreases compared with untreated karakul wool.

Thermal conductivity studies on wool fabrics with conductive coatings

Methods of improving the thermal conductivity of wool fabrics have been investigated. Thermal conductivity measurement techniques, influence of synthesis parameters on the thermal conductivity of polypyrrole (PPy)-coated wool fabrics, and the relationship between electrical conductivity and thermal conductivity of PPy-coated wool fabrics are presented. An improvement in thermal conductivity was observed when fabrics were coated with the PPy. The thermal conductivity increased with the increase of pyrrole concentration and synthesis time. Anthraquinone-2-sulfonic acid and ferric chloride showed an optimal concentration for their influence on the thermal conductivity of the coated fabric. The improvement of thermal conductivity of wool fabrics is also investigated by Physical Vapor Deposition technique.

Modification of wool fiber using steam explosion

Wool fiber was modified by steam explosion in this study. SEM results show that some scales on the fiber surface were cleaved and tiny grooves generated during the explosion. FTIR results suggest no evident changes in the chemical composition of the fiber after the explosion treatment. However, the crystallinity of the fiber decreased slightly as the steam pressure increased based on the X-ray results. In the thermal analysis, DSC results show that the temperature corresponding to vaporization of absorbed water and cleavage of disulfide bonds respectively decreased as the steam pressure increased. The reduction in thermal decomposition energy of the treated fiber indicates that steam explosion might have destroyed some crystals and crosslinks of macromolecular chains in the fiber. The treatment also led to some alterations of the fiber properties, including reduction in strength, moisture regain and solubility in caustic solution.

Preparation of Mg55Ni35Si10 amorphous powders by mechanical alloying and consolidation by vacuum hot pressing

Amorphous 55Mg35NilOSi alloy powder has been synthesized by mechanical alloying technique using pure Mg, Ni and Si elemental powders. The transformation of the crystalline powders into an amorphous one has been investigated by X-ray diffraction, scanning electron microscopy, transmission electron microscopy and differential scanning calorimetry. The new material produced has a higher thermal stability than reported results, which is beneficial to the fabrication of Mg-Ni-Si bulk amorphous components through powder metallurgy.

Changes in fibre curvature during the processing of wool and alpaca fibres and their blends

This paper studied the wool and alpaca fibre curvature and its variation during the fibre processing. It revealed the effect of wool fibre crimp on the cohesion properties of alpaca and wool blended slivers. Different wool and alpaca tops were blended via a number of gillings, and the role of wool fibre curvature in alpaca/wool blend processing has also been investigated. During the wool fibre processing, fibre curvature tended to diminish gradually from scoured fibre to top. Blending wool with alpaca fibres improved the cohesion properties of the blended sliver, compared with pure alpaca slivers. For a high ratio of alpaca component in the blend, a high-crimp wool should be used to achieve good sliver cohesion.

A comparative study of the mechanical properties of wool and alpaca fibres

This study reports the latest research into alpaca and wool fibres. In particular, those properties that have received little attention in research literature have been examined. They include single fibre abrasion and bending fatigue, single fibre tensile properties, as well as resistance to compression behaviour. These properties are important because they affect the softness and pilling propensity of these fibres and the resultant fabrics. Clean wool and alpaca fibres were used in this study. Fibre abrasion/bending fatigue measurements were carried out using a Textechno FIBRESTRESS instrument. The resistance to compression (RtC) tests were carried out according to Australian Standard AS3535-1988. The results indicate that wool and alpaca fibres behave quite differently, even though both fibre types are of animal origin. Wool fibre resistance to compression decreases as fibre diameter increases while the opposite appears to occur for alpaca fibres. For both wool and alpaca the number of abrasion/bending cycles at fibre break increases with an increase in fibre diameter, it takes longer to break the alpaca fibres. Reasons for these differences have been postulated based on differences in fibre surface and structure between alpaca and wool.