Enhanced thermal stability and lifetime of epoxy nanocomposites using covalently functionalized clay: Experimental and modelling

The present work aims at finding a relationship between kinetic models of thermal degradation process with the physiochemical structure of epoxy-clay nanocomposites in order to understand its service temperature. In this work, two different types of modified clays, including clay modified with (3-aminopropyl)triethoxysilane (APTES) and a commercial organoclay, were covalently and non-covalently incorporated into epoxy matrix, respectively. The effect of different concentrations of silanized clay on thermal behaviour of epoxy nanocomposites were first investigated in order to choose the optimum clay concentration. Afterwards, thermal characteristics of the degradation process of epoxy nanocomposites were obtained by TGA analysis and the results were employed to determine the kinetic parameters using model-free isoconversional and model-fitting methods. The obtained kinetic parameters were used to model the entire degradation process. The results showed that the incorporation of the different modified clay into epoxy matrix change the mathematical model of the degradation process, associating with different orientations of clay into epoxy matrix confirming by XRD results. The obtained models for each epoxy nanocomposite systems were used to investigate the dependence of degradation rate and degradation time on temperature and conversion degree. Our results provide an explanation as to how the life time of epoxy and its nanocomposites change in a wide range of operating temperatures as a result of their structural changes.

Integrated model of horizontal earth pipe cooling system for a hot humid climate

Energy efficiency of a building has become a major requirement since the building sector produces 40%-50% of the global greenhouse gas emissions. This can be achieved by improving building’s performance through energy savings, by adopting energy efficient technologies and reducing CO2 emissions. There exist several technologies with less or no environmental impact that can be used to reduce energy consumption of the buildings. Earth pipe cooling system is one of them, which works with a long buried pipe with one end for intake air and the other end for providing air cooled by soil to the building. It is an approach for cooling a room in a passive process without using any habitual mechanical unit. The paper investigates the thermal performance of a horizontal earth pipe cooling system in a hot and humid subtropical climatic zone in Queensland, Australia. An integrated numerical model for the horizontal earth pipe cooling system and the room (or building) was developed using ANSYS Fluent to measure the thermal performance of the system. The impact of air temperature, soil temperature, air velocity and relative humidity on room cooling performance has also been assessed. As the soil temperature was below the outdoor minimum temperature during the peak warming hours of the day, it worked as an effective heat sink to cool the room. Both experimental and numerical results showed a temperature reduction of 1.11oC in the room utilizing horizontal earth pipe cooling system which will assist to save the energy cost in the buildings.

Parametric study on thermal performance of horizontal earth pipe cooling system in summer

Rational use of energy and its associated greenhouse gas emissions has become a key issue for a sustainable environment and economy. A substantial amount of energy is consumed by today's buildings which are accountable for about 40% of the global energy consumption. There are on-going researches in order to overcome these and find new techniques through energy efficient measures. Passive air cooling of earth pipe cooling technique is one of those which can save energy in buildings with no greenhouse gas emissions. The performance of the earth pipe cooling system is mainly affected by the parameters, namely air velocity, pipe length, pipe diameter, pipe material, and pipe depth. This paper investigates the impact of these parameters on thermal performance of the horizontal earth pipe cooling system in a hot humid subtropical climate at Rockhampton, Australia. For the parametric investigation, a thermal model was developed for the horizontal earth pipe cooling system using the simulation program, FLUENT 15.0. Results showed a significant effect for air velocity, pipe length, and pipe diameter on the earth pipe cooling performance, where the pipe length dominated the other parameters.