Photoredox catalysis of intramolecular cyclizations with a reusable silica-bound ruthenium complex

Photoredox catalysis with the use of a stable, reusable silica-bound chromophore was applied to the intramolecular cyclization of a series of 2-benzylidenehydrazinecarbothioamides to give 5-phenyl-1,3,4-thiadiazol-2-amines. The catalyst was readily prepared by carbodiimide-mediated coupling of commercially available amine-functionalized silica beads to a carboxylic acid functionalized ruthenium complex. The immobilized catalyst was readily removed from the reaction product by filtration and was used eight times without loss of catalytic activity. This simple, safe, and practical method is an attractive alternative to conventional procedures.

Theorising geo-identity and David Harvey’s space: school choices of the geographically bound middle-class

This paper draws on David Harvey’s theories of absolute and relational space in order to critique geographically bound school choices of the gentrified middle-class in the City of Melbourne, Australia. The paper relies on interviews with inner-city school choosers as generated by a longitudinal ethnographic school choice study. I argue that the participants construct their class-identity in relation to their geographical (or residential) positioning and this influences their schooling choices. In the light of this argument, I theorise geo-identity in thinking about how geographies inform and instruct identity and choice. This paper contributes by offering a focused analysis of Harvey’s spatial theories and class-identity in processes of choice.