Thermal and mechanical properties of a dendritic hydroxyl-functional hyperbranched polymer and tetrafunctional epoxy resin blends

Blends of a tetrafunctional epoxy resin, tetraglycidyl- 4,40'-diaminodiphenylmethane (TGDDM), and a hydroxylfunctionalized hyperbranched polymer (HBP), aliphatic hyperbranched polyester Boltorn H40, were prepared using 3,3'-diaminodiphenyl sulfone (DDS) as curing agent. The phase behavior and morphology of the DDS-cured epoxy/HBP blends with HBP content up to 30 phr were investigated by differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), and scanning electron microscopy (SEM). The phase behavior and morphology of the DDS-cured epoxy/HBP blends were observed to be dependent on the blend composition. Blends with HBP content from 10 to 30 phr, show a particulate morphology where discrete HBP-rich particles are dispersed in the continuous cured epoxy-rich matrix. The cured blends with 15 and 20 phr exhibit a bimodal particle size distribution whereas the cured blend with 30 phr HBP demonstrates a monomodal particle size distribution. Mechanical measurements show that at a concentration range of 0–30 phr addition, the HBP is able to almost double the fracture toughness of the unmodified TGDDM epoxy resin. FTIR displays the formation of hydrogen bonding between the epoxy network and the HBP modifier.

Refinement of microstructure in steels through thermomechanical processing

The refinement of microstructure is the most generally accepted approach to simultaneously improve the strength and toughness in steels. In the current study, the role of dynamic/static phase transformation on the ferrite grain refinement was investigated using different thermomechanical processing routes. A Ni-30Fe austenitic model alloy was also used to investigate the substructure character formed during deformation. It was revealed that the microstructure of steel could further be refined to the nanoscale through both the control of processing route and steel composition design.

Quickstep

Quickstep✹ is a novel technology for composite materials manufacturing. Characterisation of carbon fibre reinforced polymer composites cured both conventionally and with the low cost Quickstep process revealed a higher glass transition temperature, enhanced fracture toughness and better impact resistance for the Quickstep composite laminates.

Fracture behaviour of a rapidly cured polyethersulfone toughened carbon fibre/epoxy composite

An out-of-autoclave rapid heating/low pressure technique has been used to cure polyethersulfone (PES) toughened HexPly 8552. Mode I and mode II tests were conducted to evaluate the fracture toughness of the composites and the effectiveness of cure was determined through thermal analysis. When compared to the autoclave process, the out-of-autoclave process resulted in a 52% reduction in processing time, without any sacrifice to the matrix intrinsic properties. Thermal analysis indicated an 8 °C improvement in glass transition temperature (T_g) as a result of an increased degree of cure. The out-of-autoclave process did lack in the ability to facilitate the removal of porosity which affected the fracture toughness results. The porosity is believed to have increased the mode I propagation fracture toughness. However its effect on mode II was quite deleterious, shown by scanning electron microscopy (SEM). This study managed to identify a number of key parameters associated with the out-of-autoclave process essential for further optimisation.

Enhancing the interfacial properties of Quickstep{u2122} cured biocomposites

This research has enhanced the performance of natural fibre composites by optimisation of the cure cycle under Quickstep{u2122} process and treatment time under atmospheric pressure glow discharge plasma. The study has also utilised many characterization methods, theoretical models, and established surface-property relationship to manufacture composites with optimum strength and toughness.

Properties of a carbon-fibre composite modified by electrospun poly (vinylidene fluoride)

The interlaminar toughening of a carbon-fibre reinforced composite by incorporation of electrospun polyvinylidene fluoride (PVDF) nanofibrous membranes was explored in this work. The nanofibres were electrospun directly onto commercial pre-impregnated carbon fibre materials under optimised conditions and PVDF was found to primarily crystallise in its β phase polymorphic form. There is strong evidence from DMTA analysis to suggest that a partial miscibility between the amorphous phases of the PVDF nanofibres and the epoxy exists. The improved plastic deformation at the crack tip after inclusion of the nanofibres was directly translated to a 57% increase in the mode II interlaminar fracture toughness (in-plane shear failure). Conversely, the fracture toughness in mode I (opening failure) was slightly lower than the reference by approximately 20%, and the results were interpreted from the complex micromechanisms of failure arising from the changes in polymorphism of the PVDF.

Effect of manufacturing process on the final properties of advanced high strength steels for automotive applications

The performance of multiphase steels with high strength and improved toughness or ductility, such as intercritically annealed dual-phase (DP) and transformation-induced plasticity (TRIP) steels, is of key importance to the automotive industry. In this work we have considered the entire manufacturing process and the effects of this on the final product performance. These steels are formed to produce the required final shape and then the car is paint baked. In this work we also consider the effect of cold working and bake hardening on the fatigue life of the components.

Toughening epoxy thermosets and their carbon fibre reinforced composites with electrospun nanofibres

Electrospun nanofibres have emerged as important fibrous materials for diverse applications. They have been shown excellent toughening results when they are applied as interlayer materials between carbon/epoxy laminas in the structural carbon fibre reinforced epoxy matrix composites. They also exhibit synergistic modification effects when they are combined with carbon nanofibres in the thermosetting polymer matrix. In this study, electrospun polyetherketone cardo (PEK-C) nanofibres were used in two ways: directly electrospun onto the surface of carbon fabric [1], and blended with epoxy resin in the form of PEK-C/VGCNF (vapour grown carbon nanofibre) composite nanofibres[2].The interlaminar fracture toughness, flexural properties and thermal mechanical properties of the modified systems were investigated.

Electrospun nanofibres

This book deals with an emerging nanofibre-making technology, electrospinning, the functionalities of electrospun nanofibres and their wound healing application. An important fundamental issue, fibre morphological evolution during electrospinning, is clarified. Effective techniques to improve the fibre toughness and control the surface wettability of nanofibre membrane have been developed. These functional nanofibre membranes have been used as dressing materials for healing skin wounds, and shown promising results. This work makes electrospun nanofibre membrane an ideal candidate for wound healing application.

Toughening of a carbon-fibre composite using electrospun poly(Hydroxyether of Bisphenol A) nanofibrous membranes through inverse phase separation and inter-domain etherification

The interlaminar toughening of a carbon fibre reinforced composite by interleaving a thin layer (~20 microns) of poly(hydroxyether of bisphenol A) (phenoxy) nanofibres was explored in this work. Nanofibres, free of defect and averaging several hundred nanometres, were produced by electrospinning directly onto a pre-impregnated carbon fibre material (Toray G83C) at various concentrations between 0.5 wt % and 2 wt %. During curing at 150 °C, phenoxy diffuses through the epoxy resin to form a semi interpenetrating network with an inverse phase type of morphology where the epoxy became the co-continuous phase with a nodular morphology. This type of morphology improved the fracture toughness in mode I (opening failure) and mode II (in-plane shear failure) by up to 150% and 30%, respectively. Interlaminar shear stress test results showed that the interleaving did not negatively affect the effective in-plane strength of the composites. Furthermore, there was some evidence from DMTA and FT-IR analysis to suggest that inter-domain etherification between the residual epoxide groups with the pendant hydroxyl groups of the phenoxy occurred, also leading to an increase in glass transition temperature (~7.5 °C).

On toughening of epoxies and their carbon fibre-reinforced composites

Compared to the neat matrix material, FRC has highly favorable mechanical properties, and their strength-to-weight ratios are superior. In addition, FRCs have potential for use in many applications in dentistry and are expected to gain increasing applications in the future. This book includes both review and research papers in different FRC areas from contributors around the world.

The long-term performance of cementitious composites reinforced with coir fibre

Effective prediction of the long-term performance of natural fibre-reinforced cementitious materials is vital for their application. In this study, coir fibres of two different average lengths were combined with cementitious materials and chemical agents to form coir fibre-reinforced cementitious composites (CFRCCs). The composites long-term performance was assessed and compared with two different accelerated ageing processes, i.e. a cement-saturated water ageing, and alternate freeze-thaw ageing. The flexural properties were compared with the properties of the reference mortar. Overall, the flexural strength of 400 days naturally aged CFRCC specimens was weaker than that of the reference mortar. The toughness and ductility of the fibre-reinforced specimens, however, improved. The cement-saturated water ageing method gave a precise prediction of the flexural strength development of 400-day-old specimens, and the freeze-thaw ageing method worked very well for the toughness performance estimation of CFRCCs.