Effect of natural organic compounds on the removal of organic carbon in coagulation and flocculation processes

Natural organic matter (NOM) in water contains organic compounds that are both hydrophobic and hydrophilic with a wide range of molecular weights. It is composed of non-homogeneous organic compounds such as humic substances, amino acids, sugars, aliphatic and aromatic acids, and other chemical synthetic organic matters. NOM in water is a major concern not only because of its contribution to the formation of disinfection by-products (DBPs) and taste and odor, but also its influence on the demand for coagulants and disinfectants, the removal efficiency of water treatment processes, etc. This research aims at identifying the influence of NOM in coagulation and flocculation processes in order to optimize the coagulation and flocculation conditions. In this study, pretreated pond water was used as the source water. It was observed from the experimental results that: (1) The optimum pH for coagulation to remove NOM is around 7. (2) The optimum alum dose at this pH can vary from 125-1,225 mgl-1 when the TOC is increased from 4 to 25 mgl-1. (3) The presence of secondary compounds such as Ca2+, Mg2+ divalent cations had no significant effect on the removal of organic matter. (4) The presence of clay increased the organic removal by 15%. (5) The organic compound with higher molecular weight has higher removal affinity in coagulation process. (6) Floc size and settling velocity of floc and sludge production all increased with the increase in NOM concentration. From the results of Capillary Suction Time (CST) tests, the floc formed with lower TOC readily released the water to make the dewatering process easier. (7) The organic removal efficiency was significantly different for natural water containing non-homogeneous organic compounds compared to the synthetic water containing humic acid only (homogeneous organic matter). For example, the NOM removal efficiency was 80% for the synthetic water containing humic acid with TOC of 7 mgl-1 at pH 7; but the NOM removal for the pretreated pond water was 60%.

The nature and scope of rights of removal

The rationale underlying the fixtures and accession presumptions is the need to protect the value of the chattel as well as the need to protect third-party interests. The destruction of the independent legal status of an attached chattel is generally deemed appropriate where the value of the co-mingled asset will be diminished if the chattel retains a separate legal title and this would generate unfairness because third parties have dealt with the co-mingled asset on the basis of its overall value. Rights to remove have evolved under both common law and equity to moderate the scope of these presumptions. Common law will uphold the right of a tenant to remove chattels that have been attached to leased premises during the currency of the lease. Equity on the other hand will uphold the right to remove affixed chattels in circumstances where the enforcement of such an entitlement is consistent with contractual intention and transactional fairness. This article examines the different rights of removal that have evolved under Australian law to date and the emergent statutory framework supporting these rights. It discusses the historical purpose and structural utility of these entitlements within a land framework that supports fixtures presumptions. Rights of removal, whether validated at law or in equity, confer positive entitlements upon the holder to access and remove affixed goods in circumstances where, because of the fixtures and accession presumptions, those goods no longer retain any separate legal status. The capacity of the holder to enforce this right against third parties is illustrative of their distinctive proprietary perspective.

Removal of ametryn through nanofiltration and reverse osmosis

 This study focused on the performance of nanofiltration (NF) and reverse osmosis (RO) in the removal of ametryn. Here, we investigated the effects of the applied pressure and ionic conditions on the removal of ametryn from water. It was found that the adsorption of ametryn onto NF membrane to decrease with the increase in ionic strength. Increased interaction between the NaCl electrolyte and the membrane surface is considered as the reason for the reduction in the adsorption. However, adsorption of ametryn onto the RO membrane did not show any trend. The removal of ametryn by NF and RO found to increase with the increase in the ionic strength. Retention of electrolyte salt (NaCl) on the membrane surface tends to decrease the membrane pore size which in turn increases the removal of ametryn at higher ionic strengths. It was found that up to 92% of ametryn could be removed using RO.

Ammonia nitrogen removal from aqueous solution using functionalized zeolite columns

In this study, a functionalized zeolites column was developed to remove ammonia nitrogen with a low concentration (50 mg/L) from aqueous solution. The absorption properties and regeneration capacity were investigated. Through breakthrough and elution curve for dynamic adsorption, we found the wastewater with 50 mg/L ammonia nitrogen took 7 h to flow 10 g modified zeolites column with diameters of 24 to 64 meshes at a flow rate of 2 mL/min. The saturated extent of adsorption was up to 7.95 mg/g, and the saturated adsorption time was 22 h. The process of dynamic adsorption could be fitted by the Thomas Model. The regeneration ability was optimized by 0.1 M Na2CO3 as a regenerant. With excellent absorption ability for removing ammonia nitrogen with a low concentration, the functionalized zeolites could be potentially used a high-performance adsorbent for removing ammonia nitrogen.

Analyzing track sprint cyclists' performances using position-specific maximal-torque and power-cadence relationships

Previous studies have demonstrated the importance of maximal Torque-Cadence (T-C) and Power-Cadence (P-C) relationships, for the performances of world class track sprint cyclists. If these relationships are affected by the function of the lower limb muscles, the ability of cyclists to generate torque and power at a given cadence may vary depending on their riding position. During sprint events (individual and team sprints and Keirin), cyclists alternate between standing and seated positions. The T-C and P-C relationships may change with the position adopted by the cyclists. PURPOSE: The aim of this study was to evaluate the necessity to define position specific maximal T-C and P-C relationships. METHODS: Eight junior elite track cyclists from the National Talent Identification squad undertook two inertial-load tests that consisted of four all-out sprints each. One test was undertaken at the velodrome in a standing position on a carbon fibre track bike, and the other test was completed in a seated position on an air-braked stationary ergometer. A calibrated SRM power meter interfaced to a custom instrumentation package was used for all mechanical measurements. Maximal T-C and P-C relationships were analysed to calculate maximal Torque (T0), maximal Power (Pmax) and optimal pedalling cadence (PCopt). RESULTS: All individual T-C and P-C relationships obtained for both body positions were fitted by linear regressions (r2=0.95 ± 0.02) and second order polynomials (r2=0.96 ± 0.01), respectively. T0 was higher (209 ± 2.2N.m vs. 177.0 ± 3.9N.m, p<0.05), PCopt was lower (112.5 ± 11.4rpm vs. 120.1 ± 6.7rpm, p<0.05), and Pmax was higher (1261 ± 235W vs. 1076 ± 183W, p<0.05) in standing position compared to seated position. CONCLUSION: Analysis of track sprint cyclists’ performances can be improved by the determination of position-specific maximal T-C and P-C relationships .

Recyclable textiles functionalized with reduced graphene Oxide@ZnO for removal of oil spills and dye pollutants

A novel recyclable and flexible membrane was prepared for the removal of oil spills and organic dye pollutants, by functionalizing polyester textiles with reduced graphene oxide@ZnO nanocomposites using a layer-by-layer technique. The membrane showed efficient water/oil separation, and the amount of oil adsorbed by the membrane could be up to 23 times its own weight. The adsorption capacity was largely retained during many adsorption recycling cycles. The membrane also displayed highly efficient removal of a dye pollutant from water under simulated sunlight. The membrane maintained a near-original removal efficiency after five cycles of dye removal. This new type of membrane may find practical applications in the large-scale separation of organic pollutants from water, particularly in the field of oil spills clean-up and dye removal from industrial effluent.

The safety and effectiveness of different methods of ear wax removal: a systematic review and economic evaluation

Build-up of earwax is a common reason for attendance in primary care. Current practice for earwax removal generally involves the use of a softening agent, followed by irrigation of the ear if required. However, the safety and benefits of the different methods of removal are not known for certain.

Ear wax removal interventions : a systematic review and economic evaluation

Excessive ear wax can lead to symptoms such as hearing loss, tinnitus, itching, vertigo, and pain. Treatment to remove ear wax is generally carried out in primary care, and recent estimates suggest that up to 2 million ear irrigations are performed in England and Wales each year.1 This places a considerable demand on GP surgeries. A range of simple and often inexpensive remedies and proprietary drops can be used either to dissipate the wax orsoften it prior to removal. Although removal through irrigation usually occurs in primary care, some people may self-treat. Treatments offered often appear to be based on custom and local practice, rather than an awareness of the comparative effectiveness and costs of the different alternatives. Although evidence on the efficacy of different treatments has been published, no study has examined both clinical and cost-effectiveness. This report summarises a systematic review and economic evaluation of different approaches to ear wax removal taken from a UK perspective.