Study of the creep behaviour of stitched woven composites

An experimental and theoretical study of the tensile creep behaviour of woven fibre composites stitched with cotton, and carbon threads, along or perpendicular to the loading direction with different densities is presented. The results of creep tests, conducted at ambient temperature and various elevated temperatures with low to high stress levels are reported.

Computer-assisted image analysis of liver collagen: relationship to Ishak scoring and hepatic venous pressure gradient

Histopathological scoring of disease stage uses descriptive categories without measuring the amount of fibrosis. Collagen, the major component of fibrous tissue, can be quantified by computer-assisted digital image analysis (DIA) using histological sections. We determined relationships between DIA, Ishak stage, and hepatic venous pressure gradient (HVPG) reflecting severity of fibrosis. One hundred fifteen patients with hepatitis C virus (HCV) who had undergone transplantation had 250 consecutive transjugular liver biopsies combined with HVPG (median length, 22 mm; median total portal tracts, 12), evaluated using the Ishak system and stained with Sirus red for DIA. Liver collagen was expressed as collagen proportionate area (CPA). Median CPA was 6% (0.2-45), correlating with Ishak stage (stage 6 range, 13%-45%), and with HVPG (r = 0.62; P < 0.001). Median CPA was 4.1% when HVPG was less than 6 mm Hg and 13.8% when HVPG was 6 mm Hg or more (P < 0.0001) and 6% when HVPG was less than 10 mm Hg and 17.3% when HVPG was 10 mm Hg or higher (P < 0.0001). Only CPA, not Ishak stage/grade, was independently associated by logistic regression, with HVPG of 6 mm Hg or more [odds ratio, 1.206; 95% confidence interval (CI), 1.094-1.331; P < 0.001], or HVPG of 10 mm Hg or more (odds ratio, 1.105; 95% CI, 1.026-1.191; P = 0.009). CPA increased by 50% (3.6%) compared with 20% in HVPG (1 mm Hg) in 38 patients with repeated biopsies. Conclusion: CPA assessed by DIA correlated with Ishak stage scores and HVPG measured contemporaneously. CPA was a better histological correlate with HVPG than Ishak stage, had a greater numerical change when HVPG was low, and resulted in further quantitation of fibrosis in cirrhosis.

Highly fluorescent TPA-PBPV nanofibers with amplified sensory response to TNT

Well-aligned nanofibers were prepared from a conjugated polymer, poly(triphenylamine-alt-biphenylene vinylene) (TPA-PBPV), using a solution-assisted template wetting technique. TPA-PBPV was also coated on the surface of electrospun polyacrylonitrile (PAN) nanofiber nonwoven membrane. The extremely large surface area, highly porous fibrous structure, optical scattering and evanescent-wave guiding effect imparted these one-dimensional (1D) nanofibrous materials with highly improved sensory ability to 2,4,6-trinitrotoluene (TNT) vapors and higher quenching efficiency than that of the neat TPA-PBPV films. The results suggest that nanofibrous structures could be a promising strategy to improve the sensory efficiency of fluorescent chemosensors.

Recent developments in wool related research in Australia

Fibre related research in Australia is entering a new era. In May 2010, the former Prime Minister of Australia, Mr Kevin Rudd, announced a $37 million grant under the Education investment Fund (EIF) scheme to establish the Australian Future Fibres Research and Innovation Centre (AFFRIC) at Deakin University’s Geelong Campus. This is $102 million joint initiative between Deakin University, CSIRO Materials Science and Engineering (MSE) and the Victorian Centre for Advanced Materials Manufacturing (VCAMM). Wool related research fits within two of the four program areas under AFFRIC: green natural fibres and functional fibrous materials. Selected examples of our recent wool related research are discussed, with a focus on the work involving researchers at Deakin University.

Synthesis and characterization of silver nanoparticles and titanium oxide nanofibers : toward multifibrous nanocomposites

A new method was investigated to produce new multiscale fibrous nanocomposites comprised of titanium oxide (TiO₂) nanofibers and silver (Ag) nanoparticles (NPs). The process involved electrospinning TiO₂ precursor solution containing colloidal solution of Ag NPs, and organic solvent (dimethyl-n′n-formamide) to fabricate a porous, nonwoven, free-standing nanofiber mesh. Postprocess heating of the electrospun nanofibers entailed calcination in air environment at 500°C for 3 h. Microemulsion processing was used to generate NPs of Ag in a monodispersed distribution throughout the colloidal solution. X-ray diffraction data were consistent with the anatase phase of TiO2, while transmission electron microscopy and hydrogen desorption measurements revealed a very porous microstructure. It was demonstrated that NP colloidal stability is solvent dependent. It is anticipated that incorporation of metal particles in nanofibers will lead to enhanced photocurrent generation, when used in functional devices.

High quality electrospun nanofibres

The data collected relates to the operating parameters of electrospinning, the nanofibre and fibrous membrane properties and the performance evaluation in different applications.

Architecture of fiber network : from understanding to engineering of molecular gels

A new approach of engineering of molecular gels was established on the basis of a nucleation-initiated network formation mechanism. A variety of gel network structures can be obtained by regulating the starting temperature of the sol−gel transition. This enables us to tune the network from the spherulitic domains pattern to the extensively interconnected fibrillar network. As the consequence of fibrous network structure turning, desirable rheological and other in-use properties of the materials can be obtained accordingly. This approach of micro-/nanostructural fabrication may open up a new route for micro-/nanofunctional materials engineering in general.

Controlling nanoparticle formation via sizable cages of supramolecular soft materials

We present a new generic strategy to fabricate nanoparticles in the “cages” within the fibrous networks of supramolecular soft materials. As the cages can be acquired by a design-and-production manner, the size of nanoparticles synthesized within the cages can be tuned accordingly. To implement this idea, both selenium and silver were chosen for the detailed investigation. It follows that the sizes of selenium and silver nanoparticles can be controlled by tuning the pore size of the fiber networks in the material. When the concentration of the gelator is high enough, monodisperse nanoparticles can be prepared. More interestingly, the morphology of the nanoparticles can be altered: silver disks can be formed when the concentrations of both the gelator and silver nitrate are sufficiently low. As the fiber network serves as a physical barrier and semisolid support for the nanoparticles, the stability in the aqueous media and the ease of application of these nanoparticles can be substantially enhanced. This robust surfactant-free approach will not only allow the controlled fabrication of nanoparticles, but also can be applied to the fabrication of composite materials for robust applications.

Modelling of fibre-diameter-dependent light scattering to determine diameter corrections for colour measurement of wool

In this paper, fibre-diameter-dependent light scattering during measurement of wool colour was quantified using the extended multiplicative signal correction technique. Furthermore, a simple-to-apply model has been developed to correct each of the CIE (International Commission on Illumination) X, Y and Z values obtained from colour measurement of fibrous masses. The model was successfully applied to both polypropylene (PP) and wool fibres, though different parameter values were used in each case, indicating different patterns of internal light scattering between PP and wool fibres. After the model corrections, the diameter dependence of measured wool yellowness (Y - Z) was either eliminated or significantly reduced for each of seven sheep flocks distributed widely over the wool-growing regions of Australia.

Needleless electrospinning and direct electrospinning of nanofiber yarns

Electrospinning is a simple, but efficient and versatile, technology to produce polymeric nanofibers for widely diverse applications in both textile and non-textile areas [1]. This technique has been shown many advantages such as universality in processing polymeric materials, eases of controlling the fiber diameter and functionalizing nanofibers through adjusting solution composition for electrospinning, and flexibility to generate fibrous membranes of various geometries. Although the novel applications of electrospun nanofibers have been extensively explored [2], the technology development for mass electrospinning of nanofibers has been hampered.

Toughening epoxy thermosets and their carbon fibre reinforced composites with electrospun nanofibres

Electrospun nanofibres have emerged as important fibrous materials for diverse applications. They have been shown excellent toughening results when they are applied as interlayer materials between carbon/epoxy laminas in the structural carbon fibre reinforced epoxy matrix composites. They also exhibit synergistic modification effects when they are combined with carbon nanofibres in the thermosetting polymer matrix. In this study, electrospun polyetherketone cardo (PEK-C) nanofibres were used in two ways: directly electrospun onto the surface of carbon fabric [1], and blended with epoxy resin in the form of PEK-C/VGCNF (vapour grown carbon nanofibre) composite nanofibres[2].The interlaminar fracture toughness, flexural properties and thermal mechanical properties of the modified systems were investigated.

Drug release rate and anti-microbial effect of controlled-diffusion biopolymer membranes

In this study, a series of fibrous membranes made from cellulose acetate (CA) and polyester urethane (PEU) by co-electrospining or blend-electrospining were evaluated for drug release kinetics, in vitro anti-microbial activity and in vivo would healing performance when used as wound dressings. To stop common clinical infections, an antibacterial agent, Polyhexamethylene Biguanide (PHMB) was incorporated into e-spun fibres. The presence of CA in the wound healing membrane was found to improve hydrophilicity and permeability to air and moisture. The in vivo tests indicated that the addition of PHMB and CA considerably improved the wound healing efficiency. CA fibres became slightly swollen upon contacting with the wound exudates. It can not only speed up the liquid evaporation but also create a moisture environment for wound recovery. The drug release dynamics of membranes was controlled by the structure of membranes and component rations within membranes. The lower ration of CA:PEU retained the sound mechanical properties of membranes, and also reduced the boost release effectively and slowed down diffusion of antibacterial agent during in vitro tests. The controlled-diffusion membranes exert long-term anti-infective effect.

Electrospinning of continuous nanofiber bundles and twisted nanofiber yarns

Spinning is a prehistoric technology in which endless filaments, shorter fibers or twisted fibers are put together to produce yarns that serve as key element to assemble multifarious structural designs for diverse functions. Electrospinning has been regarded as the most effective and versatile technology to produce nanofibers with controlled fiber morphology, dimension and functional components from various polymeric materials (Dersch et al., 2007, Frenot and Chronakis, 2003, Schreuder-Gibson et al., 2002). However, most electrospun fibers are produced in the form of randomly-oriented nonwoven fiber mats (Doshi and Reneker, 1995, Madhavamoorthi, 2005). The relatively low mechanical strength and difficulty in tailoring the fibrous structure have restricted their applications. With the rapid development in nanoscience and nanotechnology, yarns composed of nanofibers may uncover new opportunities for development of well-defined three dimensional nano fibrous architectures. This chapter focuses on recent research and advancement in electrospinning of nanofiber bundles and nanofiber yarns. The preparation, morphology, mechanical properties and potential applications of these fibrous materials are discussed in details.

Compressive properties of hot-rolled Mg-Zr-Ca alloys for biomedical applications

This paper investigated the microstructures and compressive properties of hot-rolled Mg-Zr-Ca alloys for biomedical applications. The microstructures of the Mg-Zr-Ca alloys were examined by X-ray diffraction analysis and optical microscopy, and the compressive properties were determined from compressive tests. The experimental results indicate that the hot-rolled Mg-Zr-Ca alloys with 1% Ca are composed of one single α phase and those alloys with 2% Ca consist of both Mg2Ca and α phase. The hot-rolled Mg-Zr-Ca alloys exhibit typical elongated microstructures with obvious fibrous stripe, and have much higher compressive strength and lower compressive modulus than pure Mg. All the studied alloys have much higher compressive yield strength than the human bone (90~140 MPa) and comparable modulus with the human bone, suggesting that they have a great potential to be good candidates for biomedical applications.

Fabrication of carbon nanofiber by pyrolysis of freeze-dried cellulose nanofiber

The possibility of fabricating carbon nanofibers from cellulose nanofibers was investigated. Cellulose nanofiber of ~50 nm in diameter was produced using ball milling in an eco-friendly manner. The effect of the drying techniques of cellulose nanofibers on the morphology of carbon residue was studied. After pyrolysis of freeze-dried cellulose nanofibers below 600 °C, amorphous carbon fibers of ~20 nm in diameter were obtained. The pyrolysis of oven-dried precursors resulted in the loss of original fibrous structures. The different results arising from the two drying techniques are attributed to the difference in the spatial distance between cellulose nanofiber precursors.