80 resultados para Carbon steel
Resumo:
Three different heat treatment processes have been proposed as a fundamental method to produce three kinds of TRIP-aided steels with polygonal ferritic matrix (F-TRIP), bainitic matrix (B-TRIP) and martensitic matrix (M-TRIP) in a newly designed low alloy carbon steel. By means of dilatometry study and detailed characterization, the relationships among transformation, microstructure and the resulting mechanical behavior were compared and analyzed for the three cases. The work hardening of the samples was evaluated by calculating the instantaneous n value as a function of strain. The M-TRIP sample exhibits the highest strength with the highest work hardening rate at low strains and subsequent rapid descending at high strains. In contrast, the B-TRIP sample has relatively high continuously constant work hardening behavior over strain levels greater than 0.067. The difference in work hardening behavior corresponds directly to the rate of the retained austenite-martensitic transformation during straining, which can be attributed to the carbon content, the morphology of the retained austenite and the matrix microstructure in the respective TRIP-aided samples. © 2014 Elsevier B.V.
Resumo:
The preparation and physical properties of a novel family of ionic liquids and organic salts based on the imidazolinium cation are described, and compared with their imidazolium analogues in some cases. Ionic liquids were obtained with the triflate, formate and salicylate anions, while > 100 °C melting points were observed with acetate and several other benzoate derivatives. The triflate salt was less ion-conductive than the corresponding imidazolium salt, but less so than expected on the basis of its viscosity, suggesting a contribution from proton conductivity. The electrochemical window of the imidazolinium was slightly extended in the reductive direction, due to the lower proton activity produced by the cation in this case. Imidazolinium salts are also known to exhibit anti-corrosion properties and hence a preliminary study of this property is also reported; 2-methylimidazolinium 4-hydroxycinnamate was found to show strong anodic corrosion inhibition on mild steel.
Resumo:
The effects of copper on as-cast structure, recrystallization and precipitation kinetics of strip cast low carbon steel were investigated. As-cast microstructure mainly consists of polygonal ferrite and Widmanstatten ferrite. Recrystallization responses were strongly dependent on initial microstructure and Cu content. Precipitation strengthening was observed in high copper content alloys.
Resumo:
The abrasive wear resistance of four distinct metallurgical steel microstructures - bainite, pearlite, martensite and tempered martensite, with similar hardness levels was investigated. A pin-on-disc tribometer was used to simulate the two-body abrasive condition (i.e. the metallic surface abrading against the silicon carbide abrasive particles) and evaluate the specific wear rate of the microstructures. Each microstructure had a unique response towards the abrasion behaviour and this was largely evident in the friction curve. However, the multi-phase microstructures (i.e. bainite and pearlite) demonstrated better abrasion resistance than the single-phase microstructures (i.e. martensite and tempered martensite). Abrasion induced microstructural changes at the deformed surfaces were studied using sub-surface and topographical techniques. The properties of these layers (i.e. surface profile measurements) determined the amount of material loss for each microstructure. These were directly linked to the single-wear track analysis that highlighted a marked difference in their mode of material removal. Ploughing and wedge formation modes were dominant in the case of bainite and pearlite microstructures, whereas the cutting mode could be attributed to the higher material loss in the single-phase microstructures. The combination of brittle and ductile phases in the multi-phase microstructure matrix could be one of the driving factors for their superior abrasion resistance.
Resumo:
The properties of interfaces depend not only on the lattice misorientation, but also on the interface plane orientation. Extensive studies of grain boundaries led to the conclusion that in systems evolving by grain growth, the relative areas of different grain boundary planes are inversely correlated to their relative energies. In other words, the low energy grain boundary planes make up a larger part of the population than the higher energy grain boundary planes. The hypothesis of this work is that the interface plane orientation distribution in transformed microstructures depends more on the mechanism of formation than on the relative energy. After a discussion of methods for measuring interface plane orientations, results will be presented for lath martensite in a low carbon steel and for martensite in a Ti-6Al-4V alloy processed in two different ways to promote a displacive transformation in one case and a diffusional transformation in the other.
Resumo:
Praseodymium 4-hydroxycinnamate (Pr(4OHCin)3) was investigated as a novel corrosion inhibitor for steel in NaCl solutions, and found to be effective at inhibiting corrosion in both CO2-containing and naturally-aerated systems. Surface analysis results suggest that the corrosion inhibition ability of Pr(4OHCin)3 in the naturally-aerated corrosion system could be attributed to the formation of a continuous protective film. For the CO2-containing system, the corrosion inhibition efficiency of Pr(4OHCin)3 was predominantly because of formation of protective inhibiting deposits at the active electrochemical corrosion sites, in addition to a thinner surface film deposit. © 2013.
Resumo:
A series of rare earth 4-hydroxycinnamate compounds including Ce(4OHCin)3, La(4OHCin)3, and Pr(4OHCin)3 has been synthesized and evaluated as novel inhibitors for carbon dioxide corrosion of steel in CO2-saturated sodium chloride solutions. Electrochemical measurements and surface analysis have shown that these REM(4OHCin)3 compounds effectively inhibited CO2 corrosion by forming protective inhibiting deposits that shut down the active electrochemical corrosion sites on the steel surface. Inhibition efficiency was found to increase in the order Ce(4OHCin)3 < La(4OHCin)3 < Pr(4OHCin)3 and with increase in inhibitor concentration up to 0.63 mM. Detailed insights into corrosion inhibition mechanism of these compounds in carbon dioxide environment are also provided.
Resumo:
The present work investigates the transformation behavior of a low-carbon Mo-Nb linepipe steel and the corresponding transformation product microstructures using deformation dilatometry. The continuous cooling transformation (CCT) diagrams have been constructed for both the fully recrystallized austenite and that deformed in uniaxial compression at 1148 K (875 °C) to a strain of 0.5 for cooling rates ranging from 0.1 to about 100 K/s. The obtained microstructures have been studied in detail using electron backscattered diffraction complemented by transmission electron microscopy. Heavy deformation of the parent austenite has caused a significant expansion of the polygonal ferrite transformation field in the CCT diagram, as well as a shift in the non-equilibrium ferrite transformation fields toward higher cooling rates. Furthermore, the austenite deformation has resulted in a pronounced refinement in both the effective grain (sheaf/packet) size and substructure unit size of the non-equilibrium ferrite microstructures. The optimum microstructure expected to display an excellent balance between strength and toughness is a mix of quasi-polygonal ferrite and granular bainite (often termed “acicular ferrite”) produced from the heavily deformed austenite within a processing window covering the cooling rates from about 10 to about 100 K/s.
Resumo:
The deformation and fracture mechanisms of a low carbon microalloyed steel processed by asymmetric rolling (AsR) and symmetric rolling (SR) were compared by microstructural and texture evolutions during uniaxial tensile deformation. A realistic microstructure-based micromechanical modeling was involved as well. AsR provides more effective grain refinement and beneficial shear textures, leading to higher ductility and extraordinary strain hardening with improved yield and ultimate tensile stresses as well as promoting the occurrence of ductile fracture. This was verified and further explained by means of the different fracture modes during quasi-static uniaxial deformation, the preferred void nucleation sites and crack propagation behavior, and the change in the dislocation density based on the kernel average misorientation (KAM) distribution. The equivalent strain/stress partitioning during tensile deformation of AsR and SR specimens was modeled based on a two-dimensional (2D) representative volume element (RVE) approach. The trend of strain/stress partitioning in the ferrite matrix agrees well with the experimental results.
Resumo:
This paper examines the impact of coiling temperature and duration on the phase transformation and precipitation behavior of a low carbon and low niobium direct strip cast steel. Coiling was performed at three carefully chosen temperatures: (1) in the ferrite (600°C), (2) during the austenite decomposition (700°C) and (3) in the austenite (850°C). The coiling conditions were found to strongly affect the final microstructure and hardness response, thus highlighting the necessity to judiciously design the coiling treatment. Optical microscopy, and scanning and transmission electron microscopy were used to characterize the microstructural constituents (polygonal ferrite, bainite and pearlite) and the NbC precipitates. Vickers macrohardness measurements are utilized to quantify the mechanical properties. The differences in hardening kinetics for the three different temperatures are shown to come from a complex combination of strengthening contributions.