Dynamic mechanical thermal analysis studies of factors influencing relaxation in polyetherurethane based solid electrolytes

Dynamic mechanical thermal analysis (DMTA) has been used to study the effects of plasticizers on the mobility and homogeneity of a series of solid polymer electrolytes (SPEs). With reference to previously published results on similar systems containing LiClO₄ salts and tetraglyme as plasticizer, the effects of propylene carbonate (PC) on the glass transition temperature (T_g) of the SPE and on the distribution of relaxation times within the sample are discussed; at low plasticizer concentration PC has little effect on T_g as measured by DMTA in comparison with tetraglyme, and at higher plasticizer concentrations PC significantly broadens the mechanical relaxation behaviour indicating a greater degree of dynamical heterogeneity within the sample. A second low temperature relaxation is evident at lower PC contents indicating that some regions of this plasticized SPE are distinctly more mobile than others or perhaps, on this length scale, that some degree of phase separation is present. Activation energies for the mechanical relaxation were also determined as a function of PC concentration and are significantly greater than those determined from conductivity measurements.

Thermal and physical properties of an archetypal organic ionic plastic crystal electrolyte

The thermal and mechanical properties of the ionic plastic crystal N-methyl-N-propylpyrrolidinium hexafluorophosphate have been investigated and the effect of adding a miscible polymer on the mechanical properties is reported. The physical properties of the pure plastic crystal are discussed in detail and for the first time the change in volume with temperature for an organic ionic plastic crystal is reported. An increase in volume in conjunction with increased conductivity supports the hypothesis that ion conduction within the plastic crystal proceeds via defects. For phase I and melting, the magnitude of the volume increase does not appear to be in accord with the subtle change in conductivity. This is suggested to be due to the presence of layer defects, which allow for correlated ionic motion, which does not increase the conductivity. Addition of polymer to the plastic crystal significantly increases the mechanical strength, decreases the conductivity, but has little effect on the phase behaviour, further supporting the hypothesis of vacancy-mediated conduction.

Balancing buildings and occupants - a holistic approach to thermal comfort and greenhouse gas emissions in mixed mode offices

This paper describes a holistic approach to comfort and greenhouse gas emissions in mixed mode offices. It is based on parametric studies for a typical cellular office in the Mediterranean climate of Athens, Greece, using building simulation.

Considered parameters are the influence of different building design, varying occupant behaviour and internal heat loads, as well as of an exceptionally hot summer. Additionally, the performance of a cooling strategy following the comfort limits according to the EN 15251 adaptive model is compared with the common fixed cooling set point 22°C.

The performance of mixed mode offices is evaluated regarding thermal comfort, daylight autonomy and related greenhouse gas emissions. Results indicate strategies to improve sustainability in mixed mode offices in Athens, by balancing the influencing parameters.

On the influence of building design, occupants and heat waves on comfort and greenhouse gas emissions in naturally ventilated offices. A study based on the EN 15251 adaptive thermal comfort model in Athens, Greece

According to the Intergovernmental Panel on Climate Change the buildings sector has the largest mitigation potential for CO2 emissions. Especially in office buildings, where internal heat loads and a relatively high occupant density occur at the same time with solar heat gains, overheating has become a common problem. In Europe the adaptive thermal comfort model according to EN 15251 provides a method to evaluate thermal comfort in naturally ventilated buildings. However, especially in the context of the climate change and the occurrence of heat waves within the last decade, the question arises, how thermal comfort can be maintained without additional cooling, especially in warm climates. In this paper a parametric study for a typical cellular naturally ventilated office room has been conducted, using the building simulation software EnergyPlus. It is based on the Mediterranean climate of Athens, Greece. Adaptive thermal comfort is evaluated according to EN 15251. Variations refer to different building design priorities, and they consider the variability of occupant behaviour and internal heat loads by using an ideal and worst case scenario. The influence of heat waves is considered by comparing measured temperatures for an average and an exceptionally hot year within the last decade. Since the use of building controls for shading affects thermal as well as visual comfort, daylighting and view are evaluated as well. Conclusions are drawn regarding the influence and interaction of building design, occupants and heat waves on comfort and greenhouse gas emissions in naturally ventilated offices, and related optimisation potential.

Comparison of the EN 15251 and Ashrae Standard 55 adaptive thermal comfort models in the context of a Mediterranean climate

Strong heat waves in the past decade and resulting legal cases which gave full responsibility for indoor thermal comfort to building professionals lead to an increased uncertainty how to maintain thermal comfort in offices without the use of a cooling system. Adaptive thermal comfort standards such as EN 15251 and Ashrae Standard 55 provide methodologies to evaluate comfort in naturally ventilated spaces. Based on a parametric study for a typical cellular office in the context of Athens, Greece, and using the building simulation software EnergyPlus, this study investigates the potentials for the applicability of natural ventilation in a Mediterranean climate. The Ashrae Standard 55 and EN 15251 adaptive thermal comfort models are compared in this context, and conclusions are drawn how the use of natural ventilation based on adaptive models can be further encourgaged.

Thermal and mechanical properties of ultrasonically treated wool

Wool fabrics, ultrasonically treated in various chemical conditions and for different time durations, were analysed for thermal properties by thermo-gravimetric analysis and differential scanning calorimeter, in comparison with the untreated fabric. Fabric mechanical properties, such as bending and tensile performance, and changes in fibre morphology were also evaluated before and after ultrasonic treatment.It is found that wool treated with ultrasonics at the appropriate time, has less mass loss and a higher thermal degradation temperature than that without ultrasonic treatment or with prolonged ultrasonic treatment. Resistance to thermal degradation is reduced when wool is ultrasonically treated in the presence of alkali. Differential scanning calorimeter analysis shows that while ultrasonic treatment has little effect on fibre crystallinity, an appropriate treatment can provide wool with increased water absorption. Ultrasonic treatment stiffens wool fabric to some extent when the treatment time is prolonged. The addition of detergent alone to the ultrasonic bath has little effect on fabric tensile behaviour, whereas a treatment with both detergent and alkali produces severe fibre damage and significant loss of fabric tensile strength.

The biomedical application of Ti after severe plastic deformation and thermal oxidation, especially the friction and wear properties of Ti

Surface mechanical attrition treatment (SMAT), a novel surface severe plastic deformation method, was carried out for titanium (Ti) to create a gradient-structured Ti (SMAT Ti). The tribological behaviour was studied under different loads and dry sliding conditions. The results showed that the deformation layer of SMAT Ti was about 160 lm. The friction and wear results showed that the wear resistance of SMAT Ti was enhanced compared to the coarse-grained (CG) counterpart. SMAT Ti showed abrasive wear under 1 and 5 N, and exhibited abrasive and adhesive wear under 2 N. While CG Ti showed abrasive and adhesive wear under 1–2 N, and exhibited abrasive wear under 5 N for the work hardening effects.

Designing for thermal comfort near a glazed exterior wall

In many highly glazed buildings, the thermal comfort of the occupants will tend to be related to the incoming solar energy and the heat transfer behaviour of the glazing. In this study, several glazing systems were designed using the software tools VISION 3 (University of Waterloo 1992) and WINDOW-6 (Lawrence Berkeley National Laboratory 2011), with a view to improving thermal environment of occupants near the glazed wall of a commercial office. The systems were fabricated and experimentally tested to validate the software modelling results. Subsequently, the glazing systems were retro-fitted to the office and tested in situ for a summer month. Results of this testing, in the form of Fangers’ predicted mean vote (PMV) and the predicted percentage dissatisfied (PPD), are presented, and some options for improving the thermal environment in this near-façade zone are discussed.

Effect of thermal adaptation on outdoor comfort perception

Thermal comfort in outdoor places has proven to have a strong relationship with their users’ attendance and behaviour [1]. Creating comfortable places is therefore to be considered a crucial part of the design process, as taking it into consideration help increasing the social integration between people and therefore fosters sustainability within cities [2]. With the increasing number of migrants within global cities, a new challenge has been facing thermal comfort studies. This challenge is related to the different cultural and climatic origins of those migrants and how they can adapt to the new climatic conditions they are to move in. This paper aims to explore the impact of thermal comfort adaptation on users’ thermal perception in multicultural cities. Consequently, a quantitative field study is applied in Melbourne city, Australia in order to investigate peoples’ outdoor thermal comfort. The analyses were based upon the measurement of climatic parameters that were monitored simultaneously with a questionnaire to determine users’ thermal comfort perception in relation to their time spent in the city. The findings of thermal comfort investigations could be applied into improving the quality of urban areas within global cities and therefore promote the integration within individuals in those societies.

Phase behaviour and properties of microemulsions and lyotropic liquid crystals

This research study has developed new ways to control bulk properties of self-assembled microemulsions and lyotropic liquid crystals (LLCs) by manipulations of their corresponding precursor phase behaviour. Investigation into relating phase behaviour with the morphology, porosity, thermal stability, rheological property, and photoresponse of these assemblies has been carried out.

The impact of cultural and climatic background on thermal sensation votes

The increasing number of migration and the creation of multicultural cities have generated a new challenge for urban designers. The design of shared, welcoming and well utilised urban open places is important in order to promote inclusion, interaction, belonging, and diversity within cities. Thermal comfort is directly related to the users' attitude and behaviour in outdoor places. Fulfilling the comfort needs for users having a variety of cultural and climatic backgrounds needs therefore to be taken into consideration. Microclimatic parameters strongly affect thermal sensation, however, physical, physiological and psychological adaptation have also proven to have significant influence. The satisfaction with the thermal environment does not only depend on the place, but also on personal variables people bring to that place with them. The paper investigates the role of the culture and climatic background of users' in the complex relationships between microclimate, thermal adaptation factors and human behaviour in open public places. The paper aims to understand the influence of users' cultural and climatic background variations on their thermal needs and usage of the outdoor places. Climatic measurements, surveys and observations were carried out in Federation square in Melbourne along the year to examine thermal comfort and patterns of behaviours of users having different cultural origins. Quantitative analysis is used to examine the influence of culture and climatic background of the users' on thermal sensations and adaptation factors. The findings contribute to guiding the design of outdoor public places in multicultural cities.