A pixel-based approach to estimation of solar energy potential on building roofs

Precise estimation of solar energy on building roofs plays a critical role in sustainable development and renewable energy consumption of high-density human habitats. Conventional solar radiation models based on costly Light Detection and Ranging (LiDAR) data are only adequate for existing buildings, not for future construction areas. In this paper, a pixel-based methodology is constructed for estimating solar energy potential over roofs. Buildings with flat roofs in a newly planned construction area are chosen as a case study. The solar radiation at a certain cell is mathematically formulated in the pixel unit, and its yields over a certain time period are calculated by considering multiple instantaneous solar irradiances and are visually presented by image processing. Significant spatial and temporal variations in solar radiation are measured. Within the study area, the maximum and minimum annual radiation yields are estimated at 4717.72 MJ/m2/year and 342.58 MJ/m2/year respectively. Radiation contour lines are then mapped for outlining installation ranges of various solar devices. For each apartment building, around 20% of roof areas can obtain 4500 MJ/m2/year or more solar radiation yields. This study will benefit energy investors and urban planners in accurately predicting solar radiation potential and identifying regions with high radiation over building roofs. The results can be utilised in government policies and urban planning to raise awareness of the use of renewable energy sources.

Temperature dependence of the electrode potential of a cobalt-based redox couple in ionic liquid electrolytes for thermal energy harvesting

Increasing the application of technologies for harvesting waste heat could make a significant contribution to sustainable energy production. Thermoelectrochemical cells are one such emerging technology, where the thermal response of a redox couple in an electrolyte is used to generate a potential difference across a cell when a temperature gradient exists. The unique physical properties of ionic liquids make them ideal for application as electrolytes in these devices. One of the keys to utilizing these media in efficient thermoelectrochemical cells is achieving high Seebeck coefficients, Se: the thermodynamic quantity that determines the magnitude of the voltage achieved per unit temperature difference. Here, we report the Se and cell performance of a cobalt-based redox couple in a range of different ionic liquids, to investigate the influence of the nature of the IL on the thermodynamics and cell performance of the redox system. The results reported include the highest Se to-date for an IL-based electrolyte. The effect of diluting the different ILs with propylene carbonate is also reported, which results in a significant increase in the output powers and current densities of the device.