A potential anti-corrosive ionic liquid coating for MG alloy AZ31 in simulated body fluids

Magnesium alloys are attractive materials for biomedical applications, due to their excellent biocompatibility. However, these alloys show fast corrosion rates in the body that limits their clinical applications. Low-toxic ionic liquid (IL) trimethyl(butyl)phosphonium diphenyl phosphate P1444dpp has been investigated to provide corrosion protection for magnesium alloy AZ31 in simulated body fluids (SBFs). This work reports a preliminary exploration of the influence of different treatment temperatures on the corrosion protection properties of IL films for the magnesium alloy AZ31 in SBFs. Results show that the IL treatment at room temperature did not bring significant improvement in the corrosion performance of the AZ31 in SBF. However, when the treatment temperature was increased to 75°C, the IL treatment resulted in a substantial reduction of the corrosion, in particular the reduction of localized pitting corrosion. The influence of ionic liquid treatment on the corrosion performance of the magnesium alloys AZ31 in SBFs has been investigated by electrochemical impedance spectroscopy (EIS) tests and immersion tests.

Shear-free perfect fluids with a γ-law equation of state

 We investigate all shear-free perfect fluid solutions of the Einstein field equations where the pressure and energy density satisfy a (Formula presented.)-law equation of state with (Formula presented.). We prove that such a fluid is either non rotating or non expanding. As a consequence, it follows by combining our result with those of Collins and Wainwright that any such shear-free perfect fluid which models either an expand universe or a collapsing star must in fact be a Friedmann–Robertson–Walker spacetime.