Evaluation of electrochemical methods for determination of the seebeck coefficient of redox electrolytes

Recent advances in thermoelectrochemical cells, which are being developed for harvesting low grade waste heat, have shown the promise of cobalt bipyridyl salts as the active redox couple. The Seebeck coefficient, Se, of a redox couple determines the open circuit voltage achievable, for a given temperature gradient, across the thermoelectrochemical cell. Thus, the accurate determination of this thermodynamic parameter is key to the development and study of new redox electrolytes. Further, techniques for accurate determination of Se using only one half of the redox couple reduces the synthetic requirements. Here, we compare three different experimental techniques for measuring Se of a cobalt tris(bipyridyl) redox couple in ionic liquid electrolytes. The use of temperature dependent cyclic voltammetry (CV) in isothermal and non-isothermal cells was investigated in depth, and the Se values compared to those from thermo-electromotive force measurements. Within experimental error, the Se values derived from CV methods were found to be in accordance with those obtained from electromotive force (emf) measurements. The applicability of cyclic voltammetry techniques for determining Se when employing only one part of the redox couple was demonstrated.

A random coefficient approach to the predictability of stock returns in panels

© The Author, 2014. Most studies of the predictability of returns are based on time series data, and whenever panel data are used, the testing is almost always conducted in an unrestricted unit-by-unit fashion, which makes for a very heavy parametrization of the model. On the other hand, the few panel tests that exist are too restrictive in the sense that they are based on homogeneity assumptions that might not be true. As a response to this, the current study proposes new predictability tests in the context of a random coefficient panel data model, in which the null of no predictability corresponds to the joint restriction that the predictive slope has zero mean and variance. The tests are applied to a large panel of stocks listed at the New York Stock Exchange. The results suggest that while the predictive slopes tend to average to zero, in case of book-to-market and cash flow-to-price the variance of the slopes is positive, which we take as evidence of predictability.

Determination of discharge coefficient for flow over one cycle compound trapezoidal plan form labyrinth weir

Weirs are common structure to regulate discharge and flow control inwater conveyance channels and hydraulic structures. Labyrinth weirsconsidered one of economical and effective methods to increase the efficiency of weirs that crest length of weirs increase without a related increase in structure width. Therefore, flow discharge will be increased. Compared to use compound weir, there are some benefits including the simultaneous passage of floating materials such as wood, ice, etc. Also, sedimentations are pass through compound weir. The trapezoidal Labyrinth weir is one of the combined models. In present study 15 physical models that discussion effect changes sidewall angle of labyrinth weir on discharge coefficient of flow over and through the compound trapezoidal one cycle Labyrinth weir. Also, it is developed design curves with various shapes and configurations. The researchshowed here mainly objectives at determining the coefficient of discharge for flow-over trapezoidal labyrinth weir by performing tests at wide range of values of side wall angles (α) from 6° to 35° and compound linear weir to be compared.