Nature of hardness evolution in nanocrystalline NiTi shape memory alloys during solid-state phase transition

Due to a distinct nature of thermomechanical smart materials' reaction to applied loads, a revolutionary approach is needed to measure the hardness and to understand its size effect for pseudoelastic NiTi shape memory alloys (SMAs) during the solid-state phase transition. Spherical hardness is increased with depths during the phase transition in NiTi SMAs. This behaviour is contrary to the decrease in the hardness of NiTi SMAs with depths using sharp tips and the depth-insensitive hardness of traditional metallic alloys using spherical tips. In contrast with the common dislocation theory for the hardness measurement, the nature of NiTi SMAs' hardness is explained by the balance between the interface and the bulk energy of phase transformed SMAs. Contrary to the energy balance in the indentation zone using sharp tips, the interface energy was numerically shown to be less dominant than the bulk energy of the phase transition zone using spherical tips.

Role of surface properties of titanium alloys on osteoblasts response

This thesis examined the behavior of osteoblast cells in response to material surfaces. Cell behavior at the cellular and molecular level on Ti and two Ti alloys (TiZr and TiNb) in response to their material surface properties were evaluated at different stages of cell-material interactions namely adhesion, proliferation and differentiation.

Solidification behaviour and microstructural development of ironbased alloys under conditions pertinent to strip casting - 200 series stainless steels

The castability and microstructures produced from strip casting simulations of three compositions in the 200 series stainless steels have been examined. The nucleation density was similar for all three compositions.The as-cast microstructure showed very fine austenite grains of 10–20 μm in width. Retained delta ferrite was observed in the inter-dendritic regions, and was likely to be stabilised by the segregation of Cr into these regions. An analysis of the crystallography expected of different solidification sequences is presented, but a strict adherence to the Kurdjumov-Sachs orientation relationship was not found in these samples.

Texture selection mechanisms in uniaxially extruded magnesium alloys

Extrusion textures in magnesium alloys are of high interest due to their influence on yield asymmetry. This data supports work describing three mechanisms of texture selection that may play a role during extrusion. These mechanisms involve localized differences in deformation at the grain level, the change in local environment experienced by grain boundary bulges and shear banding. The work employs visco-plastic crystal plasticity and electron backscattering diffraction.

Deformation of magnesium alloys during laboratory scale in-situ x-ray diffraction

In this research work we developed a new laboratory based transmission X-ray diffraction technique to perform in-situ deformation studies on a far more regular basis that is not possible at large scale synchrotron and neutron facilities. We studied the deformation mechanisms in light weight magnesium alloys during in-situ tensile testing.

A double inclusion homogenization scheme for polycrystals with hierarchal topologies: Application to twinning in Mg alloys

The present work introduces a double inclusion elasto-plastic self-consistent (DI-EPSC) scheme for topologies in which crystals can contain subdomains (i.e. twins, etc.). The approach yields a direct coupling between the mechanical response of grains and their subdomains via a concentration relationship on mean fields derived from both the Eshelby and the Tanaka-Mori properties. The latent effect caused by twinning on the mechanical response is observed on both initially extruded and non-textured Mg alloys. For twinned grains, it is shown that deformation system activities and plastic strain distributions within twins drastically depend on the interaction with parent domains. Moreover, a quantitative study on the coupled influence of secondary slip activities on the material response is proposed. © 2014 Published by Elsevier Ltd.

Effect of alloying and extrusion temperature on the microstructure and mechanical properties of Mg-Zn and Mg-Zn-RE alloys

Extruded Mg-Zn-RE alloys have been shown to exhibit excellent combinations of yield strength and ductility, but it is not completely clear how adding rare earth metals to Mg-Zn alters the microstructure and affects the mechanical properties. Microstructural changes and the resulting mechanical properties from changes in composition and extrusion temperature have been investigated for Mg-. x Zn-. y RE (. x=2.5 and 5. wt.%, y=0 and 1. wt. %, and RE=Gd and Y) alloys. Adding RE to Mg-Zn increased the strength and reduced the ductility, while increasing the zinc concentration in the Mg-Zn-RE alloys had the reverse effect.