Extensional rheology and stability of gas cell walls in bread doughs at elevated temperatures in relation to breadmaking performance

The rheological properties of gas cell walls in bread doughs are considered to be important in relation to their stability and gas retention during proof and baking. Large deformation rheological properties of gas cell walls were measured using biaxial extension for a number of doughs of varying breadmaking quality at constant strain rate and elevated temperatures of 25-60degreesC. Strain hardening and failure strain of cell walls both decreased with temperature, with cell walls in good breadmaking doughs remaining stable and retaining their strain hardening properties at higher temperatures (60degreesC), while the cell walls of poor breadmaking doughs became unstable at lower temperatures (45-50degreesC) and had lower strain hardening. Strain hardening measured at 50degreesC gave good correlations with baking volume, with the best correlations achieved between rheological measurements and baking tests that used similar mixing conditions. As predicted by the considered failure criterion, a strain hardening value of I defines a region below which gas cell walls become unstable, and discriminates well between the baking quality of a range of commercial flour blends of varying quality. This indicates that the stability of gas cell walls during baking is strongly related to strain hardening properties, and that extensional rheological measurements can be used as indicators of baking quality.

The reaction between silylene and ammonia: some gas-phase kinetic and quantum chemical studies

Time-resolved kinetic studies of the reaction of silylene, SiH2, generated by 193 nm laser flash photolysis of silacyclopent-3-ene, have been carried out in the presence of ammonia, NH3. Second order kinetics were observed. The reaction was studied in the gas phase at 10 Torr total pressure in SF6 bath gas at each of the three temperatures, 299, 340 and 400 K. The second order rate constants (laser pulse energy of 60 mJ/pulse) fitted the Arrhenius equation: log(k/cm3 molecule-1 s-1) = (-10.37 ± 0.17) + (0.36 ± 1.12 kJ mol-1)/RTln10 Experiments at other pressures showed that these rate constants were unaffected by pressure in the range 10-100 Torr, but showed small decreases in value at 3 and 1 Torr. There was also a weak intensity dependence, with rate constants decreasing at laser pulse energies of 30 mJ/pulse. Ab initio calculations at the G3 level of theory, show that SiH2 + NH3 should form an initial adduct (donor-acceptor complex), but that energy barriers are too great for further reaction of the adduct. This implies that SiH2 + NH3 should be a pressure dependent association reaction. The experimental data are inconsistent with this and we conclude that SiH2 decays are better explained by reaction of SiH2 with the amino radical, NH2, formed by photodissociation of NH3 at 193 nm. The mechanism of this previously unstudied reaction is discussed.

The effects of maize planting density and weeding regimes on light and water use

Light and water are among essential resources required for production of photosynthates in plants. A study on the effects of weeding regimes and maize planting density on light and water use was conducted during the 2001/2 short and 2002 long rain seasons at Muguga in - the central highlands of Kenya. Weeding regimes were: weed free (W1), weedy (W2), herbicide (W3) and hand weeding twice (W4). Maize planting densities were 9 (D1) and 18 plants m-2 (D2) intercropped with Phaseolus vulgaris (beans). The experiment was laid as randomized complete block design replicated four times and repeated twice. All plots were thinned to 4 plants m-2 at tasseling stage (96 DAE) and thinnings quantified as forage. Soil moisture content (SMC), photosynthetically active radiation (PAR) interception, evapo-transpiration (ET crop), water use efficiency (WUE), and harvest index (HI), were determined. Percent PAR was higher in D2 than in D1 before thinning but higher in D1 than in D2 after thinning in both seasons. PAR interception was highest in W2 but similar in W1, W3 and W4 in both seasons. SMC was significantly lower in W2 but similar in W1, W3 and W4. D2 had lower SMC than D1 in season two. Weeding regime significantly influenced ET crop, while planting density and weeding regime significantly influenced WUE and HI. D2 maximizes water and light use for forage production but results to increased intra-specific plant competition for water and light severely before thinning (96 DAE) that reduce grain yield in dual purpose maize, relative to D1.