Statistical evidences of cyclic changes in volcanic gas chemistry composition by inverse modelling

The identification of compositional changes in fumarolic gases of active and quiescent volcanoes is one of the most important targets in monitoring programs. From a general point of view, many systematic (often cyclic) and random processes control the chemistry of gas discharges, making difficult to produce a convincing mathematical-statistical modelling. Changes in the chemical composition of volcanic gases sampled at Vulcano Island (Aeolian Arc, Sicily, Italy) from eight different fumaroles located in the northern sector of the summit crater (La Fossa) have been analysed by considering their dependence from time in the period 2000-2007. Each intermediate chemical composition has been considered as potentially derived from the contribution of the two temporal extremes represented by the 2000 and 2007 samples, respectively, by using inverse modelling methodologies for compositional data. Data pertaining to fumaroles F5 and F27, located on the rim and in the inner part of La Fossa crater, respectively, have been used to achieve the proposed aim. The statistical approach has allowed us to highlight the presence of random and not random fluctuations, features useful to understand how the volcanic system works, opening new perspectives in sampling strategies and in the evaluation of the natural risk related to a quiescent volcano

I Riflessi letterari dell’Unità d’Italia nella narrativa siciliana

El treball d'investigació té per objecte oferir un inventari raonat de novel•les i contes curts d’autors sicilians d’entre 1860 i 1898, de Giovanni Verga a la Simonetta Agnello Hornby, diferents en edat, cultura i condició social. Vol fer evident la persistència de la reflexió sobre el Risorgimento "traït", i ajudar a comprendre com hi havia un marc d’unitat política i institucional en el què no es donava cabuda a les diferències entre el Nord i el Sud d’Itàlia

Selenium cycling in volcanic environments: the role of soils as reactive interfaces

Selenium (Se) is an element with important health implications that is emitted in significant amounts from volcanoes. Attracted by the fertility of volcanic soils, around 10% of the world population lives within 100 km of an active volcano. Nevertheless, the behaviour of Se in volcanic environments is poorly understood. Therefore, the main aim of this thesis is to investigate the role of soils in the Se cycling in volcanic environments. Prior to the geochemical studies, precise and accurate methods for the determination of Se contents, speciation and isotopic signatures were developed. Afterwards, a combination of field studies and lab controlled experiments were performed with soils from two contrasting European volcanic settings: Mount Etna in Sicily (Italy) and Mount Teide in Tenerife (Spain). The results showed a strong link between Se behaviour and soil development, indicating that Se mobility in volcanic soils is controlled by sorption processes and soil mineralogy.

Caterina Llull i Çabastida: una mercantessa catalana nella Sicilia del '400

El trabajo se asienta sobre en el estudio y la edición de un libro de contabilidad del siglo XV Libre de la magnifica señora Caterina Llull començat el 2 de jener de 1472 compilado por una mujer catalana Caterina Llull y Çabastida que vivió entre Siracusa y Barcelona y que se conserva en el Archivo del Centro Borja de S. Cugat del Vallès dentro del fondo archivístico privado de la familia Requesens. La investigación de la fuente mencionada se ha completado con otros documentos del mismo archivo familiar y con la documentación de otros archivos catalanes permitiendome, además, profundizar en algunos aspectos económicos y sociales de la Sicilia oriental del siglo XV, y llevar a cabo un análisis más amplio de las características y de los diferentes aspectos del así llamado "Medioevo en femenino". La tesis està dividida en tres partes: estudio paleografico-codocologico, socio-economico y transcripciòn completa del manuscrito con indice onomàstico.