Gestor de contenidos del geoportal de la IDE del Calbildo Insular de la Palma

Dos de los problemas más comunes presentes en las Administraciones que gestionan Información Territorial a través de una IDE, son la dificultad de que los técnicos para gestionar y actualizar la información, y la dependencia tecnológica de terceros. Parte del problema de la actualización y gestión de la información lo hemos solucionado con el desarrollo de un Gestor de Contenidos del Geoportal y de los servicios WMS, que se liberará como software libre. El Gestor funciona a través de una navegador web estándar donde el usuario, tras validarse, accede a la configuración y publicación de servicios que le permite entre otras: crear nuevos WMS, gestionar los WMS existentes, gestionar las capas del Geoportal, generar leyendas, gestionar usuarios, etc. De este modo, un usuario no técnico y sin conocimientos avanzados de geomática puede publicar capas como servicios WMS sin dificultad

Síntesi, caracterització i avaluació com a catalitzadors de nous complexos quirals de platí

The oxidative addition proved to be a useful method to prepare platinum (II) hydridotiolate by reaction of tetrakis(triphenylphosphine)platinum(0) with aminothiolate and phosphinothiolate ligands like cysteamine, cysteine ethyl and methyl Esther, 2-(diphenylphosphino)ethanetiol and 2-(diphenylphosphino)propanetiol. The complexes are square-planar and the aminothiolate or phosphinothiolate ligands are chelated to platinum (II). The hydrido ligand is trans to the sulfur and the other coordination position is occuped by a triphenylphosphine ligand. The complexes are mononuclear and they show low symmetry. The only symmetry element, the plan is broke if the ligand is branched, obtaining asymmetric complexes C1. If the ligand has electronic or esteric impediments the reaction doesn't run and the starting products are recovered. This was observed with N,N-dimethylcysteamine and penicylamine methyl esther ligands. In the special case of orthoaminotiophenol the hydridotiolate was obtained but the ligand was not chelated. The aminothiolate complexes don't show solution equilibrium. Otherwise, the complexe with 2-(diphenylphosphino)ethanetiol show an isomerisation equilibrium which forms cis isomer as a minor component. The complexe with 2-(diphenylphosphino)-propanetiol shows a conformational equilibrium between chair and twist forms. The complexes have been tested as catalyst precursors in hydroformylation and hydrosilylation reactions. The hydroformylation reaction runs only in presence of SnCl2 as cocatalyst. Catalytic activity depends on the presence of triphenylphosphine and, with less magnitude, CO and H2 pressure. We also studied the enantioselectivity using a chiral complexe. In the hydrosililation reaction, catalysts run with good results (<90%) using triethylsilane as silicon hydride. Dehydrogenative addition product has been also found in this reaction.