Studies in stoichiometry with compositional data

Geochemical data that is derived from the whole or partial analysis of various geologic materials represent a composition of mineralogies or solute species. Minerals are composed of structured relationships between cations and anions which, through atomic and molecular forces, keep the elements bound in specific configurations. The chemical compositions of minerals have specific relationships that are governed by these molecular controls. In the case of olivine, there is a well-defined relationship between Mn-Fe-Mg with Si. Balances between the principal elements defining olivine composition and other significant constituents in the composition (Al, Ti) have been defined, resulting in a near-linear relationship between the logarithmic relative proportion of Si versus (MgMnFe) and Mg versus (MnFe), which is typically described but poorly illustrated in the simplex. The present contribution corresponds to ongoing research, which attempts to relate stoichiometry and geochemical data using compositional geometry. We describe here the approach by which stoichiometric relationships based on mineralogical constraints can be accounted for in the space of simplicial coordinates using olivines as an example. Further examples for other mineral types (plagioclases and more complex minerals such as clays) are needed. Issues that remain to be dealt with include the reduction of a bulk chemical composition of a rock comprised of several minerals from which appropriate balances can be used to describe the composition in a realistic mineralogical framework. The overall objective of our research is to answer the question: In the cases where the mineralogy is unknown, are there suitable proxies that can be substituted? Kew words: Aitchison geometry, balances, mineral composition, oxides

Métodos de reconocimiento del subsuelo

The aim of this workshop is to present the main methods of subsoil studies (namely mechanical and geophysical methods) to the Earth Sciences professorate. These methods frequently involve the use of specific material. The different methods are usually taught in the classroom where there is no real contact between the students and the equipment. Several activities, all of them taking place in surrounding areas of the university campus of Girona, will provide the assistants to the workshop with the opportunity of making measurements with different equipment. These activities will be made in the field so as to contribute to the resolution of a problem which will have been previously proposed. The problems presented are situations, most of them real, when subsoil investigation techniques are usually used. These cases have been employed as teaching-learning strategies with university and second grade students in the area of Girona. Finally, some examples of exercises involving the treatment of data obtained through subsoil investigation techniques are also presented to complement the workshop

Investigación geofísica de los paleovalles pleistocenos del NE de Cataluña: el ejemplo de la Riera de Tossa (Costa Brava meridional)

The geometry of Riera de Tossa (Costa Brava, Catalonia) Pleistocene paleovalley has been studied by two geophysical prospecting methods: vertical electric sounding (VES-DC) and seismic refraction. The results show the existence of a sudden slope change of the thalweg that permits to differentiate two sections where erosion processes operated in unequal intensity. Based on geological and geomorphological available data, it can be inferred that this slope rupture is caused by the litological control imposed by the alineation of resistant materials, which limited the headward erosion extend of the creek during the Upper Pleistocene