Unusual surface and edge morphologies, sp2 to sp3 hybridized transformation and electronic damage after Ar+ ion irradiation of few-layer graphene surfaces

Roughness and defects induced on few-layer graphene (FLG) irradiated by Ar+ ions at different energies were investigated using X-ray photoemission spectroscopy (XPS) and atomic force microscopy techniques. The results provide direct experimental evidence of ripple formation, sp2 to sp3 hybridized carbon transformation, electronic damage, Ar+ implantation, unusual defects and edge reconstructions in FLG, which depend on the irradiation energy. In addition, shadowing effects similar to those found in oblique-angle growth of thin films were seen. Reliable quantification of the transition from the sp2-bonding to sp3-hybridized state as a result of Ar+ ion irradiation is achieved from the deconvolution of the XPS C (1s) peak. Although the ion irradiation effect is demonstrated through the shape of the derivative of the Auger transition C KVV spectra, we show that the D parameter values obtained from these spectra which are normally used in the literature fail to account for the sp2 to sp3 hybridization transition. In contrast to what is known, it is revealed that using ion irradiation at large FLG sample tilt angles can lead to edge reconstructions. Furthermore, FLG irradiation by low energy of 0.25 keV can be a plausible way of peeling graphene layers without the need of Joule heating reported previously

The Edge C4 Graph of a Graph

Abstract. The edge C4 graph E4(G) of a graph G has all the edges of Gas its vertices, two vertices in E4(G) are adjacent if their corresponding edges in G are either incident or are opposite edges of some C4. In this paper, characterizations for E4(G) being connected, complete, bipartite, tree etc are given. We have also proved that E4(G) has no forbidden subgraph characterization. Some dynamical behaviour such as convergence, mortality and touching number are also studied

Design of an Edge -coupled dual -ring Split-ring resonator

Electric permittivity and magnetic permeability control electromagnetic wave propagation th rough materials. I n naturally occu rring materials, these are positive. Artificial materials exhi b iting negative material properties have been reported : they are referred to as metamaterials. This paper concentrates on a ring-type split-ring resonator (SRR) exhibiting negative magnetic permeability. The design and synthesis of the SRR using the genetic-algorithm approach is explained in detail. A user-friendly g raphical user i nterface (G U I ) for an SRR optim izer and estimator using MATLAB TM is also presented