Copper(II) complexes of embelin and 2-aminobenzimidazole encapsulated in zeolite Y-potential as catalysts

Copper(II) complexes of two biologically important ligands, viz., embelin (2,5-dihydroxy-3-undecyl-2,5-cyclohexadien 1,4-dione) and 2-aminobenzimidazole were entrapped in the cages of zeolite Y by the flexible ligand method. The capability of these compounds in catalyzing the reduction of oxygen (industrially known as deoxo reaction) was explored and the results indicate an enhancement of the catalytic properties from that of the simple copper ion exchanged zeolite. These point to the ability of the ligands in enhancing the oxygen binding capability of the metal ion. Elemental analyses, Fourier transform infrared (FTIR), diffuse reflectance and EPR spectral studies, magnetic susceptibility measurements, TG, surface area analyses and powder X-ray diffraction studies were used in understanding the presence, composition and structure of the complexes inside the cages. The study also reveals the increased thermal and mechanical stability of the complexes as a result of encapsulation.

An agroclimatic assessment of the crop growth potential of south india

Usually, under rainfed conditions the growing period exists in the humid months. Hence, for agricultural planning knowledge about the variabilities of the duration of the humid seasons are very much needed. The crucial problem affecting agriculture is the persistency in receiving a specific amount of rainfall during a short period. Agricultural operations and decision making are highly dependent on the probability of receiving given amounts of rainfall; such periods should match the water requirements of different phenological phases of the crops. While prolonged dry periods during sensitive phases are detrimental to their growth and lower the yields, excess of rainfall causes soil erosion and loss of soil nutrients. These factors point to the importance of evaluation of wet and dry spells. In this study the weekly rainfall data have been analysed to estimate the probability of wet and dry periods at all selected stations of each agroclimatic zone and the crop growth potentials of the growing seasons have been analysed. The thesis consists of six Chapters.