Singlet Oxygen in Microporous Silica Xerogel:Quantum Yield and Oxidation at the Gas–Solid Interface

The quantum yields of singlet oxygen production and lifetimes at the gas–solid interface in silica gel material are determined. Different photosensitizers (PS) are encapsulated in parallelepipedic xerogel monoliths (PS-SG). PS were chosen according to their known photooxidation properties: 9,10-dicyanoanthracene (DCA), 9,10-anthraquinone (ANT), and a benzophenone derivative, 4-benzoyl benzoic acid (4BB). These experiments are mainly based on time-resolved 1O2 phosphorescence detection, and the obtained FD and tD values are compared with those of a reference sensitizer for production, 1H-phenalen-1- one (PN), included in the same xerogel. The trend between their ability to oxidize organic pollutants in the gas phase and their efficiency for production is investigated through photooxidation experiments of a test pollutant dimethylsulfide (DMS). The FD value is high for DCA-SG relative to the PN reference, whereas it is slightly lower for 4BB-SG and for ANT-SG. FD is related to the production of sulfoxide and sulfone as the main oxidation products for DMS photosensitized oxidation. Additional mechanisms, leading to C!S bond cleaveage, appear to mainly occur for the less efficient singlet oxygen sensitizers 4BB-SG and ANTSG.

Investigations on the Dynamics of Combination Maps and the Analysis of Bifurcation in a Discontinuous Logistic Map

This thesis is a study of discrete nonlinear systems represented by one dimensional mappings.As one dimensional interative maps represent Poincarre sections of higher dimensional flows,they offer a convenient means to understand the dynamical evolution of many physical systems.It highlighting the basic ideas of deterministic chaos.Qualitative and quantitative measures for the detection and characterization of chaos in nonlinear systems are discussed.Some simple mathematical models exhibiting chaos are presented.The bifurcation scenario and the possible routes to chaos are explained.It present the results of the numerical computational of the Lyapunov exponents (λ) of one dimensional maps.This thesis focuses on the results obtained by our investigations on combinations maps,scaling behaviour of the Lyapunov characteristic exponents of one dimensional maps and the nature of bifurcations in a discontinous logistic map.It gives a review of the major routes to chaos in dissipative systems,namely, Period-doubling ,Intermittency and Crises.This study gives a theoretical understanding of the route to chaos in discontinous systems.A detailed analysis of the dynamics of a discontinous logistic map is carried out, both analytically and numerically ,to understand the route it follows to chaos.The present analysis deals only with the case of the discontinuity parameter applied to the right half of the interval of mapping.A detailed analysis for the n –furcations of various periodicities can be made and a more general theory for the map with discontinuities applied at different positions can be on a similar footing

Existence of multiple attractors and the nature of bifurcations in a discontinuous logistic map

We present the analytical investigations on a logistic map with a discontinuity at the centre. An explanation for the bifurcation phenomenon in discontinuous systems is presented. We establish that whenever the elements of an n-cycle (n > 1) approach the discontinuities of the nth iterate of the map, a bifurcation other than the usual period-doubling one takes place. The periods of the cycles decrease in an arithmetic progression, as the control parameter is varied. The system also shows the presence of multiple attractors. Our results are verified by numerical experiments as well.

Stability of periodic orbits of coupled-map lattices

We consider the stability properties of spatial and temporal periodic orbits of one-dimensional coupled-map lattices. The stability matrices for them are of the block-circulant form. This helps us to reduce the problem of stability of spatially periodic orbits to the smaller orbits corresponding to the building blocks of spatial periodicity, enabling us to obtain the conditions for stability in terms of those for smaller orbits.

Dynamics of the logistic map under discrete parametric perturbation

By introducing a periodic perturbation in the control parameter of the logistic map we have investigated the period locking properties of the map. The map then gets locked onto the periodicity of the perturbation for a wide range of values of the parameter and hence can lead to a control of the chaotic regime. This parametrically perturbed map exhibits many other interesting features like the presence of bubble structures, repeated reappearance of periodic cycles beyond the chaotic regime, dependence of the escape parameter on the seed value and also on the initial phase of the perturbation etc.

Bifurcation structure and Lyapunov exponents of a modulated logistic map

We have studied the bifurcation structure of the logistic map with a time dependant control parameter. By introducing a specific nonlinear variation for the parameter, we show that the bifurcation structure is modified qualitatively as well as quantitatively from the first bifurcation onwards. We have also computed the two Lyapunov exponents of the system and find that the modulated logistic map is less chaotic compared to the logistic map.

An analogue of the logistic map in two dimensions

This is a sequel to our earlier work on the modulated logistic map. Here, we first show that the map comes under the universality class of Feigenbaum. We then give evidence for the fact that our model can generate strange attractors in the unit square for an uncountable number of parameter values in the range μ∞<μ<1. Numerical plots of the attractor for several values of μ are given and the self-similar structure is explicity shown in one case. The fractal and information dimensions of the attractors for many values of μ are shown to be greater than one and the variation in their structure is analysed using the two Lyapunov exponents of the system. Our results suggest that the map can be considered as an analogue of the logistic map in two dimensions and may be useful in describing certain higher dimensional chaotic phenomena.

Evidence for the existence of Sarkovskii ordering in a two-dimensional map

We analyse numerically the bifurcation structure of a two-dimensional noninvertible map and show that different periodic cycles are arranged in it exactly in the same order as in the case of the logistic map. We also show that this map satisfies the general criteria for the existence of Sarkovskii ordering, which supports our numerical result. Incidently, this is the first report of the existence of Sarkovskii ordering in a two-dimensional map.

Universal behaviour in a ``modulated'' logistic map

We study the period-doubling bifurcations to chaos in a logistic map with a nonlinearly modulated parameter and show that the bifurcation structure is modified significantly. Using the renormalisation method due to Derrida et al. we establish the universal behaviour of the system at the onset of chaos.

Influence of Interface Surface Geometries In The Tensile Characteristics Of Friction Welded Joints From Aluminium Alloys

Friction welding is a solid state joining process that produces coalescence in materials, using the heat developed between surfaces through a combination of mechanical induced rubbing motion and applied load. In rotary friction welding technique heat is generated by the conversion of mechanical energy into thermal energy at the interface of the work pieces during rotation under pressure. Traditionally friction welding is carried out on a dedicated machine because of its adaptability to mass production. In the present work, steps were made to modify a conventional lathe to rotary friction welding set up to obtain friction welding with different interface surface geometries at two different speeds and to carry out tensile characteristic studies. The surface geometries welded include flat-flat, flat-tapered, tapered-tapered, concave-convex and convex-convex. A comparison of maximum load, breaking load and percentage elongation of different welded geometries has been realized through this project. The maximum load and breaking load were found to be highest for weld formed between rotating flat and stationary tapered at 500RPM and the values were 19.219kN and 14.28 kN respectively. The percentage elongation was found to be highest for weld formed between rotating flat and stationary flat at 500RPM and the value was 21.4%. Hence from the studies it is cleared that process parameter like “interfacing surface geometries” of weld specimens have strong influence on tensile characteristics of friction welded joints