Photothermal beam deflection for non-destructive evaluation of semiconductor thin films

Non-destructive testing (NDT) is the use of non-invasive techniques to determine the integrity of a material, component, or structure. Engineers and scientists use NDT in a variety of applications, including medical imaging, materials analysis, and process control.Photothermal beam deflection technique is one of the most promising NDT technologies. Tremendous R&D effort has been made for improving the efficiency and simplicity of this technique. It is a popular technique because it can probe surfaces irrespective of the size of the sample and its surroundings. This technique has been used to characterize several semiconductor materials, because of its non-destructive and non-contact evaluation strategy. Its application further extends to analysis of wide variety of materials. Instrumentation of a NDT technique is very crucial for any material analysis. Chapter two explores the various excitation sources, source modulation techniques, detection and signal processing schemes currently practised. The features of the experimental arrangement including the steps for alignment, automation, data acquisition and data analysis are explained giving due importance to details.Theoretical studies form the backbone of photothermal techniques. The outcome of a theoretical work is the foundation of an application.The reliability of the theoretical model developed and used is proven from the studies done on crystalline.The technique is applied for analysis of transport properties such as thermal diffusivity, mobility, surface recombination velocity and minority carrier life time of the material and thermal imaging of solar cell absorber layer materials like CuInS2, CuInSe2 and SnS thin films.analysis of In2S3 thin films, which are used as buffer layer material in solar cells. The various influences of film composition, chlorine and silver incorporation in this material is brought out from the measurement of transport properties and analysis of sub band gap levels.The application of photothermal deflection technique for characterization of solar cells is a relatively new area that requires considerable attention.The application of photothermal deflection technique for characterization of solar cells is a relatively new area that requires considerable attention. Chapter six thus elucidates the theoretical aspects of application of photothermal techniques for solar cell analysis. The experimental design and method for determination of solar cell efficiency, optimum load resistance and series resistance with results from the analysis of CuInS2/In2S3 based solar cell forms the skeleton of this chapter.

Effect of silver nano particles on the fluorescence quantum yield of Rhodamine 6G determined using dual beam thermal lens method

Nano structured noble metals have very important applications in diverse fields as photovoltaics, catalysis, electronic and magnetic devices, etc. Here, we report the application of dual beam thermal lens technique for the determination of the effect of silver sol on the absolute fluorescence quantum yield (FQY) of the laser dye rhodamine 6G. A 532 nm radiation from a diode pumped solid state laser was used as the excitation source. It has been observed that the presence of silver sol decreases the fluorescence quantum efficiency. This is expected to have a very important consequence in enhancing Raman scattering which is an important spectrochemical tool that provides information on molecular structures. We have also observed that the presence of silver sol can enhance the thermal lens signal which makes the detection of the signal easier at any concentration.

Corrugated flange technique for beam shaping of sectoral electromagnetic horn antennas

The need for improved feed systems for large reflector antennas employed in Radio Astronomy and Satellite tracking spurred the interest in horn antenna research in the 1960's. The major requirements were to reduce spill over, cross-polarisation losses,and to enhance the aperture efficiency to the order of about 75-8O%L The search for such a feed culminated in the corrugated horn. The corrugat1e 1 horn triggered widespread interest and enthusiasm, and a large amount of work(32’34’49’5O’52’53’58’65’75’79)has already been done on this type of antennas. The properties of corrugated surfaces has been investigated in detail. It was strongly felt that the flange technique and the use of corrugated surfaces could be merged together to obtain the advantages of both. This is the idea behind the present work. Corrugations are made on the surface of flange elements. The effect of various corrugation parameters are studied. By varying the flange parameters, a good amount of data is collected and analysed to ascertain the effects of corrugated flanges. The measurements are repeated at various frequencies, in the X— and S-bands. The following parameters of the system were studied: (a) beam shaping (b) gain (c) variation of V.S.U.R. (d) possibility of obtaining circularly polarised radiation from the flanged horn. A theoretical explanation to the effects of corrugated flanges is attempted on the basis of the line-source theory. Even though this theory utilises a simplified model for the calculation of radiation patterns, fairly good agreement between the computed pattern and experimental results are observed.