Thermohaline variability in the upper layers of the Arabian Sea

The Arabian Sea is an area of complex air-sea interaction processes with seasonal reversing monsoons. The associated thermohaline variability in the upper layers appears to control the large scale monsoon flow which is not yet completely understood. The variability in the thermohaline fields is known to occur in temporal domain ranging from intra-diurnal to inter-annual time scales and on spatial domains of few tens of kilometers to few thousands of kilometers. In the Arabian Sea though the surface temperature was routinely measured by both conventional measurements and satellites, the corresponding information on the subsurface thermohaline field is very sparse due to the lack cw adequate measurements. In such cases the numerical models offer promise in providing information on the subsurface features given an initial thermohaline field and surface heat flux boundary conditions. This thesis is an outcome of investigations carried out on the various aspects of the thermohaline variability on different time scales. In addition to the description of the mean annual cycle. the one dimensional numerical models of Miller (1976) and Price et a1 (1986) are utilised to simulate the observed mixed layer characteristics at selected locations in the Arabian Sea on time scales ranging from intra-diurnal to synoptic scales under variable atmospheric forcing.

POST-MONSOON SEA SURFACE TEMPERATURE AND CONVECTION ANOMALIES OVER INDIAN AND PACIFIC OCEANS

We have studied sea surface temperature (SST) anomalies over the Indian and Pacific Oceans (domain 25 °S to 25°N and 40 °E to 160 °W) during the three seasons following the Indian summer monsoon for wet monsoons and also for dry monsoons accompanied or not by El Ni˜no. A dry monsoon is followed by positive SST anomalies in the longitude belt 40 to 120 °E, negative anomalies in 120 to 160 °E and again positive anomalies east of 160 °E. In dry monsoons accompanied by El Ni˜no the anomalies have the same sign, but are much stronger. Wet monsoons have weak anomalies of opposite sign in all three of the longitude belts. Thus El Ni˜no and a dry monsoon have the same types of association with the Indian and Pacific Ocean SSTs. In the sector 40 to 120 °E SST anomalies first appear over the western part of the Indian Ocean (June to September) followed by the same sign of anomalies over its eastern part and China Sea (October to March). By March after a dry monsoon or El Ni˜no the Indian Ocean between 10 °N and 10 °S has a spatially large warm SST anomaly. Anomalies in deep convection tend to follow the SST anomalies, with warm SST anomalies producing positive convection anomalies around the seasonal location of the intertropical convergence zone

Diurnal Structure of Monsoon Boundary Layer

The characteristics of the monsoon boundary layer are imperative to understand in the perception of the tropical regions. The southwest monsoon is associated with a strong wind in the lower troposphere near 1.5 km and is referred to as Low Level Jet stream (LLJ). The boundary layer structure associated with the LLJ during monsoon can be studied using L-band Ultra High Frequency (UHF) radar. This L-band wind profiler-commonly referred as lower atmospheric wind profiler (LAWP), was installed at NARL, Gadanki. Zonal, meridional and vertical wind components are used to understand the diurnal variation of the wind in the Atmospheric Boundary Layer (ABL) and associated features. From the analysis during non rainy days of the southwest monsoon, it is found that the LLJ has maximum strength during the early morning hours at lower level and the height increases as day progresses. The vertical wind shows the transfer of momentum from the LLJ towards the surface, indicating the sinking motion during the daytime. Vertical gradient of the wind shear shows the intensity of clear air turbulence is moderate and no severe clear air turbulence is noticed during the monsoon period

Low temperature Mössbauer studies on magnetic nanocomposites

Nanocomposites with magnetic components possessing nanometric dimensions, lying in the range 1–10 nm, are found to be exhibiting superior physical properties with respect to their coarser sized counterparts. Magnetic nanocomposites based on gamma iron oxide embedded in a polymer matrix have been prepared and characterized. The behaviour of these samples at low temperatures have been studied using Mössbauer spectroscopy. Mössbauer studies indicate that the composites consist of very fine particles of g-Fe2O3 of which some amount exists in the superparamagnetic phase. The cycling of the preparative conditions were found to increase the amount of g-Fe2O3 in the matrix

Near fifty percent sodium substituted lanthanum manganites—A potential magnetic refrigerant for room temperature applications

Nearly half of lanthanum sites in lanthanum manganites were substituted with monovalent ion-sodium and the compound possessed distorted orthorhombic structure. Ferromagnetic ordering at 300K and the magnetic isotherms at different temperature ranges were analyzed for estimating magnetic entropy variation. Magnetic entropy change of 1.5 J kg 1 K 1 was observed near 300 K. An appreciable magnetocaloric effect was also observed for a wide range of temperatures near 300K for small magnetic field variation. Heat capacity was measured for temperatures lower than 300K and the adiabatic temperature change increases with increase in temperature with a maximum of 0.62K at 280 K

Temperature dependent polarized Raman spectra of nonaaqualanthanoid (Pr) single crystal

Polarized Raman spectral changes with respect to temperature were investigated for Pr(BrO3)3·9H2O single crystals. FTIR spectra of hydrated and deuterated analogues were also recorded and analysed. Temperature dependent Raman spectral variation have been explained with the help of the thermograms recorded for the crystal. Factor group analysis could propose the appearance ofBrO3 ions at sites corresponding to C3v (4) and D3h (2). Analysis of the vibrational bands at room temperature confirms a distorted C3v symmetry for the BrO3 ion in the crystal. From the vibrations of water molecules, hydrogen bonds of varying strengths have also been identified in the crystal. The appearance υ1 mode of BrO3− anion at lower wavenumber region is attributed to the attachment of hydrogen atoms to the BrO3− anion. At high temperatures, structural rearrangement is taking place for bothH2Omolecule and BrO3 ions leading to the loss ofwater molecules and structural reorientation of bromate ions causing phase transition of the crystal at the temperature of 447 K.

Mn2þ-induced room-temperature ferromagnetism and spin-glass behavior in hydrothermally grown Mn-doped ZnO nanorods

The magnetic properties of Mn-doped ZnO (ZnO:Mn) nanorods grown by hydrothermal process at a temperature of 200 8C and a growth time of 3 h have been studied. The samples were characterized by using powder X-ray diffraction with Rietveld refinement, scanning electron microscopy, energy-dispersive X-ray analysis and SQUID magnetometry. Mn (3 wt%) and (5 wt%)-doped ZnO samples exhibit paramagnetic and ferromagnetic behavior, respectively, at room temperature. The spin-glass behavior is observed from the samples with respect to the decrease of temperature. At 10 K, both samples exhibit a hysteresis loop with relatively low coercivity. The room-temperature ferromagnetism in 5 wt% Mn-doped ZnO nanorods is attributed to the increase in the specific area of grain boundaries, interaction between dopant Mn2þ ions substituted at Zn2þ site and the interaction between Mn2þ ions and Zn2þ ions from the ZnO host lattice

Biochemical effects of cadmium, salinity and temperature on the catabolism of proteins and purines in oreochromis mossambicus (Peters)

In the present investigation, three important stressors: cadmium ion (Cd++), salinity and temperature were selected to study their effects on protein and purine catabolism of O. mossambicus. Cadmium (Cd) is a biologically nonessential metal that can be toxic to aquatic animals. Cadmium is a trace element which is a common constituent of industrial effluents. It is a non-nutrient metal and toxic to fish even at low concentrations. Cadmium ions accumulate in sensitive organs like gills, liver, and kidney of fish in an unregulated manner . Thus; the toxic effects of cadmium are related to changes in natural physiological and biochemical processes in organism. The mechanics of osmoregulation (i.e. total solute and water regulation) are reasonably well understood (Evans, 1984, 1993), and most researchers agree that salinities that differ from the internal osmotic concentration of the fish must impose energetic regulatory costs for active ion transport. There is limited information on protein and purine catabolism of euryhaline fish during salinity adaptation. Within a range of non-lethal temperatures, fishes are generally able to cope with gradual temperature changes that are common in natural systems. However, rapid increases or decreases in ambient temperature may result in sub lethal physiological and behavioral responses. The catabolic pathways of proteins and purines are important biochemical processes. The results obtained signifies that O. mossambicus when exposed to different levels of cadmium ion, salinity and temperature show great variation in the catabolism of proteins and purines. The organism is trying to attain homeostasis in the presence of stressors by increasing or decreasing the activity of certain enzymes. The present study revealed that the protein and purine catabolism in O. mossambicus is sensitive to environmental stressors.