Rotation-electronic interaction in the 3p-complex Rydberg state of water

An energy theory is formulated for the rotational energy levels in a p-complex Rydberg state of an asymmetric top molecule of symmetry C2v. The effective Hamiltonian used consists of the usual rigid rotor Hamiltonian augmented with terms representing electronic spin and orbital angular momentum effects. Criteria for assigning symmetry species to the rotational energy levels, following Houganfs scheme that uses the full molecular group,are established and given in the form of a table. This is particularly suitable when eigenvectors are calculated on a digital computer. Also, an intensity theory for transitions to the Rydberg p-complex singlet states is presented and selection rules in terms of symmetry species of energy states are established. Finally, applications to HpO and DpO are given.

Science Complex Opening

Pictured here from left to right are James Gibson, President Emeritus, R. A. Macleod, Board of Trustees, and Dr. Cecil Shaver, former Chancellor, during the 1984 Science Complex opening - an addition to the Mackenzie Chown Complex now simply known as H Block.

Science Complex Opening

Pictured here from left to right are Henry Tomarin, Board of Trustees, St. Catharines Mayor Roy Adams, R. Campbell, Niagara Region chairman, Peter Misener, and R. Misener, Chancellor, during the 1984 Science Complex opening - an addition to the Mackenzie Chown Complex now simply known as H Block.

Science Complex Opening

Dr. Earp unveils a sign at the joint Science Complex opening ceremony and the Academic Staging Building renaming ceremony. The Academic Staging Building was henceforth called the Mackenzie Chown Complex.

Science Complex Opening

Dr. Alan Earp speaks at the opening ceremony for the Science Complex addition in 1984.

Science Complex Opening

Doris Chown speaking at the Science Complex Opening and the unveiling of a sign in conjunction with the renaming of the Academic Staging Building to the Mackenzie Chown Complex.

Science Complex Opening

Robert S. K. Welch celebrates the opening of the new Science Complex wing, an addition to the Mackenzie Chown Complex, as Dr. Alan Earp (pictured behind Welch) and others look on. The new name for the Academic Staging Building was also unveiled. It was renamed after former mayor Mackenzie Chown.

Science Complex Opening

Rather then cutting a piece of red tape with scissors, the Science students at Brock prepared a laser devise to cut through a specially made piece of metallic ribbon for the opening ceremony of the Science Complex addition. Pictured here is Robert Welch with the laser device as he attempts to 'cut' the tape. Unfortunately the device failed and Dr. Earp resorted to cutting the tape with a Swiss Army knife he had on hand.

Greenhouse and Science Complex

The Aumni Greenhouse and the Science Complex in the background.

Complex Model

Mackenzie Chown Complex model.

Complex Model

View of the Mackenzie Chown Complex model from above.

Science Complex Model

A model showing the Mackenzie Chown complex and the H Block addition.

Complex takes shape

View of the progress of the Mackenzie Chown Complex several months into construction.

Science Complex Construction

Initial groundwork taking place during the construction of the addition.

Science Complex Construction

Early groundwork continues during the construction of the addition.