Attempted asymmetric synthesis of Lactobacillic acid / |nFawzy F. Z. Georges. -- 260 St. Catharines, Ont. : [s. n.],

This research work has been planned with the intention of proving the absolute configuration of lactobacillc acid. During the course of this work, attempts have been made to synthesize cis-2-carboxycyclopropane- l-.acetic acid as,v,a suitable resolvable material. As the results were not satisfactory, the synthesis of ci,s-2-carboxycyclopropane-l-propionic acid has been alternatively attempted by ring opening of bicyclo- [4.1.~-heptan-2-onewithout much success. Attempts to resolve or prepare bicyclo[ 4.1.~-hePtan-2-one optically active are also reported. On the other hand, a complete scheme is described for the possible synthesis of optically active lactobacillic acid. If only bicyclo- ~.1.~ -heptan-2-one can be resolved or prepared optically active, this described scheme can be applied smoothly to the synthesis of enant~omeric lactobacillic acid.

HOEK UNIT C (Z) B3

Light brown sediment with clasts ranging from small to medium in size. The clast shape ranges from sub-angular to rounded. Lineations and edge-to-edge grain crushing can mainly be seen in this sample. There are also a few examples of grain stacking and crushed grains.

PB 1C(z)

Dark brown sediment with well dispersed clasts. The clasts are mainly small and range from sub-angular to rounded in shape. This sample is mainly structure-less but does contain lineations.