Families of the traumatically brian-injured : a case study approach to perceptions of quality of service, degree of satisfaction, and family needs /

The purpose of this qualitative research study was to foster an understanding of the rehabilitation counselling practice offamilies of the brain-injured. Specifically, the study explores the perceptions of stakeholders in regards to the degree of satisfaction with the quality of service received. Questionnaires were administered, and semi-structured, openended interviews were conducted, with six participating families (n=8). Preliminary data were collected via two instruments: (i) the Family Participant Questionnaire, consisting of participants' sample characteristics, information pertaining to the history of the family, details of the injury, and information relating to the type, use, and need offamily services utilized; and (ii) the Community Integration Questionnaire, a measurement of the degree of social displacementllevel of community integration of the injured family member. Utilizing the procedural steps outlined by Colaizzi's (1978) method of protocol analysis, recommendations for a future program based on related and current family needs are discussed in detail. Substantiating and supporting information are offered to rehabilitation practitioners, educational planners, and policymakers alike, concerning the degree of satisfaction with rehabilitative service, and the means of improving upon the overall quality of health care to families of the brain-injured. Implications for clinical practice and research are also raised for discussion.

The Synthesis and Coordination Chemistry of Two Families of Polydentate Ligands - Exploring Their Potential for the Preparation of Molecule-Based Magnets

The synthesis and studies of two classes of poly dentate ligands are presented as two projects. In project 1, four new carboxamide ligands have been synthesised via the condensation of 2,2',6,6'-tetrachloroformyl-4,4'-bipyridine or 2,6-dichloroformyl pyridine together with heterocyclic amines containing pyridine or pyrazole substituents. The coordination chemistry of these ligands has been investigated and studies have shown that with a Cu(II) salt, two carboxamide ligands LJ and L2 afford large clusters with stoichiometries [Cu8(L1)4Cl16].CHCl3.5H2O.7CH3OH (I) and [Cu9(L2)6Cl6].CH3OH.5H2O.(C2H5)3N (II) respectively. [molecular diagram availabel in pdf]. X-ray diffraction studies of cluster (I) reveal that it has approximate S4 symmetry and is comprised of four ligands and eight copper (II) centers. Here, coordination takes place via amide 0 atoms, and pyrazole nitrogens. This complex is the first reported example of an octanuclear copper cluster with a saddle-shaped structure. The second cluster comprises nine copper ions that are arranged in a cyclic array. Each ligand coordinates three copper centers and each copper ion shares two ligands to connect six ligands with nine copper ions. The amide nitrogens are completely deprotonated and both amide Nand 0 atoms coordinate the metal centres. The cluster has three-fold symmetry. There are six chloride ions, three of which are bridging two neighbouring Cu(II) centres. Magnetic studies of (I) and (II) reveal that both clusters display weak antiferromagnetic interactions between neighbouring Cu(II) centers at low temperature. In the second project, three complexes with stoichiometries [Fe[N302](SCN)2]2 (III), R,R-[Fe[N3O2](SCN)2 (IV) and R,R-]Fe[N3O2](CN)2] (V) were prepared and characterized, where [N302] is a pentadentate macrocycle. Complex (III) was prepared via the metal templated Schiff-base condensation of 2,2',6,6'-tetraacetyl-4,4'-bipyridine together with 3,6-dioxaoctane-I,8-diamine and comprises of a dimeric macro cycle where the two Fe(II) centres are in a pentagonal-bipyramidal environment with the [N302] ligands occupying the equatorial plane and two axial NCS ligands. Complexes (IV) and (V) were prepared via the condensation of 2,6-diacetylpyridine together with a chiral diamine in the presence of FeCh. The synthetic strategy for the preparation of the chiral diamine (4R,5R)-4,5-diphenyl-3,6-dioxa-I,8-octane-diamine was elucidated. The chirality of both macrocycles (IV) and (V) was probed by circular dichroism spectroscopy. The crystal structure of (IV) at 200 K contains two independent molecules in the unit cell, both of which contain a hepta-coordinated Fe(II) and axial NCS ligands. Variable temperature magnetic susceptibility and structural studies are consistent with a high spin Fe(II) complex and show no evidence of any spin crossover behaviour. In contrast, the bis cyanide derivative (V) crystallizes with two independent molecules in the unit cell, both of which have different coordination geometries consistent with different spin states for the two Fe(II) centres. At 250 K, the molecular structure of (V) shows the presence of both 7- and a 6-coordinate Fe(II) complexes in the crystal lattice. As the temperature is lowered, the molecules undergo a structural change and at 100 K the structural data is consistent with a 6- and 5-coordinate Fe(II) complex in the unit cell. Magnetic studies confirm that this complex undergoes a gradual, thermal, spin crossover transition in the solid state. Photomagnetic measurements indicate this is the first chiral Fe (II) sea complex to exhibit a LIESST.

Proceedings of the Grand Chapter of Royal Arch Masons of Canada at the annual convocation, 1872

Annual Convocation proceedings for the year 1872. The title varies slightly and convocation is held at different cities or towns in Canada. Fifteenth annual convocation.

Proceedings of the Grand Chapter of Royal Arch Masons of Canada at the annual convocation, 1873

Annual Convocation proceedings for the year 1873. Title varies slightly and convocation is held at different cities or towns in Canada. Sixteenth annual convocation.

Proceedings of the Grand Chapter of Royal Arch Masons of Canada at the annual convocation, 1874

Annual Convocation proceedings for the year 1874. The title varies slightly and convocation is held at different cities or towns in Canada. Seventeenth annual convocation.

Proceedings of the Grand Chapter of Royal Arch Masons of Canada at the annual convocation, 1875

Annual Convocation proceedings for the year 1875. The title varies slightly and convocation is held at different cities or towns in Canada. Eighteenth annual convocation.

Proceedings of the Grand Chapter of Royal Arch Masons of Canada at the annual convocation, 1876

Annual Convocation proceedings for the year 1876. The title varies slightly and convocation is held at different cities or towns in Canada. Nineteenth annual convocation.

Proceedings of the Grand Chapter of Royal Arch Masons of Canada at the annual convocation, 1877

Annual Convocation proceedings for the year 1877. The title varies slightly and convocation is held at different cities or towns in Canada. Twentieth annual convocation.

Proceedings of the Grand Chapter of Royal Arch Masons of Canada at the annual convocation, 1878

Annual Convocation proceedings for the year 1878. The title varies slightly and convocation is held at different cities or towns in Canada. Twenty-First annual convocation.

Proceedings of the Grand Chapter of Royal Arch Masons of Canada at the annual convocation, 1879

Annual Convocation proceedings for the year 1879. The title varies slightly and convocation is held at different cities or towns in Canada. Twenty-second annual convocation.

Proceedings of the Grand Chapter of Royal Arch Masons of Canada at the annual convocation, 1880

Annual Convocation proceedings for the year 1880. The title varies slightly and convocation is held at different cities or towns in Canada. Twenty-third annual convocation.

Proceedings of the Grand Chapter of Royal Arch Masons of Canada at the annual convocation, 1881

Annual Convocation proceedings for the year 1881. The title varies slightly and convocation is held at different cities or towns in Canada. Twenty-fourth annual convocation.

Proceedings of the Grand Chapter of Royal Arch Masons of Canada at the annual convocation, 1882

Annual Convocation proceedings for the year 1882. The title varies slightly and convocation is held at different cities or towns in Canada. Twenty-fifth annual convocation.

Proceedings of the Grand Chapter of Royal Arch Masons of Canada at the annual convocation, 1883

Annual Convocation proceedings for the year 1883. The title varies slightly and convocation is held at different cities or towns in Canada. Twenty-sixth annual convocation.

Proceedings of the Grand Chapter of Royal Arch Masons of Canada at the annual convocation, 1884

Annual Convocation proceedings for the year 1884. The title varies slightly and convocation is held at different cities or towns in Canada. Twenty-seventh annual convocation.