Andrew Tinnish

Andrew Tinnish reaches the home plate in the 1998 Blue/Red scrimmage. Tinnish was inducted into the Brock Baseball Hall of Fame.

Mass spectral studies of some pentafluorophenyl derivatives of group V /|nby Andrew Tanner Rake. -- 260 St. Catharines, Ont. : [s. n.],

The mass spectra of compounds of t he series (C6F5 )3-n MP~ (n = 1,2,3, M = P and As ), (C6F5>3Sb, Ph) Sb and (C6F5 )2SbPh have been studied in detail and the important modes of fragmentation were e1ucidated, a ided by metastable ions. Various trends attributed to the central atom and or the . substituent groups have been noted and, where applicable, compared to recent studies on related phenyl and pentafluorophenyl compounds of groups IV and V. The mass spectra of fluorine containing organometallic compounds exhibit characteristic migrations of fluorine to t he central atom, giving an increasing abundance of MF+, MF2+' and RMF+ (R = Ph or C6F5) ions on descending the group_ The mass spectra of pentafluorophenyl , antimony, and arsenic compounds show a greater fragmentation of the aromatic ring than those of phosphorus. The mixed phenyl pentafluorophenyl derivatives show a characteristic pattern depending on the number of phenyl grm.lps present but show t he general characteristics of both the tris(phenyl) and tris(pentafluorophenyl) compounds. The diphenyl pentafluorophenyl der ivatives show the loss of biphenyl ion as the most import ant step, the los s of phenyl t o give the i on PhMC6F5 + being of secondary importance. The ,bis(pentafluorophenyl) phenyl derivatives fragment primarily by loss of PhC6F5 to give C6F5M+ ions, the abundance of t hese increasing r apidly from phosphorus to arsenic. This species then, exhibits a characteristic fragmentation observed in the tris(penta- fluorophenyl ) compounds. However, the abundance of (C6F5)2M+ species in these compounds i s small. I ons of the type C6H4MC6F4 + and tetrafluorobiphenylene ions C6H4C6F4 + also are observed on substitution of a phenyl group for a penta- fluorophenyl group. The fully fluorinated species (C6F4)2M+ is not observed, although octafluorobiphenylene ions , (C6F4)2+' are evident in several spectra . The appearance potentials of the major ions were obtatned from the ionisation efficiency curves. Attempts were made to correlate these to the effect of the central atom in substituent groups, but the large errors involved prevented the reaching of quantitative conclusions, although it would appear that the electron is removed from the ligand in the ionisation of t he parent molecule .

Proceedings : Grand Lodge, A.F. & A.M. of Canada in the Province of Ontario - 1858

On spine : The Grand Lodge of Canada in the Province of Ontario.

Welland Canal Survey of Lands Andrew Wilson 1831

Survey map and description of Andrew Wilson's land created by The Welland Canal Company. Included is a written description of the land along with a drawing of the land. Noteable features include; line between Marlatt and Wilson's land, canal. The land is a total of 23 acres, 1 road, and 33 perches. Surveyor notes are seen in pencil on the map. The land was surveyed by George Keefer in August 1831.Survey notes are on page 89, map is on page 91 and includes George Marlatt's land.

Andrew Dean Grist and Flouring Mills - Vignette

A vignette of Grist and Flouring Mills, Clinton, Andrew Dean, Esq., Proprietor.

Niagara Ship Canal [to accompany Bill H.R. no.432] (1858)

At head of Caption title: 35th Congress, 1st session. House of Representatives, Report no. 374.

Andrew Bloomfield collection, 2006-2012

Andrew Bloomfield, and his twin sister Victoria, were born on May 6, 1968 in Auckland, New Zealand. The following year, the family moved to Guelph, Ontario. It became apparent from the time Andrew was 14 months old that he differed considerably from his twin sister, and he was subsequently diagnosed with autism when he was four years old. As a result, he lived away from his family for much of his early life in order to participate in programs for autistic people. Andrew found this very difficult, but also made some significant progress. He became able to relate to and care for his dog, and was able to express his thoughts with Augmentative and Alternative Communication, especially using Supported Typing. His twin sister Victoria was an important person in his life, and her untimely death in a car accident in 1996 devastated him. However, his network of friends and family have provided immense support and helped him build a fulfilling and meaningful life. In 2004 Andrew founded a group of other adult communicators who "type to talk" which he named "Bridges-Over-Barriers". They meet monthly in Guelph and contributed to the 2010 volume with accompanying documentary film on DVD. He lives in his own home in Guelph, guaranteed by a housing trust, and has written several books, including an autobiography, Bridges over Barriers in My Life with Autism.

Letter - Andrew Cowan to William Cowan

A letter from Andrew Cowan to his son William Cowan 29 Septemer 1841. The letter reads "Dear William, I have taken my pen the third time since I have received any word from you, my first letter was about the beginning of the year, and the second in the month of April with John Armstrong of Northhouse, he sailed from Liverpool the fifteen of that month with his sisters Jane and Jenny and their two children. I received a letter from him dated Cleavland in the State of Ohio the 6 of June. He did not intend stopping in that place. The leaves us all well for any thing that I know, but I have not heard from Andrew since March altho I have writen to him three months since your Mother and I are both sore faild altho we have tolerable good health for which we desire to be thankfull to the giver of all our mercies, which are new every day, that we may be found in Christs and clothed in his imputed righteousness at the last, for in him is only found true happyness. We have had another cold wet Summer and the crops is far back ------ not light, the price of -----is high and trade bad, but sheep and cattle are high. Cattle have not been higher since the French war, but the cattle trade is very bad at present and the opperatives out of imployment and consequently verrry badly of. If none of my former letters have reached you this will inform you that James is at Lanshawburn, and gets imployment all the year, he keeps a cow and five or six sheep, they have three children, Mary, Hannah, and Andrew; I was there after clipping time seeing them, they seem to be verry happy. James Lamb is well he was here the other night, he has got two letters from his son Adam this Summer; they are still in the same place and will finish their job this fall, and seem to be doing well, your Uncle Adam Scott and family are well. John was there lately there is little prospect of his getting to America as the money that was left him is not got yet and will not for some time, If ever this reach you, you must let us know how all the Scotch people that are near you, that went from this place of the Country are doing, as their freinds are anxious to hear from them, perticularly if you know what is becomed of Alexander Hoggs widow and family of ------hill, as I was desired to write to you about them - I got a letter from John Miller dated Gatt but I understand it is a long way from your place he was a gentleman and had the charge of a farm and seems verry ----- Now William if this ever reach you, you must excuse me for not filling this letter up, but if I receive an answer I promise to fill the next better, We all join in our love and respect to you and family. From your loving Father Andrew Cowan

Indenture between Andrew Heron and Charles Donaldson

Indenture (vellum) between Andrew Heron of Niagara Township and Charles Donaldson of Niagara Township concerning a portion of the estate of the late Colonel John Butler consisting of Three Mile Creek Farm - indenture no. 2135. This document is water damaged and wrinkled. Part of the document is missing. March 1, 1845.

Letter with the letterhead “Allan Line of Royal Mail Steamships, Hugh and Andrew Allan, agents, Montreal”

Letter with the letterhead “Allan Line of Royal Mail Steamships, Hugh and Andrew Allan, agents, Montreal”. The salutation is “Dear Sir” and it is signed by Andrew Allan. Mr. Allan had enclosed $150 for shooting rights for last season and is asking if there are any rights available for next year, Dec. 16, 1886.

Estimate of clearing and chopping done by Alexander Cook and Andrew Mains

Estimate of clearing and chopping done by Alexander Cook and Andrew Mains, signed by Fred Holmes, Feb. 23, 1855.

Estimate of work done by Alexander Cook, Andrew Mains, Frederick Holmes, Louis Clement, Patrick Roche and Thomas Baird

Estimate of work done by Alexander Cook, Andrew Mains, Frederick Holmes, Louis Clement, Patrick Roche and Thomas Baird, signed by S.D. Woodruff, Feb. 26, 1855.

Estimatesfor clearing done by the contractors including Alexander Cook, Andrew Mains, Frederick Holmes, Louis Clements and Thomas Baird

Estimatesfor clearing done by the contractors including Alexander Cook, Andrew Mains, Frederick Holmes, Louis Clements and Thomas Baird. This document is signed by S.D. Woodruff. This is complete with an envelope made out to S.D. Woodruff, April 28, 1855.

Estimate of work done on marsh lands drainage by Alexander Cook and Andrew Mains

Estimate of work done on marsh lands drainage by Alexander Cook and Andrew Mains. This is signed by S.D. Woodruff. Also on this sheet is pay roll for engineer services for the months of September, October and November, 1855. This was paid to Frederick Holmes, Thomas Baird, Joseph Simpson and Len [illegible name], Nov.30, 1855.