19 resultados para C-15-Acetogenin

em Brock University, Canada


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A brief note to Arthur Schmon that reads: " February fifteenth. Dear, This is to let you see that I am not neglecting my duties as a member of the "cheer committee". Remember that the only thing that never goes out of style is a smile, so keep on wearing one. Affectionately, Lessie."

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This letter discusses the long wait between correspondence due to the mail delivery. She also discusses the weeks plans. This letter is labelled 57th.

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This letter mentions that Eleanore Celeste has not heard from Arthur in nearly a month. She hopes that this means he will be coming home soon from France. It is labelled number 175.

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The letter mentions a possibility of Arthur returning home. Eleanore Celeste also mentions a recently engaged friends sadness since her fiance will leave for a camp. This letter is labelled number 161.

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The letter mentions a train from Newark to Princeton. She writes "Shall keep all news until I see you". The second part of the letter is written another day and describes the time she spent with Arthur.

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The letter discusses more studies in French. She is learning grammar from a textbook and reading a book written in French entitled "En France".

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The letter begins by describing her Red Cross uniform to be worn during the Xmas campaign. She also mentions an outing to see a show "Glorianna", then dancing at Murrays, then Hunter Island Inn for dinner. This letter is labelled number 202.

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Eleanore Celeste mentions that Arthur is to return in July. She discusses the way the troops are returning to New York and New Jersey and the discharge process. These letters are labelled number 279 and 280.

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Modifications to the commercial hydride generator, manufactured by Spectrametrics, resulted in improved operating procedure and enhancement of the arsenic and germanium signals. Experiments with arsenic(III) and arsenic(V) showed that identical reiults could be produced from both oxidation states. However, since arsenic(V) is reduced more slowly than arsenic(III), peak areas and not peak heights must be measured when the arsine is immediately stripped from the system (approximately 5 seconds reaction). When the reduction is allowed to proceed for 20 seconds before the arsine is stripped, peak heights may be used. For a 200 ng/mL solution, the relative standard deviation is 2.8% for As(III) and 3.8% for As(V). The detection limit for arsenic using the modified system is 0.50 ng/mL. Studies performed on As(V) standards show that the interferences from 1000 mg/L of nickel(II), cobalt(II), iron(III), copper(II), cadmium(II), and zinc(II) can be eliminated with the aid of 5 M Hel and 3% L-cystine. Conditions for the reduction of germanium to the corresponding hydride were investigated. The effect of different concentrations of HCl on the reduction of germanium to the covalent hydride in aqueous media by means of NaBH 4 solutions was assessed. Results show that the best response is accomplished at a pH of 1.7. The use of buffer solutions was similarly characterized. In both cases, results showed that the element is best reduced when the final pH of the solution after reaction is almost neutral. In addition, a more sensitive method, which includes the use of (NH4)2S208' has been developed. A 20% increase in the germanium signal is registered when compared to the signal achieved with Hel alone. Moreover, under these conditions, reduction of germanium could be accomplished, even when the solution's pH is neutral. For a 100 ng/mL germanium standard the rsd is 3%. The detection limit for germanium in 0.05 M Hel medium (pH 1.7) is 0.10 ng/mL and 0.09 ng/mL when ammonium persulphate is used in conjunction with Hel. Interferences from 1000 mg/L of iron(III), copper(II), cobalt(II), nickel(II), cadmium(II), lead(II), mercury(II), aluminum(III), tin(IV), arsenic(III), arsenic(V) and zinc(II) were studied and characterized. In this regard, the use of (NH4)ZS20S and Hel at a pH of 1.7 proved to be a successful mixture in the sbppression of the interferences caused by iron, copper, aluminum, tin, lead, and arsenic. The method was applied to the determination of germanium in cherts and iron ores. In addition, experiments with tin(IV) showed that a 15% increase in the tin signal can be accomplished in the presence of 1 mL of (NH4)2S20S 10% (m/V).

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A letter from Lieut. A. Watson to Col. F.C. McCordick dated only July 3rd. The letter reads "My dear Col. McCordick, If you haven't already heard, you will be surprised to get this letter from me - in Germany. It happened at that awful slaughter - the 3rd battle of Ypres, & even now when I think of it all, I doubt my reality of existence. Everything was O.K at 730am on the 2nd - a little morning hate in the way of trench mortars, that was all. I had just visited a few of my guns & had passed Gen.s Mercer & Williams & their aides, Lyman Gooderham and Fraser (two latter at this camp) on the way to the -- C.M.R Bn. Head Quarters when the storm broke. It last for 5 hours & by the time the Germans came over there were few left to oppose them. By a miracle, the 15 yard bay of the front line, where I was with 6 others, was not levelled like all the rest of the line & we did our best with rifle & bomb. I got a crack on the head & 3 hours later I found myself in a waterfilled shell hole. By night I tried to crawl back & through, but at dawn was caught. Am very comfortable here & glad to have company of Col. Usher, Capt. Light Bourne, Capt. Frank Park M.O. -- CMR) & about 20 other Canadians. Hope all is well with you & 35 - Good luck & best regards to all. A. Watson Sime, Lieut. Haus 62-B OFFIZIER-KRIEGSGEFANGENLAGER Gutersloh.

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This thesis describes a method involving the preparation of an L-proline-derived imidazolone protected with an N-triethylsilyl group that undergoes diastereoselective lithiation followed by electrophile quench to give C5-substituted products with syn stereochemistry. The N-silylated derivatives may be more easily N-deprotected as compared to previous N-t-Bu analogues to give secondary ureas. These may serve as precursors to N-phenyl chiral bicyclic guanidines or as NHC precursors for synthesis of corresponding complexes.

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The letter describes a day Eleanore Celeste spent downtown and many friends she ran into during her outing. She then mentions an article she read that states most troops will be out of France by July 1st. This letter is labelled number 278.

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Eleanore Celeste writes that she is waiting for her "big sister to dismiss two bad boys, then we are going down town shopping". This letter is incomplete and undated.

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Eleanore Celeste has had a falling out with her friend Hilda Hartdegen because she doesn't want to contact "Uncle Dickie", but Hilda wants her to call him to set up an outing. Arthur had said that he didn't want Eleanore Celeste to see "Uncle Dickie" without the company of her Mother.

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Letter (1 typed page) to Mr. C. Howard from Louis J. Cahill of the Niagara Editorial Bureau stating that they are sending information in regard to the Zimmerman Bank and Whirlpool Rapids Bridge in relation to the forthcoming Centennial celebrations of the bridge, July 9, 1948.