The crystal and molecular structure of 18-Crown-6 HgC12 and 18-Crown-6 Cdc12

Hg(18-Crown-6)C12 and Cd(18-Crown-6)C12 are isostructura1, space group Cl~ Z = 2. For the mercury compound, a = 10.444(2) A° , b = 11. 468(1) A° , c = 7.754(1) A° , a = 90.06(1)°, B = 82.20(1)°, Y = 90.07(1)°, Dobs = 1.87, Dca1c = 1.93, V = 920.05 13, R = 4.66%. For the cadmium compound, 000 a = 10.374(1) A, b = 11.419(2) A, c = 7.729(1) A, a = 89.95(1)°, B = 81.86(2)°, Y = 89.99(1)°, Dobs = 1.61, Dcalc = 1.64, V = 906.4613, R = 3.95%. The mercury and cadmium ions exhibit hexagonal bipyramidal coordination, with the metal ion located on a centre of symmetry in the plane of the oxygen atoms. The main differences between the two structures are an increase in the metal-oxygen distance and a reduction in the metalchloride distance when the central ion changes from Cd2+ to Hg2+. These differences may be explained in terms of the differences in hardness or softness of the metal ions and the donor atoms.

Second Welland Canal - Book 1, Survey Map 6 - Through Grantham and Louth Townships

Survey map of the Second Welland Canal created by the Welland Canal Company showing the area between the Townships of Grantham and Louth. Identified structures associated with the Canal include the floating tow path. The surveyors' measurements and notes can be seen in red and black ink and pencil. Features of the First Welland Canal are noted in red ink and include the old towing path, and the original bed of the Twelve Mile Creek. Local area landmarks are also identified and include streets and roads (ex. New Road, 1st Concession Road, and an unnamed road in the top right corner), an unnamed bridge along New Road, J. Martindale's House, an Old Saw Mill, Richardsons Creek, Georges Point, and an oak tree at Georges Point. Properties and property owners of note are: Concession 2 Lot 23 and Concession 3 Lot 23 in the Grantham Township, Concession 2 Lots 1 and 2, and Concession 3 Lots 1 and 2 in the Louth Township, Peter Weaver, J. Martindale, and John Bonner. A property belonging to the Board of Works is outlined in red at Georges Point.

Second Welland Canal - Book 2, Survey Map 1 - Locks 5, 6 and 7 in Grantham

Survey map of the Second Welland Canal created by the Welland Canal Company showing the Grantham Township just southeast of the Town of St. Catharines. Identified structures associated with the Canal include Locks 5, 6, and 7, two Lock House Lots, Small Lock House, waste weir, and the towing path. The surveyors' measurements and notes can be seen in red and black ink and pencil. Local area landmarks are also identified and include roads (ex. Road to Thorold), Dicks Creek, R. Collier's Saw Mill, a gate yard, paper mill, grist mill, store house, and a barn. Properties and property owners of note are: Concession 7 Lots 13, 14, and 15, R. Collier, Orson Phelps, and a Mill Lot leased to Richard Collier.

Second Welland Canal - Book 2, Survey Map 6 - Locks 19, 20, 21 and 22 in Grantham

Survey map of the Second Welland Canal created by the Welland Canal Company showing south Merritton along the boundary between the Grantham and Thorold Townships. Identified structures associated with the Canal include Locks 19, 20, 21, and 22, Lock Tenders House, and the towing path. The surveyors' measurements and notes can be seen in red and black ink and pencil. Local area landmarks are also identified and include streets and roads (ex. Pine Street and Macadamized Road), J. Brown Cement Mill, W. B. Hendershot Saw Mill, W. Parnall Spoke and Sash Factory, W. Beatty Saw Mill, W. Beatty Tannery, a number of structures (possibly houses) belonging to: Mrs. Aikins, J. Battle, and E. Keefer, and a foundry, smithy, and machine shop (all of which possible belonged to J. Dobbie). Properties and property owners of note are: Concession 10 Lots 9 and 10, W. C. Loan Company, P.H. Ball, and J. Keefer. Two small properties belonging to W. B. Hendershot and W. Beatty exist and are outlined in red. A half acre property reserved for a lock lot exists and is outlined in blue. An additional property reserved for a quarry is also identified, but not outlined.

Second Welland Canal - Book 3, Survey Map 6 - Canal along Chippewa Creek in Thorold

Survey map of the Second Welland Canal created by the Welland Canal Company showing the canal along Chippewa Creek in Thorold Township. Identified structures and features associated with the Canal include the towing path, the back ditch, and the waterway itself. The surveyors' measurements and notes can be seen in red and black ink and pencil. Local area landmarks are also identified and include roads (ex. Road to Welland), Chippewa Creek, and a pond. Properties and property owners of note are: Lots 214, 215, 216 and 222, and Heaslip.

Letter from Lt.Col. Chewett to Ensign Kuck- 6 Sept 1814

Transcript (spelling and grammar retained): York 6th Sepber [September] 1814 Sir I will thank your for the Rolls and Returns of the Pickering Company due on the 1st instance that I may Make up mine to be returned to the Adjutant General – I have the honor to be Sir Your Most Obed [Obedient] W Chewett Lt Col 3rd Reg Yk [York] Militia

Letter - E.C. Schmon to Arthur A. Schmon, 6 February 1917

The letter reads:" The sixth of February. Artie dear, I am going to be a real good girl and not make you read a long letter, when your thoughts are so completely occupied with "war". Newark is also greatly excited. All arrangements for the mobilization of the militia forces have been made, and in case of any local uprisings, two hundred policemen are to be added to the force. Of course everyone is thinking the worst at present, but I cannot help but believe that in a few months, people will feel like kicking themselves, for having done an unnecessary amount of worrying. (Let us hope so). If nothing unforeseen occurs, I am going to take the "Congressional limited" to Washington, Wednesday the twenty first. Saw in the paper that the public ceremonies of inauguration are to be eliminated, or I would go down the following week. Don't think to steadily about the war. It's bad for the head. Affectionately, Lessie."

Letter - E.C. Schmon to Arthur A. Schmon, 6 August 1918

The letter mentions some men that may be returning the United States and some that have returned. This letter is labelled number 138.

Letter - E.C. Schmon to Arthur A. Schmon, 6 March 1919

Eleanore Celeste begins by discussing her birthday gifts she received from friends and family. There is talk that Arthur might soon be release from the army. She also mentions she is teaching higher grades and she finds it "very hard". The children of celebrities in Newark attend the school she is currently placed. The letter is labelled number 242.

Letter - E.C. Schmon to Arthur A. Schmon, 6 January 1919

The letter mentions that Eleanore Celeste's mother "is so much better" so she "shall be able to teach several days a week now". She says that "word has just been sent thru the buidling that Theodore Roosevelt died at his Long Island home today." This letter is labelled number 212.

Letter - E.C. Schmon to Arthur A. Schmon, 6 May 1919

Eleanore Celeste has just received four letters from Arthur. She includes a poem by Darrach: "The weakness that you know is yours, She in her strength would vitally sustain, And that fine strength you drew from her, You would when she had need, return to her again. Yes, where your strength were great and she were weak, You'd courage her and strengthen her, Until the heavy burdens given her to hear, Would be tasks easy for her new formed will." The letter is labelled number 272.

DE #6 260.90-261.0

Coarse grained sediment with clasts ranging from small to medium in size. Clast shape range from sub-angular to sub-rounded. Lineations are present throughout the sample. Edge-to-edge grain crushing, grain stacking, and comet structures can also be seen. Some grains are crushed into one another. Areas of finer sediment can also be seen.

ARTHUR 6

Dark brown sediment with clasts ranging from small to large. Clast shape ranges from angular to sub-rounded. Necking structures are abundant in this sample, especially between larger clasts. Rotation structures can also be commonly seen in this sample. This sample also contains lineations, comet structures and grain crushing in minor amounts.

PBURWELL #6-87

Brown sample with mainly small clasts and a few medium sized grains. Grains range from sub-angular to sub-rounded. Lineations are abundant. There are patches of darker brown organic material throughout the sample. Grain crushing and some comet structures can also be seen.

J.R. Ai-6

Coarse grained sediment with clasts ranging from small to large. Clast shape ranges from angular to rounded. Lineations are abundant throughout the sample, along with rotation structures. Some comet structures and grain crushing can also be seen throughout the sample. Rotation structures can mainly be seen around larger clasts.