On-line –jatkojalostuksen integrointi mäntysahan tuotantoprosessiin

Diplomityön tavoitteena oli selvittää erilaisia jatkojalostusmahdollisuuksia, joilla voidaan nostaa suuren mäntysahan tuotteiston arvoa. Lisäksi tuli tarkastella jalostuksen integrointia sahan tuotantoprosessiin. Työn taustalla on toisaalta puutuotemarkkinoiden muuttuminen ja toisaalta raaka-aineen laadullinen huononeminen. Molemmat seikat vaikuttavat negatiivisesti perinteisen mäntysahan kannattavuuteen .Jatkojalostuksen integroinnilla sahatavaraprosessiin saavutetaan säästöjä tuotantokustannuksissa, kun tarkastellaan koko prosessia tukista jatkojalosteeksi. Myös raaka-aineen tuottavuutta voidaan nostaa integraation avulla. Jatkojalostus voidaan integroida sahatavaraprosessiin raaka-aineen valikoinnilla sahatavaraprosessin eri osissa, on-line –jalostuksella sekä taloudellisesti. Sahatavaraprosessissa tapahtuva raaka-aineen valikointi voidaan suorittaa tukeista ja sahatavarasta. Valikointikriteerinä voi olla puun ominaisuudet, sahatavaran mitat ja laatu. Valikointiin voidaan nykyteknologiasta hyödyntää röntgentekniikkaa sekä konenäköä. On-line –jalostus tarkoittaa kiinteästi sahatavaraprosessiin liittyvää jalostusta, jolloin ns. turhia prosessivaiheita jää pois ja syntyy säästöjä. On-line –jalostuksen edellytys on raaka-aineen jonkin asteinen valikointi, esim. pituus. Taloudellisesti integroitu jalostus tarkoittaa, että jalostuslaitoksella pyritään nollatulokseen ja jalostuksen lisäarvo palautetaan sahan toimittamaan raaka-aineen hintaan. Tällainen toiminta yhtiön sisällä poistaa turhaa keskustelua raaka-aineen siirtohinnoista ja siten vapauttaa osaltaan resursseja tuottavampaan toimintaan. Erilaisten jatkojalostusmuotojen ja puun ominaisuuksien hyödyntämisen seulonnan perusteella löytyi yksi jalostusmuoto, jolla voidaan kohottaa mäntysahan tuotteiston arvoa. Työn tuloksena syntyi investointiehdotus aihiotankotuotannosta ikkunateollisuuden tarpeisiin. Raaka-aineen hyödynnettäviä ominaisuuksia ovat männyn sydänpuun luonnollinen kestävyys sekä keskimääräinen oksaväli. Valikointi tehdään välitukeista, joiden sahaamisen kannattavuus on männyn rungon osista heikoin. Aihiotankoprosessissa hyödynnetään konenäköä ja sormijatkostekniikkaa. Jatkojalostuksen integrointi sahatavaraprosessiin toteutetaan rakentamalla on-line –jalostuslaitos sekä soveltamalla röntgentekniikkaa raaka-aineen valinnassa.

Statistical Inversion Theory in X-ray Tomography

In this thesis the X-ray tomography is discussed from the Bayesian statistical viewpoint. The unknown parameters are assumed random variables and as opposite to traditional methods the solution is obtained as a large sample of the distribution of all possible solutions. As an introduction to tomography an inversion formula for Radon transform is presented on a plane. The vastly used filtered backprojection algorithm is derived. The traditional regularization methods are presented sufficiently to ground the Bayesian approach. The measurements are foton counts at the detector pixels. Thus the assumption of a Poisson distributed measurement error is justified. Often the error is assumed Gaussian, altough the electronic noise caused by the measurement device can change the error structure. The assumption of Gaussian measurement error is discussed. In the thesis the use of different prior distributions in X-ray tomography is discussed. Especially in severely ill-posed problems the use of a suitable prior is the main part of the whole solution process. In the empirical part the presented prior distributions are tested using simulated measurements. The effect of different prior distributions produce are shown in the empirical part of the thesis. The use of prior is shown obligatory in case of severely ill-posed problem.

Gamma spectrometry and gamma and X-ray tomography of nuclear fuel

The purpose of gamma spectrometry and gamma and X-ray tomography of nuclear fuel is to determine both radionuclide concentration and integrity and deformation of nuclear fuel. The aims of this thesis have been to find out the basics of gamma spectrometry and tomography of nuclear fuel, to find out the operational mechanisms of gamma spectrometry and tomography equipment of nuclear fuel, and to identify problems that relate to these measurement techniques. In gamma spectrometry of nuclear fuel the gamma-ray flux emitted from unstable isotopes is measured using high-resolution gamma-ray spectroscopy. The production of unstable isotopes correlates with various physical fuel parameters. In gamma emission tomography the gamma-ray spectrum of irradiated nuclear fuel is recorded for several projections. In X-ray transmission tomography of nuclear fuel a radiation source emits a beam and the intensity, attenuated by the nuclear fuel, is registered by the detectors placed opposite. When gamma emission or X-ray transmission measurements are combined with tomographic image reconstruction methods, it is possible to create sectional images of the interior of nuclear fuel. MODHERATO is a computer code that simulates the operation of radioscopic or tomographic devices and it is used to predict and optimise the performance of imaging systems. Related to the X-ray tomography, MODHERATO simulations have been performed by the author. Gamma spectrometry and gamma and X-ray tomography are promising non-destructive examination methods for understanding fuel behaviour under normal, transient and accident conditions.

Magnetic and transport properties of InGaAs quantum wells with Mn

In the present work structural, magnetic and transport properties of InGaAs quantum wells (QW) prepared by MBE with an remote Mn layer are investigated. By means of high-resolution X-ray diffractometry the structure of the samples is analyzed. It is shown that Mn ions penetrate into the QW. Influence of the thickness of GaAs spacer and annealing at 286 ºС on the properties of the system is shown. It is shown that annealing of the samples led to Mn activation and narrowing of the Mn layer. Substantial role of 2D holes in ferromagnetic ordering in Mn layer is shown. Evidence for that is observation of maximum at 25 – 55 K on the resistivity temperature dependence. Position of maximum, which is used for quantitative assessment of the Curie temperature, correlates with calculations of the Curie temperature for structures with indirect interaction via 2D holes’ channel. Dependence of the Curie temperature on the spacer thickness shows, that creation of applicable spintronic devices needs high-precision equipment to manufacture extra fine structures. The magnetotransport measurements show that charge carrier mobility is very low. This leads to deficiency of the anomalous Hall effect. At the same time, magnetic field dependences of the magnetization at different temperatures demonstrate that systems are ferromagnetically ordered. These facts, most probably, give evidence of presence of the ferromagnetic MnAs clusters.

RAY:n vastine Psykologia-lehden toimittajan kommenttiin

Artikkeli on vastine Jussi Valtosen kommenttiin suomalaisesta rahapelijärjestelmästä ja raha-automaattien osuudesta suomalaisessa pelikentässä, joka julkaistiin Psykologia-lehden numerossa 6/2011.

Magnetic properties of defective graphene

In this thesis, the influence of the functionalization of graphene and graphite on their magnetic properties was investigated. The functionalization was performed by covalent attaching of a phenyl groups with three different radicals (4-bromoaniline, 4-chloroaniline and 4-nitroaniline). Magnetic properties were measured by SQUID magnetometer. Both pristine graphite and graphene showed strong diamagnetic behavior. For good quality graphite, diamagnetism was found to be temperature-dependent. All samples demonstrated noticeable paramagnetic contribution below 50 K. According to fitting experimental results with Brillouin function and Curie law, it was shown that paramagnetism is provided by small clusters of spins (superparamagnetic behavior). Moreover, the clusters size and spin concentrations were calculated. For the samples functionalized with nitroaniline the antiferromagnetic transition around 120 K was observed. To explain this behavior, a simple model was proposed. Additional analysis of the graphene quality, structure and composition of the samples was carried out by HRTEM, EDS mapping, Raman spectroscopy and X-ray diffraction techniques.