Fischer-Tropsch Slurry Bubble Column Reactor Modeling

The literature part of the work reviews overall Fischer-Tropsch process, Fischer-Tropsch reactors and catalysts. Fundamentals of Fischer-Tropsch modeling are also presented. The emphasis is on the reactor unit. Comparison of the reactors and the catalysts is carried out to choose the suitable reactor setup for the modeling work. The effects of the operation conditions are also investigated. Slurry bubble column reactor model operating with cobalt catalyst is developed by taking into account the mass transfer of the reacting components (CO and H2) and the consumption of the reactants in the liquid phase. The effect of hydrostatic pressure and the change in total mole flow rate in gas phase are taken into account in calculation of the solubilities. The hydrodynamics, reaction kinetics and product composition are determined according to literature. The cooling system and furthermore the required heat transfer area and number of cooling tubes are also determined. The model is implemented in Matlab software. Commercial scale reactor setup is modeled and the behavior of the model is investigated. The possible inaccuraries are evaluated and the suggestions for the future work are presented. The model is also integrated to Aspen Plus process simulation software, which enables the usage of the model in more extensive Fischer-Tropsch process simulations. Commercial scale reactor of diameter of 7 m and height of 30 m was modeled. The capacity of the reactor was calculated to be about 9 800 barrels/day with CO conversion of 75 %. The behavior of the model was realistic and results were in the right range. The highest uncertainty to model was estimated to be caused by the determination of the kinetic rate.

Production of Biofuels by Fischer Tropsch Synthesis

Production of biofuel via biomass gasification followed by Fischer Tropsch synthesis is of considerable interest because of the high quality of fuels produced which do not contain sulphur and are free of carbon dioxide. The purpose of this Master’s thesis is to study feasibility production of biofuels integrated with Fischer Tropsch process using Aspen Plus simulation. The simulation results were used to size process equipment and carry out an economic evaluation. The results show that lowering the reactor temperature from 1000 oC - 850 oC and raising the water gas shift temperature from 500 oC - 600 oC can improve overall gas efficiency, which in turn leads to better production of ultra clean syngas for the Fischer Tropsch synthetic reactor. Similarly, the Fischer Tropsch offgas is converted into a gas turbine for power production, and finally biodiesel is produced as fuels for transportation.

Mikrokanavareaktorin käyttö reaktorina eksotermisissä reaktioissa

Tämän työn kirjallisuusosassa on tarkasteltumikrokanavareaktoria teknisestä näkökulmasta. Kirjallisuusosassa käydään läpi mikrokanavareaktorin rakennetta, valmistajia sekä valmistusmenetelmiä. Toisena näkökulmana kirjallisuusosassa tarkastellaan mikrokanavareaktorin soveltuvuutta eksotermisiin reaktioihin. Eksotermisista reaktioista tarkasteluun valittiin FIscher-Tropsch synteesi, jota tarkastellaan tässä työssä tarkemmin. Lopuksi kirjallisuusosassa käsitellään mikrokanavareaktoritekniikkalla saavutettavia etuja sekä mikrokanavareaktoritekniikkaan liittyviä ongelmia. Soveltavassa osassa tarkasteltiin mikrokanavareaktorin soveltuvuutta Fischer-Tropsch synteesiin käyttäen apuna Aspen+ simulointiohjelmaa. Aspen+ simulointiohjelman avulla nähtiin mikrokanavareaktorin koon vaikutus Fischer-Tropsh synteesiin. Lisäksi soveltavassa osassa suunniteltiin simulointituloksiin sekä kirjallisuudesta saatuihin tietoihin perustuva teollisuuden mittakaavaan soveltuva mikrokanavareaktori. Lopuksi työssä pohdittiin mikrokanavareaktoritekniikkaa kirjallisuus sekä sekä soveltavan osan perusteella.

Ensimmäisen ja toisen sukupolven nestemäisten liikennebiopolttoaineiden kasvihuonekaasupäästöjenvertailu

Elinkaariarviointia voidaan käyttää ensimmäisen ja toisensukupolven nestemäisten liikennebiopolttoaineiden kasvihuonekaasupäästöjen ja primäärienergian kulutuksen vertailuun. Elinkaariarviointia käyttämällä pyritään tuottamaan luotettavaa tietoa koko elinkaaren ajalta. Nestemäisiä liikennebiopolttoaineita käsittelevissä tutkimuksissa elinkaari jaetaan yleensä kahteen osaan,joista suurempi painoarvo on elinkaaren alkuosalla. Tässä diplomityössä tehdään yksinkertaistettu elinkaariarviointi selluloosaetanolin ja Fischer-Tropsch-dieselin elinkaaren alkuosalle ja verrataan niitä sitten ohraetanoliin ja rypsimetyyliesteriin. Tässä työssä keskitytään primäärienergian kulutukseen sekä hiilidioksidi-, metaani- ja dityppioksidipäästöihin. Selluloosaetanolin raaka-aineena tarkasteltiin ruokohelpeä, Fischer-Tropsch-dieselin raaka-aineena metsätähdettä. Diplomityö osoitti, että toisen sukupolven nestemäisten liikennebiopolttoaineiden tuotannossa kuluu vähemmän primäärienergiaa ja syntyy vähemmän kasvihuonekaasupäästöjä kuin ensimmäisen sukupolven nestemäisten liikennebiopolttoaineiden tuotannossa. Sama tulos on saatu myös muissa aihetta käsittelevissä tutkimuksissa.

Flow phenomena, heat and mass transfer in microchannel reactors

The studies of flow phenomena, heat and mass transfer in microchannel reactors are beneficial to estimate and evaluate the ability of microchannel reactors to be operated for a given process reaction such as Fischer-Tropsch synthesis. The flow phenomena, for example, the flow regimes and flow patterns in microchannel reactors for both single phase and multiphase flow are affected by the configuration of the flow channel. The reviews of the previous works about the analysis of related parameters that affect the flow phenomena are shown in this report. In order to predict the phenomena of Fischer-Tropsch synthesis in microchannel reactors, the 3-dimensional computational fluid dynamic simulation with commercial software package FLUENT was done to study the flow phenomena and heat transfer for gas phase Fischer-Tropsch products flow in rectangular microchannel with hydraulic diameter 500 ¿m and length 15 cm. Numerical solution with slip boundary condition was used in the simulation and the flowphenomena and heat transfer were determined.

Effect of forest-based biofuels production on carbon footprint, Case: Integrated LWC paper mill

International energy and climate strategies also set Finland’s commitments to increasing the use of renewable energy sources and reducing greenhouse gas emissions. The target can be achieved by, for example, increasing the use of energy wood. Finland’s forest biomass potential is significant compared with current use. Increased use will change forest management and wood harvesting methods however. The thesis examined the potential for integrated pulp and paper mills to increase bioenergy production. The effects of two bioenergy production technologies on the carbon footprint of an integrated LWC mill were studied at mill level and from the cradle-to-customer approach. The LignoBoost process and FT diesel production were chosen as bioenergy cases. The data for the LignoBoost process were obtained from Metso and for the FT diesel process from Neste Oil. The rest of the information is based on the literature and databases of the KCL-ECO life-cycle computer program and Ecoinvent. In both case studies, the carbon footprint was reduced. From the results, it can be concluded that it is possible to achieve a fossil-fuel-free pulp mill with the LignoBoost process. By using steam from the FT diesel process, the amount of auxiliary fuel can be reduced considerably and the bark boiler can be replaced. With a choice of auxiliary fuels for use in heat production in the paper mill and the production methods for purchased electricity, it is possible to affect the carbon footprints even more in both cases.