Spin-Dynamics in Cold Gases of 87Rb and Atomic Hydrogen. The spins they are a-changin’

In this thesis the dynamics of cold gaseous atoms is studied. Two different atomic species and two different experimental techniques have been used. In the first part of the thesis experiments with Bose-Einstein condensates of Rb-87 are presented. In these experiments the methods of laser cooling and magnetic trapping of atoms were utilized. An atom chip was used as the experimental technique for implementation of magnetic trapping. The atom chip is a small integrated instrument allowing accurate and detailed manipulation of the atoms. The experiments with Rb-87 probed the behaviour of a falling beam of atoms outcoupled from the Bose-Einstein condensate by electromagnetic field induced spin flips. In the experiments a correspondence between the phases of the outcoupling radio frequency field and the falling beam of atoms was found. In the second part of the thesis experiments of spin dynamics in cold atomic hydrogen gas are discussed. The experiments with atomic hydrogen are conducted in a cryostat using a dilution refrigerator as the cooling method. These experiments concentrated on explaining and quantifying modulations in the electron spin resonance spectra of doubly polarized atomic hydrogen. The modifications to the previous experimental setup are described and the observation of electron spin waves is presented. The observed spin wave modes were caused by the identical spin rotation effect. These modes have a strong dependence on the spatial profile of the polarizing magnetic field. We also demonstrated confinement of these modes in regions of strong magnetic field and manipulated their spatial distribution by changing the position of the field maximum.

Structural and operational optimisation : applications in energy systems

In this work mathematical programming models for structural and operational optimisation of energy systems are developed and applied to a selection of energy technology problems. The studied cases are taken from industrial processes and from large regional energy distribution systems. The models are based on Mixed Integer Linear Programming (MILP), Mixed Integer Non-Linear Programming (MINLP) and on a hybrid approach of a combination of Non-Linear Programming (NLP) and Genetic Algorithms (GA). The optimisation of the structure and operation of energy systems in urban regions is treated in the work. Firstly, distributed energy systems (DES) with different energy conversion units and annual variations of consumer heating and electricity demands are considered. Secondly, district cooling systems (DCS) with cooling demands for a large number of consumers are studied, with respect to a long term planning perspective regarding to given predictions of the consumer cooling demand development in a region. The work comprises also the development of applications for heat recovery systems (HRS), where paper machine dryer section HRS is taken as an illustrative example. The heat sources in these systems are moist air streams. Models are developed for different types of equipment price functions. The approach is based on partitioning of the overall temperature range of the system into a number of temperature intervals in order to take into account the strong nonlinearities due to condensation in the heat recovery exchangers. The influence of parameter variations on the solutions of heat recovery systems is analysed firstly by varying cost factors and secondly by varying process parameters. Point-optimal solutions by a fixed parameter approach are compared to robust solutions with given parameter variation ranges. In the work enhanced utilisation of excess heat in heat recovery systems with impingement drying, electricity generation with low grade excess heat and the use of absorption heat transformers to elevate a stream temperature above the excess heat temperature are also studied.

OL1/OL2-suojarakennuksen jäähdytteenmenetysonnettomuusanalyysit APROS 5.09 -ohjelmistolla

Tässä työssä on tutkittu OL1/OL2-suojarakennuksen käyttäytymistä jäähdytteenmenetysonnettomuuden eli LOCA:n aikana. Onnettomuuden simulointiin on kehitetty suojarakennusmalli suomalaiseen APROS 5.09 - ohjelmistoon sisältyvällä LP-koodilla (Lumped Parameter Code). Työssä on keskitytty suojarakennuksen kannalta oleellisimpien suureiden: kaasutilavuuksien paineen sekä lämpötilan ja lauhdutusaltaan lämpötilan ja pinnankorkeuden ajalliseen käyttäytymiseen. Mallinnetut LOCA:t ovat päähöyrylinjan ja sammutetun reaktorin jäähdytysjärjestelmän putkikatkoksia. Simulointeja on tehty laitoksen täyden tehon ja kuumavalmiuden lähtötiloissa ja tarkasteltavien suureiden käyttäytymistä on tutkittu erikseen valituilla konservatiivisilla oletuksilla. Laskentatapaukset rajoittuvat lyhyeen aikaväliin 27.78 tuntia kuvitellusta putkirikosta eteenpäin. Tuloksia on verrattu OL1/OL2- laitostoimittajan, Westinghouse Electric Sweden AB:n, tekemiin lisensiointianalyyseihin. Työssä on myös kuvattu APROS-laskennan epävarmuustekijöitä. Suojarakennuksen on todettu käyttäytyvän fysikaalisesti yhtenevästi lisensiointianalyyseissä ja APROS:lla tehdyissä vertailulaskuissa.

Structural and functional Studies of angucycline tailoring enzymes

Polyketides are a diverse group of natural products produced in many bacteria, fungi and plants. These metabolites have diverse biological activities and several members of this group are in clinical use as antibiotics, anticancer agents, antifungals and immunosuppressants. The different polyketides are produced by polyketide synthases, which catalyze the condensation of extender units into various polyketide scaffolds. After the biosynthesis of the polyketide backbone, more versatility is created to the molecule by tailoring enzymes catalyzing for instance hydroxylations, methylations and glycosylations. Flavoprotein monooxygenases (FPMO) and short-chain alcohol dehydrogenases/reductases (SDR) are two enzyme families that catalyze unusual tailoring reactions in the biosynthesis of natural products. In the experimental section, functions of homologous FPMO and SDR tailoring enzymes from five different angucycline pathways were studied in vitro. The results revealed how different angucyclinones are produced from a common intermediate and that FPMO JadH and SDR LanV are responsible for the divergence of jadomycins and landomycins, respectively, from other angucyclines. Structural studies of these tailoring enzymes revealed differences between homologous enzymes and enabled the use of structure-based protein engineering. Mutagenesis experiments gave important information about the enzymes behind the evolution of distinct angucycline metabolites. These experiments revealed a correlation between the substrate inhibition and bi-functionality in JadH homologue PgaE. In the case of LanV, analysis of mutagenesis results revealed that the difference between the stereospecificities of LanV and its homologues CabV and UrdMred is unexpectedly related to the conformation of the substrate rather than to the structure of the enzyme. Altogether, the results presented here have improved our knowledge about different steps of angucycline biosynthesis and the reaction mechanisms used by the tailoring enzymes behind these steps. This information can hopefully be used to modify these enzymes to produce novel metabolites, which have new biological targets or possess novel modes-of-action. The understanding of these unusual enzyme mechanisms is also interesting to enzymologists outside the field of natural product research.

Torrefioidun biohiilipelletin kirjallisuustutkimus ja koeajot pilottilaitoksessa

Tämä raportti käsittelee ”Torrefioidun biohiilipelletin laatu ja varastoitavuus” hankkeen tuloksia. Hankkeen tavoitteena oli tutkia torrefioidun biohiilipelletin prosessiteknologiaa, markkinoita ja tuotantokustannuksia kirjallisuustutkimusosiossa. Hankkeen päätutkimus keskittyi koeajoihin pilottilaitoksella, jossa valmistettiin biohiilipellettiä erilaisista puuraaka-aineista. Pilottilaitos oli perustettu Torrec Oy:n toimesta Etelä-Savon Energian Pursialan voimalaitoksen yhteyteen Mikkelissä ja sen tuotanto oli käynnistynyt kesällä 2014. Kaikki koe-erät valmistettiin vain käyttämällä sidonta-aineena lauhdevettä, jota oli tiivistynyt säiliön pohjalle torrefiointiprosessin aikana. Näin ollen erillistä lisäsidonta-aineita ei tarvittu, jolloin voidaan säästää tuotantokustannuksissa jatkossakin. Euroopan Unioni on asettanut 20 % tavoitteen uusiutuvien energioiden käytölle vuoteen 2020, josta biomassalla voidaan kattaa kaksi kolmannesta. Tutkimushankkeen tavoitteena oli metsään perustuvan bioenergiatuotannon lisääminen ja tuontienergian korvaaminen kotimaisella polttoaineella. Hankkeen tarkoituksena oli tutkimusanalyysien kautta kehittää uutta kilpailukykyistä teknologiavaihtoehtoa puupolttoaineiden hyödyntämiseksi. Torrefiointiteknologiaa ollaan kaupallistamassa ympäri Eurooppaa parasta aikaa ja uusia biohiilen tuotantolaitoksia on kehitteillä ja rakenteilla. Tutkimuksen tulokset osoittavat, että biohiilipelletillä on mahdollisuudet suurimittakaavaiseen energiantuotantoon laadun suhteen, kunhan sen käyttäminen tulee edullisemmaksi laitoksissa. Toisaalta, tämä kehitys vaatii tukimekanismeja valtion puolelta, jotta pelletit lähtisivät todella liikkeelle markkinoilla.

Yleinen suhteellisuusteoria : Albert Einsteinin mestariteos

Referee-artikkeli

Droplet Deposition in the Last Stage of Steam Turbine

During the expansion of steam in turbine, the steam crosses the saturation line and hence subsequent turbine stages run under wet condition. The stages under wet condition run with low efficiency as compared to stages running with supersaturated steam and the life of the last stage cascade is reduced due to erosion. After the steam crosses the saturation line it does not condense immediately but instead it becomes supersaturated which is a meta-stable state and reversion of equilibrium results in the formation of large number of small droplets in the range of 0.05 - 1 μm. Although these droplets are small enough to follow the stream lines of vapor however some of the fog droplets are deposited on the blade surface. After deposition they coagulate into films and rivulets which are then drawn towards the trailing edge of the blade due to viscous drag of the steam. These large droplets in the range of radius 100 μm are accelerated by steam until they impact on the next blade row causing erosion. The two phenomenon responsible for deposition are inertial impaction and turbulent-diffusion. This work shall discuss the deposition mechanism in steam turbine in detail and numerically model and validate with practical data.