25 resultados para Frustrated Lewis Pair
em Consorci de Serveis Universitaris de Catalunya (CSUC), Spain
Resumo:
A Pair of Blue Eyes ha estat considerada tradicionalment como el primer exemple de pessimisme i fatalisme en les novel·les de Hardy. Aquest treball pretén mostrar que la novel·la no segueix aquest patró, sinó que en base al model aristotèlic de catarsis, mostra l’ error que suposa seguir falsos models amorosos.
Resumo:
We include solvation effects in tight-binding Hamiltonians for hole states in DNA. The corresponding linear-response parameters are derived from accurate estimates of solvation energy calculated for several hole charge distributions in DNA stacks. Two models are considered: (A) the correction to a diagonal Hamiltonian matrix element depends only on the charge localized on the corresponding site and (B) in addition to this term, the reaction field due to adjacent base pairs is accounted for. We show that both schemes give very similar results. The effects of the polar medium on the hole distribution in DNA are studied. We conclude that the effects of polar surroundings essentially suppress charge delocalization in DNA, and hole states in (GC)n sequences are localized on individual guanines
Resumo:
In the assignment game framework, we try to identify those assignment matrices in which no entry can be increased without changing the coreof the game. These games will be called buyer¿seller exact games and satisfy the condition that each mixed¿pair coalition attains the corresponding matrix entry in the core of the game. For a given assignment game, a unique buyerseller exact assignment game with the same core is proved to exist. In order to identify this matrix and to provide a characterization of those assignment games which are buyer¿seller exact in terms of the assignment matrix, attainable upper and lower core bounds for the mixed¿pair coalitions are found. As a consequence, an open question posed in Quint (1991) regarding a canonical representation of a ¿45o¿lattice¿ by means of the core of an assignment game can now be answered
Resumo:
We calculate the production of two b-quark pairs in hadron collisions. Sources of multiple pairs are multiple interactions and higher order perturbative QCD mechanisms. We subsequently investigate the competing effects of multiple b-pair production on measurements of CP violation: (i) the increase in event rate with multiple b-pair cross sections which may reach values of the order of 1 b in the presence of multiple interactions and (ii) the dilution of b versus b tagging efficiency because of the presence of events with four B mesons. The impact of multiple B-meson production is small unless the cross section for producing a single pair exceeds 1 mb. We show that even for larger values of the cross section the competing effects (i) and (ii) roughly compensate so that there is no loss in the precision with which CP-violating CKM angles can be determined.
Resumo:
L'objectiu d'aquest article és mostrar els parámetres clàssics de Shadowlands de R. Attenborough, amb guió de W. Nicholson, sobre la vida i obra de C. S. Lewis. Basant-se en una anàlisi acurada dels textos de Lewis, l'autor proposa d'interpretar l'oposició Lewis / Gresham com la traducció en la vida real de la oposició entre els temperaments platònic o idealista i aristotèlic o materialista que ja mencionava Coleridge. En qualsevol cas, són moltes les referències clàssiques que cal tenir en compte si volem comprendre fins a quin punt el cristianisme de Lewis és també un cristianisme clàssic, és a dir, grecollatí.
Resumo:
El objetivo de este artículo es mostrar los parámetros clásicos de Shadowlands de R. Attenborough, con guión de W. Nicholson, sobre la vida y obra de C. S. Lewis. Basándose en un análisis minucioso de los textos de Lewis, el autor propone interpretar la oposición Lewis / Gresham como la traducción en la vida real de la oposición entre los temperamentos platónico o idealista y aristotélico o materialista que ya mencionaba Coleridge. En cualquier caso, son muchas las referencias clásicas que hay que tener en cuenta si se quiere comprender hasta qué punto el cristianismo de Lewis es también un cristianismo clásico, es decir grecolatino.
Resumo:
The aim of this article is to show the classical parameters of Shadowlands by R. Attenborough, with a screenplay by W. Nicholson, on C. S. Lewis's life and work. Based upon an accurate reading of Lewis's works, the author of this article proposes to interpret the opposition Lewis / Gresham as the translation into the real life of the opposition between the Platonic or idealistic and the Aristotelian or materialistic temperaments which was already maintained by Coleridge. In any case, there are many classical references which must be taken into account in order to understand to what extent C. S. Lewis's Christianity is also a classic Christianity, that is, a Greek and Latin one.
Resumo:
We use the method of Bogolubov transformations to compute the rate of pair production by an electric field in (1+1)-dimensional de Sitter space. The results are in agreement with those obtained previously using the instanton methods. This is true even when the size of the instanton is comparable to the size of the de Sitter horizon.
Resumo:
We argue that production of charged black hole pairs joined by a cosmic string in the presence of a magnetic field can be analyzed using the Ernst metric. The effect of the cosmic string is to pull the black holes towards each other, opposing to the background field. An estimation of the production rate using the Euclidean action shows that the process is suppressed as compared to the formation of black holes without strings.
Resumo:
A general method to find, in a systematic way, efficient Monte Carlo cluster dynamics among the avast class of dynamics introduced by Kandel et al. [Phys. Rev. Lett. 65, 941 (1990)] is proposed. The method is successfully applied to a class of frustrated two-dimensional Ising systems. In the case of the fully frustrated model, we also find the intriguing result that critical clusters consist of self-avoiding walk at the theta point.
Resumo:
We consider a Potts model diluted by fully frustrated Ising spins. The model corresponds to a fully frustrated Potts model with variables having an integer absolute value and a sign. This model presents precursor phenomena of a glass transition in the high-temperature region. We show that the onset of these phenomena can be related to a thermodynamic transition. Furthermore, this transition can be mapped onto a percolation transition. We numerically study the phase diagram in two dimensions (2D) for this model with frustration and without disorder and we compare it to the phase diagram of (i) the model with frustration and disorder and (ii) the ferromagnetic model. Introducing a parameter that connects the three models, we generalize the exact expression of the ferromagnetic Potts transition temperature in 2D to the other cases. Finally, we estimate the dynamic critical exponents related to the Potts order parameter and to the energy.
Resumo:
We numerically study the dynamical properties of fully frustrated models in two and three dimensions. The results obtained support the hypothesis that the percolation transition of the Kasteleyn-Fortuin clusters corresponds to the onset of stretched exponential autocorrelation functions in systems without disorder. This dynamical behavior may be due to the large scale effects of frustration, present below the percolation threshold. Moreover, these results are consistent with the picture suggested by Campbell et al. [J. Phys. C 20, L47 (1987)] in the space of configurations.
Resumo:
To understand the origin of the dynamical transition, between high-temperature exponential relaxation and low-temperature nonexponential relaxation, that occurs well above the static transition in glassy systems, a frustrated spin model, with and without disorder, is considered. The model has two phase transitions, the lower being a standard spin glass transition (in the presence of disorder) or fully frustrated Ising (in the absence of disorder), and the higher being a Potts transition. Monte Carlo results clarify that in the model with (or without) disorder the precursor phenomena are related to the Griffiths (or Potts) transition. The Griffiths transition is a vanishing transition which occurs above the Potts transition and is present only when disorder is present, while the Potts transition which signals the effect due to frustration is always present. These results suggest that precursor phenomena in frustrated systems are due either to disorder and/or to frustration, giving a consistent interpretation also for the limiting cases of Ising spin glass and of Ising fully frustrated model, where also the Potts transition is vanishing. This interpretation could play a relevant role in glassy systems beyond the spin systems case.