Importance of the embedding environment on the strain within small rings in siliceous materials

The effect of the local environment on the energetic strain within small (SiO)N rings (with N=2,3) in silica materials is investigated via periodic model systems employing density functional calculations. Through comparison of the energies of various nonterminated systems containing small rings in strained and relatively unstrained environments, with alpha quartz, we demonstrate how small ring strain is affected by the nature of the embedding environment. We compare our findings with numerous previously reported calculations, often predicting significantly different small-ring strain energies, leading to a critical assessment of methods of calculating accurate localized ring energies. The results have relevance for estimates of the strain-induced response (e.g., chemical, photo, and radio) of small silica rings, and the propensity for them to form in bulk glasses, thin films, and nanoclusters.

Ultralow-density nanocage-based metal-oxide polymorphs

For two important metal oxides (MO, M=Mg, Zn) we predict, via accurate electronic structure calculations, that new low-density nanoporous crystalline phases may be accessible via the coalescence of nanocluster building blocks. Specifically, we consider the assembly of cagelike (MO)12 clusters exhibiting particularly high gas phase stability, leading to new polymorphs with energetic stabilities rivaling (and sometimes higher) than those of known MO polymorphs.

Lyra Viol “Instrument de música domèstica”

El propòsit d'aquest treball és donar a conèixer la lyra viol i la seva música. Entre d'altres maneres de tocar aquest instrument, mostrar com aquest servia per acompanyar la veu, així com arranjar peces polifòniques tal i com trobem en publicacions de l'època. I serà a partir d'aquests exemples, que he fet els meus propis arranjaments per a viola de gamba i que incloc en aquest treball.

El neolític antic i l"inici de l"edat del bronze a les excavacions del nou conservatori del Liceu

[cat] En aquest article es presenta l"estudi interdisciplinari de les ocupacions prehistòriques recents (neolític i inici de l"edat del bronze) localitzades durant la construcció del Conservatori del Gran Liceu de Barcelona, al barri del Raval de la mateixa ciutat. Les restes ocupacionals corresponen a un assentament amb evidències d"estructures de combustió i diversos elements de suport. Hi destaca la conservació d"alguns magnífics fogars, així com un conjunt de materials abiòtics i biòtics que permeten augmentar el coneixement de les primeres comunitats agrícoles del Pla de Barcelona. [spa] En este artículo se presenta el estudio interdisciplinar de las ocupaciones prehistóricas recientes (Neolítico e inicio de la Edad del Bronce) localizadas durante la construcción del Conservatorio del Gran Liceo de Barcelona, en el barrio del Raval de la misma ciudad. Los restos de ocupación corresponden a un asentamiento con evidencias de estructuras de combustión y otros elementos de soporte. Entre ellos destaca la conservación de algunos magníficos hogares así como un conjunto de materiales abióticos y bióticos que permiten aumentar el conocimiento sobre las primeras comunidades agrícolas del llano de Barcelona. [eng] This paper presents the interdisciplinary study of the recent prehistoric occupations (Neolithic and Early Bronze Age) found during the construction of El Liceu Conservatoire in Barcelona"s El Raval district. Occupational remains correspond to a settlement with traces of combustion structures and several supporting elements. It emphasises the preservation of some magnificent fireplaces and a set of archaeological abitoic and biotic materials that can increase knowledge of the first farming communities in the Barcelona plain. [fra] Cet article présente l"étude interdisciplinaire des occupations préhistoriques récentes (néolithique et début de l"âge du bronze) localisées lors de la construction du Conservatoire du Grand Théâtre du Liceu (opéra) de Barcelone, dans le quartier du Raval. Les vestiges d"occupation correspondent à un établissement présentant des structures de combustion et différents éléments de support. On y remarque la conservation de quelques magnifiques foyers ainsi qu"un ensemble de matériaux abiotiques et biotiques qui peuvent enrichir les connaissances sur les premières communautés agricoles de la plaine de Barcelone.

Review and new therapeutic alternatives for the treatment of cutaneous Leishmaniasis

Leishmaniasis comprises a group of diseases caused by protozoa of the genus Leishmania and has two basic clinical forms, visceral Leishmaniasis and cutaneous Leishmaniasis. The clinical features of Leishmaniasis depend on the species of Leishmania, the interaction between host and parasite and the immune response. This work focuses on cutaneous leishmaniosis because although it is not a deadly disease it results in significant scars and facial disfigurements, thus being clinically important. Furthermore, the first-line treatment consists of intravenous or intramuscular administration of intralesional pentavalent antimonials, which are highly toxic, making hospitalization of patients compulsory during treatment, with the associated financial costs. Herein, we review studies on drugs and treatments with fewer side effects and easier routes of administration such as topical administration. Recent research shows that the topical route of administration holds promise for the future treatment of cutaneous leishmaniosis.

Review and new therapeutic alternatives for the treatment of cutaneous Leishmaniasis

Leishmaniasis comprises a group of diseases caused by protozoa of the genus Leishmania and has two basic clinical forms, visceral Leishmaniasis and cutaneous Leishmaniasis. The clinical features of Leishmaniasis depend on the species of Leishmania, the interaction between host and parasite and the immune response. This work focuses on cutaneous leishmaniosis because although it is not a deadly disease it results in significant scars and facial disfigurements, thus being clinically important. Furthermore, the first-line treatment consists of intravenous or intramuscular administration of intralesional pentavalent antimonials, which are highly toxic, making hospitalization of patients compulsory during treatment, with the associated financial costs. Herein, we review studies on drugs and treatments with fewer side effects and easier routes of administration such as topical administration. Recent research shows that the topical route of administration holds promise for the future treatment of cutaneous leishmaniosis.

Functional diversity of macrophyte communities within and between Pyrenean lakes

Submersed vegetation is a common feature in about 70% Pyrene an high mountain (>1500 m a.s.l.) lakes. Isoetids and soft-water elodeids are common elements of this underw ater flora and can form distinct vegetation units (i.e. patches of vegetation dominated by different species) within complex mosaics of vegetation in shallow waters (<7 m). Since is oetids exert a strong influence on sediment biogeochemistry due to high radial oxygen loss, we examined the small scale characteristics of the lake environment (water and sediment) associated to vegetation patches in order to ascertain potential functional differences among them. To do so, we characterised the species composition and biomass of the main vegetation units from 11 lakes, defined plant communities based on biomass data, and then related each community with sediment properties (redox and dissolved nutrient concentration in the pore water) and water nutrient concentration within plant canopy. We also characterised lake water and sediment in areas without vegetation as a reference. A total of twenty-one vegetation units were identified, ranging from one to five per lake. A cluster analysis on biomass species composition suggested seven different macrophyte communities that were named after the most dominant species:Nitella sp.,Potamogeton praelongus, Myriophyllum alterniflorum, Sparganium angustifolium , Isoetes echinospora,Isoetes lacustris and Carex rostrata . Coupling between macrophyte communities and their immediate environment (overlying water and sediment) was manifested mainly as variation in sediment redox conditions and the dominant form of inorganic nitrogen in pore-water. These effects depended on the specific compositi on of the community, and on the allocation between above- and belowground biomass, and could be predicted with a model relating the average and standard deviation of sediment redox potential from 0 down to -20 cm, across macrophyte communities. Differences in pore-water total dissolved phosphorus were related to the trophic state of the lakes. There was no correlation between sediment and water column dissolved nutrients. However, nitrate concentrations tended to be lower in the water overlaying isoetid communities, in apparent contradiction to the patterns of dissolved nitrates in the pore-water. These tendencies were robust even when comparing the water over laying communities within the same lake, thus pointing towards a potential effect of isoetids in reducing dissolved nitrogen in the lakes.