Ophiolite-related ultramafic rocks (Serpentinites) in the Caribbean region: a review of their occurrence, composition, origin, emplacements and Ni-Laterite soil formation

Ultramafic rocks, mainly serpentinized peridotites of mantle origin, are mostly associated with the ophiolites of Mesozoic age that occur in belts along three of the margins of the Caribbean plate. The most extensive exposures are in Cuba. The ultramafic-mafic association (ophiolites) were formed and emplaced in several different tectonic environments. Mineralogical studies of the ultramafic rocks and the chemistry of the associated mafic rocks indicate that most of the ultramafic-mafic associations in both the northern and southern margins of the plate were formed in arc-related environments. There is little mantle peridotite exposed in the ophiolitic associations of the west coast of Central America, in the south Caribbean in Curacao and in the Andean belts in Colombia. In these occurrences the chemistry and age of the mafic rocks indicates that this association is mainly part of the 89 Ma Caribbean plateau province. The age of the mantle peridotites and associated ophiolites is probably mainly late Jurassic or Early Cretaceous. Emplacement of the ophiolites possibly began in the Early Cretaceous in Hispaniola and Puerto Rico, but most emplacement took place in the Late Cretaceous to Eocene (e.g. Cuba). Along the northern South America plate margin, in the Caribbean mountain belt, emplacement was by major thrusting and probably was not completed until the Oligocene or even the early Miocene. Caribbean mantle peridotites, before serpentinization, were mainly harzburgites, but dunites and lherzolites are also present. In detail, the mineralogical and chemical composition varies even within one ultramafic body, reflecting melting processes and peridotite/melt interaction in the upper mantle. At least for the northern Caribbean, uplift (postemplacement tectonics) exposed the ultramafic massifs as a land surface to effective laterization in the beginning of the Miocene. Tectonic factors, determining the uplift, exposing the peridotites to weathering varied. In the northern Caribbean, in Guatemala, Jamaica, and Hispaniola, uplift occurred as a result of transpresional movement along pre-existing major faults. In Cuba, uplift occurred on a regional scale, determined by isostatic adjustment. In the south Caribbean, uplift of the Cordillera de la Costa and Serrania del Interior exposing the peridotites, also appears to be related to strike-slip movement along the El Pilar fault system. In the Caribbean, Ni-laterite deposits are currently being mined in the central Dominican Republic, eastern Cuba, northern Venezuela and northwest Colombia. Although apparently formed over ultramafic rocks of similar composition and under similar climatic conditions, the composition of the lateritic soils varies. Factors that probably determined these differences in laterite composition are geomorphology, topography, drainage and tectonics. According to the mineralogy of principal ore-bearing phases, Dominican Ni-laterite deposits are classified as the hydrous silicate-type. The main Ni-bearing minerals are hydrated Mg-Ni silicates (serpentine and ¿garnierite¿) occurring deeper in the profile (saprolite horizon). In contrast, in the deposits of eastern Cuba, the Ni and Cooccurs mainly in the limonite zone composed of Fe hydroxides and oxides as the dominant mineralogy in the upper part of the profile, and are classified as the oxide-type.

Geochemical exploration in the Montseny Mountains (NE Spain)

A five year program of systematic multi-element geochemical exploration of the Catalonian Coastal Ranges has been initiated by the Geological Survey of Autonomic Government of Catalonia (Generalitat de Catalunya) and the Department of Geological and Geophysical Exploration (University of Barcelona). This paper reports the first stage results of this regional survey, covering an area of 530 km2 in the Montseny Mountains, NE of Barcelona (Spain). Stream sediments for metals and stream waters for fluoride were chosen because of the regional characteristics. Four target areas for future tactic survey were recognized after the prospect. The most important is a 40 km* zone in the Canoves-Vilamajor area, with high base metal values accompanied by Cd, Ni, Co, As and Sb anomalies. Keywords: Catalanides. Geochemical exploration. Stream sediments. Base metal anomalies. Principal Component Analysis.

Elements traça en esfalerites i galenes del dipòsit de Cierco (Pb-Zn). Alta Ribagorça, Pirineu Central

El diposit consisteix en dos filons E-W, tallats per un altre N-S. El rebliment filonia ès zonat amb esfalerita- galena-calcita als nivells profunds i galena-baritina als superiors. Els elements traça en esfalerites i galenes, plenament separades, han estat analitzats mitjancant fluorescència de raigs X. Els resultats mostren que l'esfalerita concentra la majoria d'elements traça, preferentment Fe, Co, Cd, Sn, Sb, Ga, Cu, Ge i Ag, amb una bona correlació entre els sis primers. La galena concentra únicament Sb, Ag i As, amb bona correlació entre els dos primers. Els continguts en elements traça estan homogèniament distribuits en tot el diposit.

Magmatismo paleozoico en el Macizo del Roc de Frausa (Pirineos Orientales)

En el Macizo del Roc de Frausa se han diferenciado mediante criterios geoquímicos dos tipos diferentes de anfibolitas. El primer tipo lo forman metabasitas de afinidad toleitica y composición próxima a los E-MOIIB. Proceden de magmas poco evolucionados moderadamente bajos en potasio. Forman sills intercalados entre los metasedimentos cambro-ordovícicos y están asociadas a porfiroides gneísicos. Los porfiroides gneisicos representan términos ácidos subaluminicos de carácter explosivo y afinidad calcoalcalina con un contenido medio en potasio. Su relación genética con las metabasitas es poco clara; se interpretan como diferenciados ácidos de estas con una importante mezcla de material cortical. Se sugiere para este magmatismo un ámbito geodinámico continental fini-compresivo en relación con cucncas marginales.

Procesos de alteración de materiales pétreos en edificios de interés histórico

Sin pretender ser un trabajo exhaustivo, se exponen las bases generales y las fases de estudio que se realizan actualmente en los trabajos técnicos de diagnosis sobre el estado de conservación de un monumento, como paso previo a la restauración. Los estudios de diagnosis se centran habitualmente en la acción de la contaminación (como factor extrínseco) y en el estudio de la porosidad de la roca y sus propiedades hídncas (como factores intrínsecos). Además de estos factores existen otros procesos de alteración que tienen su origen en la naturaleza mineralógica y sus caractensticas cristaloquímicas (fábricas cristalinas, fases de cemento); se trata de mecanismos que pueden ser determinantes en alteración y que pueden pasar desapercibidos si no se realiza un estudio petrológico y cristaloquimico en profundidad, especialmente con las nuevas técnicas de microscopía electrónica y de análisis puntual con sonda de electrones.

Fifth-order cyclicity and organic matter contents relationship (Lower Eocene, Pyrenees)

The Upper Limestone Member of the Corones Formation of the Spanish Pyrenees consists of various units (Lower and Upper Foraminifera Units, Shale Unit, Cherty-ostracode Unit, Ostracode Unit and Chara-ostracode Unit) and offers strong facies and lateral thickness (20 to 80 m) variations. Detailed facies analyses, fifth-order cycles and organic geochemical determinations in the central domain of the Corones platform carbonates (Cherty-ostracode Unit), lower Eocene in age, were carried out to establish a case of close relationship between variations in organic matter productivity and cyclicity with annual period. The Cherty-ostracode Unit displays a continuous and pervasive fifth-order cyclicity, represented by 5 cycles. Each cycle consists of a lower part (mollusc facies) and an upper part (laminated ostracode facies). The calculated fifth-order cycle period ranges from about 17,000 to 28,000 years, which falls within the Milankovitch Band. Variations in organic matter content related to these carbonate cycles have been established. The lower mollusc facies members show a low organic carbon content and Hydrogen Index (HI) below 0.6% in weight and 261, respectively. By contrast, the upper laminated ostracode facies members show high organic carbon contents (up to 2% in weight) and high HI (between 164 and 373), and are also characterized by important silicification processes (the content in chert is up to 30%). The organic geochemistry resulting from these organic rich levels reflects a contribution of algal marine input.

Técnicas composicionales para concentraciones geoquímicas por debajo del límite de detección

In most geochemical analyses log-ratio techniques are required to analyse compositional data sets. When a chemical element is present at a low concentration in is usally identified as a value below the detection límit and added to the data set either as zero or simply by attaching a less-than label. In any case, the occirrence of such concentration prevents us from applying the log-ratio approach. We review here the tehoretical bases of the most recent proposals for dealing with these types of observation, give some advice on their practical application and illustrate their performance throgh some examples using geochemical data

Aplicación de la técnica de espectrometría de fluorescencia de rayos-X en el estudio de la dispersión de metales en áreas mineras

One critical factor for success in characterizing metals polluting mining environments so as to be able to eliminate them and subsequently recover these areas depends upon a speedy and correct response in the analysis of samples. Rapid, simultaneous, multi-element analysis can be undertaken using X-ray fluorescence spectrometry, a versatile, non-destructive analytical technique commonly employed to identify both major and minor elements in samples related to environmental studies. An additional advantage of this technique is the possibility of conducting the analysis directly on solid samples, which is extremely convenient when dealing with environmental samples that are difficult to dissolve, such as soils, sediments and mining wastes. Moreover, in recent years the development of spectrometers equipped with digital-signal processors combined with enlarged X-ray production, using better designs for excitation-detection, has contributed to an improvement in instrumental sensitivity, thus allowing us to detect important polluting elements such as Cd and Pb at trace levels. In this paper the authors describe, on the basis of their own experience, some interesting applications of XRF spectrometry for the analysis of several types of environmental samples related to the study of the dispersion of metals within mining environments: (A) analysis of mining wastes, soils and sediments; (B) analysis of samples of vegetation used as bioindicators or related to phytoremediation studies; and (C) analysis of water samples related to mining operations

Características geoquímicas de la formación de sales potásicas de Navarra (Eoceno superior). Comparación con la cuenca potásica catalana

Se estudia la distribución de una serie de elementos mayoritarios (Na, K, Ca, Mg) y minoritarios (Li, Rb, Sr, Fe, Br) en las sales de los yacimientos de la cuenca potásica navarra. Se insiste en un dispositivo de cubeta asimétrica, con acumulación marginal de las salmueras más densas, para explicar algunas anomalías en la distribución vertical de bromo dentro el yacimiento. Se concluye que, desde el punto de vista geoquímico, dicha formación evaporítica es semejante a su homóloga catalana, tratándose de sales marinas y básicamente primarias. Las paragénesis de silvinita transformada son secundarias. Su génesis a partir de carnalita se pone de manifiesto tanto desde el punto de vista petrográfico, como geoquímico y mineralógico.

A detailed stream sediment Geochemical survey in the Canoves St. Pere de Vilamajor area (Montseny massif. NE Spain)

Se ha realizado una prospección geoquímica táctica de sedimentos aluviales en el Brea de Cánoves-St. Pere de Vilamajor (Macizo del Montseny, Barcelona), como consecuencia de una exploración geoquimica estratégica de sedimentos aluviales previa, en la que se localizó un Brea anómala en Pb, Zn, Cu, As, Cd, Ni, y Co. El Brea estudiada tiene 35 km2 y esta constituida por materiales sedimentarios y volcánicos del Paleozoico, metamorfizados en mayor o menor grado e intruidos por el granito de Vallfornés, y materiales detríticos terciarios...

Los filones plumbíferos de Linares (Jaen) son continuos hasta el paleocaliche de la base del Trias

El area de Linares (Jaen) pertenece al distrito minero de Linares-La Carolina. caracterizado por filones de ankerita y galena, principalmente de gran longitud y extensión vertical, encajados en materiales hercinicos. Cerca de Linares, entre los pozs La Esmeralda y San Juan puede observarse como todos los constituyentes del relleno de los Filones del zocalo cortan igualmente al paleosuelo carbonatado de la base del trias.

Estudio geoquímico preliminar de diversas muestras salinas de Sallent y Balsareny (Barcelona, España)

Se exponen los métodos analíticos seguidos en el estudio de muestras salinas extraídas de la Cuenca Potásica Catalana poniendo interés especial en las pertenecientes a 'zonas de esterilización'. Estas 'zonas de esterilización' o 'zonas de empobrecimiento total' (Borchert, 1969) son planos de cizalla en la masa salina estratificada.

Aplicación de criterios geoquímicos al reconocimiento de medios hipersalinos en los materiales arcillosos terciarios de la Depresión Central Catalana

El efecto de distintos cidos en la puesta en solución de cationes adsorbidos en los minerales de las arcillas ha sido tratado a menudo, tanto desde el punto de vista del estudio de sedimentos arcillosos como del análisis de elementos traza en carbonatos. En este trabajo se estudia el comportamiento de algunos cationes frente al lavado con agua destilada y con ácido actico (20 % v/v). Asimismo se comparan las concentraciones de cationes en las soluciones de lavado de sedimentos depositados en medios de distinta salinidad. Se observa que, comparando sedimentos de composición mineralógica parecida, las concentraciones de sodio, potasio, litio y magnesio de muestras depositadas en ambientes hipersalinos son mucho más elevadas que las depositadas en ambientes de salinidad menor.