Analcime crystallization and compositional profiles - Comparing approaches to detect post-depositional alterations in archaeological pottery

The approaches of comparative studies and profile measurements, often used in order to detect post-depositional alterations of ceramics, have been applied simultaneously to two sets of Roman pottery, both of which include altered individuals. As analytical techniques, Neutron Activation Analysis and X-Ray Diffraction have been used. Both approaches lead to substantially different results. This shows that they detect different levels of alteration and should complement each other rather than being used exclusively. For the special process of a glassy phase decomposition followed by a crystallization of the Na-zeolite analcime, the results suggest that it changes high-fired calcareous pottery rapidly, and so fundamentally that the results of various archaeometric techniques can be severely disturbed.

Un conjunt de materials d'època tardo-republicana de la ciutat romana de Pollentia (Alcúdia, Mallorca)

El pou D 18, situat a la part sud-oest de la zona coneguda del forum de Pollentia, fou amortitzat en el segon quart del segle 1 a.C. EIs materials que formaven part del farciment constitueixen un conjunt tancat representatiu sobretot deIs tipus ceramics locals i d'importació utilitzats en aquesta epoca. El volum principal d'importacions correspon als productes italics, seguits a gran distancia pels materials púnics, iberics i egeus.

Designing and testing of a sensor based on a magnetoresistive manganese perovskite thick film

In this paper we report on the growth of thick films of magnetoresistive La2/3Sr1/3MnO3 by using spray and screen printing techniques on various substrates (Al2O3 and ZrO2). The growth conditions are explored in order to optimize the microstructure of the films. The films display a room-temperature magnetoresistance of 0.0012%/Oe in the 1 kOe field region. A magnetic sensor is described and tested.

Production of nanometric particles in radio frequency glow discharges in mixtures of silane and methane

The formation of silicon particles in rf glow discharges has attracted attention due to their effect as a contaminant during film deposition or etching. However, silicon and silicon alloy powders produced by plasma¿enhanced chemical vapor deposition (PECVD) are promising new materials for sintering ceramics, for making nanoscale filters, or for supporting catalytic surfaces. Common characteristics of these powders are their high purity and the easy control of their stoichiometry through the composition of the precursor gas mixture. Plasma parameters also influence their structure. Nanometric powders of silicon¿carbon alloys exhibiting microstructural properties such as large hydrogen content and high surface/volume ratio have been produced in a PECVD reactor using mixtures of silane and methane at low pressure (-1 Torr) and low frequency square¿wave modulated rf power (13.56 MHz). The a¿Si1¿xCx:H powders were obtained from different precursor gas mixtures, from R=0.05 to R=9, where R=[SiH4]/([SiH4]+[CH4]). The structure of the a¿Si1¿xCx:H powder was analyzed by several techniques. The particles appeared agglomerated, with a wide size distribution between 5 and 100 nm. The silane/methane gas mixture determined the vibrational features of these powders in the infrared. Silicon-hydrogen groups were present for every gas composition, whereas carbon¿hydrogen and silicon¿carbon bonds appeared in methane¿rich mixtures (R-0.6). The thermal desorption of hydrogen revealed two main evolutions at about 375 and 660¿°C that were ascribed to hydrogen bonded to silicon and carbon, respectively. The estimated hydrogen atom concentration in the sample was about 50%.

Playas fósiles sumergidas en la Costa Brava Meridional (Girona)

This paper describes petrologic and morphologic characteristics of fossil beaches submerged in the sector of the Costa Brava located between the Pals Beach and Blanes (Girona). These submerged beaches are composed of large-grain sandstone andconglomerate platforms, situated at a depth between 0.5 and 2.5 meters. These platforms are slightly inclinated towards the open sea. These deposits have been formed very recently, and date from Holocene, as noted by the presence of fragments of roman ceramics inside sandstone

The use of micro-XRD for the study of glaze color decorations

The compounds responsible for the colours and decorations in glass and glazed ceramics include: colouring agents (transition metal ions), pigments (micro-and nano-precipitates of compounds that either do not dissolve or recrystallize in the glassy matrix) and opacifiers (microcrystalline compounds with high light scattering capability). Their composition, structure and range of stability are highly dependent not only on the composition but also on the procedures followed to obtain them. Chemical composition of the colorants and crystallites may be obtained by means of SEM-EDX and WDX. Synchrotron Radiation micro-X-ray Diffraction has a small beam size adequate (10 to 50 microns footprint size) to obtain the structural information of crystalline compounds and high brilliance, optimal for determining the crystallites even when present in low amounts. In addition, in glass decorations the crystallites often appear forming thin layers (from 10 to 100 micrometers thick) and they show a depth dependent composition and crystal structure. Their nature and distribution across the glass/glazes decorations gives direct information on the technology of production and stability and may be related to the color and appearance. A selection of glass and glaze coloring agents and decorations are studied by means of SR-micro- XRD and SEM-EDX including: manganese brown, antimony yellow, red copper lusters and cobalt blue. The selection includes Medieval (Islamic, and Hispano Moresque) and renaissance tin glazed ceramics from the 10th to the 17th century AD.

El poblament rural del Camp de Tarragona en època tardo-republicana (segles II-I aC)

This project consists of a study of the settlement of population during the Late Republican period in the Camp de Tarragona, an extensive agricultural plain in the shape of a crescent moon opening out towards the sea which constitutes the area of land in closest proximity to the capital, Tarraco. It does not therefore include the entirety of the ager Tarraconensis, which covered a considerably larger area. After reviewing the preceding Iberian presence in the area, the study focuses on the archaeological evidence corroborating the settlement of population referred to above and its evolution during the course of the two centuries prior to the rule of Augustus. Attention is also given to certain speciic themes, such as the centuriation of certain sectors, the presence of military checkpoints, the production of ceramics during the Republican period (at Fontscaldes and Valls) and the appearance of the irst Roman villas (El Moro and El Mas d’en Gras).

LRCW.NET: A web site with a virtual laboratory for the study of coarse and cooking wares in the Late Antique Mediterranean

This contribution presents the LRCW.net a website with a virtual laboratory intranet devoted to the study of coarse and cooking wares in the late Antique Mediterranean. It is designed as a public website with a virtual laboratory intranet. There, all institutions and researchers interested in the subject can work together towards a specific purpose such as the creation of an on-line ‘encyclopedia’ for these categories of ceramics. The LRCW.net website and the associated virtual laboratory are just a small part of a wider initiative that aims to create an on-line Encyclopedia for Ancient Ceramics in the Mediterranean.

T.P.M.T., alfarero ilerdense de terra sigillata

Damos noticia del primer alfarero conocido de terrra sigillata de la antigua Ilerda, -aunque no podemos sino conjeturar su nombre completo- tras los análisis de pasta que indican su condición de local. Se incide asimismo en la estimable fabricación de estas cerámicas (buen número de moldes), así como la cronología de las mismas.

Optimización de un nuevo método de preparación de óxidos mixtos tipo perovskita con vacantes de oxígeno.

Se han optimizado las condiciones para la deslitiación de compuestos de fórmula general La2/3-xLi3xTiO3 así como las de la posterior termólisis de compuestos de fórmula general La2/3-xTiO3-3x(OH)3x. En ambos procesos se mantiene la estructura perovskita cúbica Pm3m. Estudios preliminares de conductividad eléctrica indican que los compuestos La2/3-xTiO3-3x/2 obtenidos mediante química suave a partir de la perovskita de lantano y litio se comportan como semiconductores.

Assessment of dissolution techniques for the analysis of ceramic samples by plasma spectrometry

In this study, 13 ceramic samples were subjected to dissolution using three different procedures: (a) acid attack in open PTFE vessels with a mixture of HF-HClO4, (b) fusion of the sample with lithium metaborate and (c) microwave digestion in PTFE bombs. The samples used in the study had been previously analyzed by neutron activation analysis (NAA), X-ray fluorescence (XRF) and X-ray diffraction (XRD) and they cover a wide range of ceramics fired in different atmospheres and temperatures as well as different mineralogical and chemical compositions. The effectiveness of each procedure is evaluated in terms of its ability to dissolve the various mineralogical phases of the samples, of the number of elements that can be determined and of the time needed for the whole scheme of analysis to be completed.

Influencia de la atmosfera de sinterizacion en la estabilidad termica de ceramicas de hidroxiapatita reforzadas con circona

En este trabajo se estudia la influencia de la atmósfera de sinterización sobre la estabilidad térmica de cerámicas de hidroxiapatita (HA) reforzadas con partículas de circona parcialmente estabilizada con magnesia (Mg-PSZ). Los cuerpos verdes fueron obtenidos por prensado uniaxial y las sinterizaciones se realizaron en aire y en oxígeno húmedo. El estudio por difracción de rayos-X y espectroscopía infrarroja permitió comprobar que la atmósfera húmeda evita la descomposición de la hidroxiapatita, todo lo contrario a lo que sucede en aire donde es evidente la presencia del zirconato cálcico (CZ) en la interfaz entre la partícula de circona y la matriz de HA. La caracterización microestructural de los materiales por Microscopía Electrónica de Barrido permitió apreciar el desarrollo de tamaño de grano de los materiales sinterizados. El estudio del comportamiento mecánico mediante ensayos de indentación reveló un aumento de la tenacidad a la fractura en el caso de los materiales que presentaban Mg-PSZ con respecto a la HA pura.

Disseny amforal i canvi tecnològic al voltant del canvi d'era: L'aportació de l'Anàlisi d'Elements Finits

[spa] Mediante el Análisis de Elementos Finitos es posible evaluar un diseño cerámico en función de su tipologia y de las propiedades mecánicas del material. Su aplicación permite considerar los factores tecnológicos que puedan haber condicionado el cambio de una tipologia cerámica. Este análisis se ilustra con los primeros tipos anfóricos romanos producidos en la actual Cataluña (Dressel 1, Tarraconense 1 y Pascuai 7).

Domain matched epitaxial growth of Bi1.5Zn1Nb1.5O7 thin films by pulsed laser deposition

Bi1.5Zn1Nb1.5O7 (BZN) epitaxial thin films were grown by pulsed laser deposition on Al2O3 with a double ZnO buffer layer through domain matching epitaxy (DME) mechanism. The pole figure analysis and reciprocal space mapping revealed the single crystalline nature of the thin film. The pole figure analysis also shows a 60º twinning for the (222) oriented crystals. Sharp intense spots in the SAED pattern also indicate the high crystalline nature of BZN thin film. The Fourier filtered HRTEM images of the BZN-ZnO interface confirms the domain matched epitaxy of BZN with ZnO buffer. An electric field dependent dielectric tunability of 68% was obtained for the BZN thin films with inter digital capacitors patterned over the film.

Caracterizacion por difraccion de rayos-X, analisis termico y espectroscopia Raman de los cristales mixtos Li(NH4)(1-x)KxSO4

En este trabajo se estudia la preparació n y caracterizació n de las fases de los cristales mixtos de f órmula Li(NH4)1-xKxSO4. La caracterizacói n se ha efectuado por aná lisis té rmico con DSC y ATD, difracci ón de rayos-X sobre polvo cristalino con temperatura variable, difracci n de rayos-X sobre muestra monocristalina a temperatura variable a fin de determina su estructura cristalina y por espectroscop"a Raman a temperatura variable. Se han obtenido dos tipos de fases. Una soluci n s lida con 0.94 < x < 1 que presenta los mismos tipos estructurales que el LiKSO4, pero seg n el m todo de cristalizaci n pueden aparecer nuevas fases que no presenta el LiKSO4. El segundo tipo de compuesto tiene por f rmula Li(NH4)0.53K0.47SO4, el cual presenta una estructura hexagonal con par metro a » 3 aLiKSO4. Este compuesto tiene por encima de la temperatura ambiente una sola transici n a 463K.