Use of a pre-sidedress soil nitrate test (PSNT) to determine nitrogen fertilizer requirements for irrigated corn

In the present study, a 2-year N rate response experiment was conducted in different fields to monitor NO3-N soil profiles, N accumulation by the crop and final crop performance, in order to assess if soil NO3-N at pre-sidedressing (Pre-Sidedress Soil Nitrate Test, PSNT) is a reliable indicator for soil N availability for corn in the irrigated area served by canal d’Urgell (Lleida, Spain), and if the test can be used to separate responsive fields from non-responsive fields to sidedress N fertilizer applications. Preliminary soil N availability (N sidedress fertilizer rate + PSNT) critical levels to identify fields that need supplementary N fertilizer applications were established at ca. 300 and 210 kg NO3-N·ha–1, for PSNTrooting–zone and PSNT0–30 cm, respectively (for a yield goal of 14 t grain·ha–1).

Psicofarmacología y drogodependencias. Una respuesta docente en estudiantes de medicina

Se ha diseñado una asignatura optativa y de libre elección, para estudiantes de la Facultad de Medicina, de la Universitat de Lleida. El actual curso académico ha sido el cuarto que se viene realizando dicha asignatura. Por ella ha pasado cerca de 320 alumnos. Se trata de cubrir un vacío habitual en los planes de estudio para futuros médicos, ofreciendo tanto información específica sobre teoría del tema drogas, como experiencias prácticas referidas a modalidades de tratamiento, aspectos preventivos, recursos asistenciales, intervenciones mínimas, etc. La valoración de los alumnos de la experiencia ha sido excelente. Se insiste especialmente en transmitir el modelo bio- psico-social del fenómeno drogas, tanto en su vertiente originaria de la adicción, como en su aspecto terapéutico, por lo que implica el trabajo interdisciplinar entre profesionales.

Sant Llorenç del Montsec (La Noguera): un despoblat medieval

The medieval deserted village of St. Lloreng, a fortified place in the west lands of Catalonia, in Lleida, near Aragon, is studied from its origins in 11th. century unti1 14th.C. The growth and evolution of population during this time is shown by the houses, placed between the castle and the church, some so simply with only one room, some wider. The authors don't know why the village became deserted, but they indicate the possible move of the population into the limits of the Ager valley.

El monument funerari de l'Ardiaca Major de la Seu Vella de Lleida Berenguer Barutell

We know about the tomb of Berenguer Barutell, built in the Seu Vella of Lleid by Rotllí Gaulter, from the Work's Books and the relation of the delivery notes, registered by the same craftman and sculptor. In this study, we can offer all the execution process and the analysis stylistic and iconographic in detail.

A semi-grand canonical Monte Carlo simulation model for ion binding to ionizable surfaces: Proton binding of carboxylated latex particles as a case study

In this paper, we present a computer simulation study of the ion binding process at an ionizable surface using a semi-grand canonical Monte Carlo method that models the surface as a discrete distribution of charged and neutral functional groups in equilibrium with explicit ions modelled in the context of the primitive model. The parameters of the simulation model were tuned and checked by comparison with experimental titrations of carboxylated latex particles in the presence of different ionic strengths of monovalent ions. The titration of these particles was analysed by calculating the degree of dissociation of the latex functional groups vs. pH curves at different background salt concentrations. As the charge of the titrated surface changes during the simulation, a procedure to keep the electroneutrality of the system is required. Here, two approaches are used with the choice depending on the ion selected to maintain electroneutrality: counterion or coion procedures. We compare and discuss the difference between the procedures. The simulations also provided a microscopic description of the electrostatic double layer (EDL) structure as a function of pH and ionic strength. The results allow us to quantify the effect of the size of the background salt ions and of the surface functional groups on the degree of dissociation. The non-homogeneous structure of the EDL was revealed by plotting the counterion density profiles around charged and neutral surface functional groups. © 2011 American Institute of Physics.

Conditional equilibrium constants in multicomponent heterogeneous adsorption: The conditional affinity spectrum

The concept of conditional stability constant is extended to the competitive binding of small molecules to heterogeneous surfaces or macromolecules via the introduction of the conditional affinity spectrum (CAS). The CAS describes the distribution of effective binding energies experienced by one complexing agent at a fixed concentration of the rest. We show that, when the multicomponent system can be described in terms of an underlying affinity spectrum [integral equation (IE) approach], the system can always be characterized by means of a CAS. The thermodynamic properties of the CAS and its dependence on the concentration of the rest of components are discussed. In the context of metal/proton competition, analytical expressions for the mean (conditional average affinity) and the variance (conditional heterogeneity) of the CAS as functions of pH are reported and their physical interpretation discussed. Furthermore, we show that the dependence of the CAS variance on pH allows for the analytical determination of the correlation coefficient between the binding energies of the metal and the proton. Nonideal competitive adsorption isotherm and Frumkin isotherms are used to illustrate the results of this work. Finally, the possibility of using CAS when the IE approach does not apply (for instance, when multidentate binding is present) is explored. © 2006 American Institute of Physics.

Affinity distribution functions in multicomponent heterogeneous adsorption. Analytical inversion of isotherms to obtain affinity spectra

An analytical approach for the interpretation of multicomponent heterogeneous adsorption or complexation isotherms in terms of multidimensional affinity spectra is presented. Fourier transform, applied to analyze the corresponding integral equation, leads to an inversion formula which allows the computation of the multicomponent affinity spectrum underlying a given competitive isotherm. Although a different mathematical methodology is used, this procedure can be seen as the extension to multicomponent systems of the classical Sips’s work devoted to monocomponent systems. Furthermore, a methodology which yields analytical expressions for the main statistical properties (mean free energies of binding and covariance matrix) of multidimensional affinity spectra is reported. Thus, the level of binding correlation between the different components can be quantified. It has to be highlighted that the reported methodology does not require the knowledge of the affinity spectrum to calculate the means, variances, and covariance of the binding energies of the different components. Nonideal competitive consistent adsorption isotherm, widely used in metal/proton competitive complexation to environmental macromolecules, and Frumkin competitive isotherms are selected to illustrate the application of the reported results. Explicit analytical expressions for the affinity spectrum as well as for the matrix correlation are obtained for the NICCA case. © 2004 American Institute of Physics.

Complexation to macromolecules with a large number of sites

This paper presents an approach based on the saddle-point approximation to study the equilibrium interactions between small molecules and macromolecules with a large number of sites. For this case, the application of the Darwin–Fowler method results in very simple expressions for the stoichiometric equilibrium constants and their corresponding free energies in terms of integrals of the binding curve plus a correction term which depends on the first derivatives of the binding curve in the points corresponding to an integer value of the mean occupation number. These expressions are simplified when the number of sites tends to infinity, providing an interpretation of the binding curve in terms of the stoichiometric stability constants. The formalism presented is applied to some simple complexation models, obtaining good values for the free energies involved. When heterogeneous complexation is assumed, simple expressions are obtained to relate the macroscopic description of the binding, given by the stoichiomeric constants, with the microscopic description in terms of the intrinsic stability constants or the affinity spectrum. © 1999 American Institute of Physics.

La Genética forense y sus aplicaciones

La Genética forense es una disciplina que en la actualidad goza de una gran popularidad debido a su reiterada aparición en la prensa escrita, series de televisión y producciones cinematográfi cas. Aunque la palabra"forense" se asocia comúnmente con"médico forense" y el estudio de los cadáveres, técnicamente deriva de la palabra latina"forum", el foro, donde los romanos llevaban a cabo sus juicios. De forma que"forense" es un adjetivo que indica referencia a temas judiciales. Por tanto, la Genética forense no es más que la utilización de esta rama de la ciencia para resolver temas judiciales. Los ámbitos principales de actuación de la Genética forense son: la identificación de individuos para resolver diferentes tipos de delitos (asesinatos, robos, etc.), la identifi cación de individuos desaparecidos o de cuerpos seriamente dañados como consecuencia de una gran catástrofe (natural o producida por el hombre), los estudios de paternidad (o de otros grados de parentesco) y por último la identifi cación de diferentes especies o de individuos concretos de ciertas especies (para resolver temas de fraudes alimentarios, casos criminales, ataques terroristas mediante microorganismos, etc.).

Why Mathematics is essential in Biomedical Sciences degree?

Improvement of mathematical education and motivation of students in the mathematics" area is needed. What can be done? We introduce some ideas to generate the student"s interest for mathematics, because they often present difficulties in appreciating the relevance of mathematics and its role in the health sciences. We consider that a cornerstone in the strategy to attract the students" interest is linking the mathematics with real biomedical situations. We proceed in the following manner: We first present a real biomedical situation to produce interest and to generate curiosity. Second, we ask thought-provoking questions to students as: Which is the biomedical problem presented? Which is my knowledge on this situation? What could I do to solve this biomedical situation? Do I need some new mathematical concepts and procedures? Thereupon, the teacher explains the mathematical concepts necessary to solve the case presented, providing definitions, properties and tools for graphical display and/or mathematical calculations. In this learning methodology, ICTs were cornerstones for reaching the proposed competences. Furthermore, ICTs can also be used in the evaluative task in its two possible aspects: formative and for obtaining a qualification. Comments from students about this new mathematics teaching method indicate that the use of real biomedical case studies kept the lessons in mathematics interesting.