Numerical prediction of diffusion and electric field-induced iron nanoparticle transport

Zero valent iron nanoparticles (nZVI) are considered very promising for the remediation of contaminated soils and groundwaters. However, an important issue related to their limited mobility remains unsolved. Direct current can be used to enhance the nanoparticles transport, based on the same principles of electrokinetic remediation. In this work, a generalized physicochemical model was developed and solved numerically to describe the nZVI transport through porous media under electric field, and with different electrolytes (with different ionic strengths). The model consists of the Nernst–Planck coupled system of equations, which accounts for the mass balance of ionic species in a fluid medium, when both the diffusion and electromigration of the ions are considered. The diffusion and electrophoretic transport of the negatively charged nZVI particles were also considered in the system. The contribution of electroosmotic flow to the overall mass transport was included in the model for all cases. The nZVI effective mobility values in the porous medium are very low (10−7–10−4 cm2 V−1 s−1), due to the counterbalance between the positive electroosmotic flow and the electrophoretic transport of the negatively charged nanoparticles. The higher the nZVI concentration is in the matrix, the higher the aggregation; therefore, low concentration of nZVI suspensions must be used for successful field application.

Electrodialytic remediation of two types of air pollution control residues and their applicability in construction materials

Dissertação para obtenção do Grau de Mestre em Engenharia do Ambiente Perfil de Engenharia de Sistemas Ambientais

Limitações dos sistemas de transmissão AC quando aplicados a parques eólicos offshore

De modo a garantir as metas propostas pela União Europeia de diminuição de emissão de gases poluentes, alguns países membros apostaram na tecnologia eólica offshore. Com a evolução tecnológica, estes países pretendem aumentar as potências instaladas nos parques eólicos offshore, garantindo a sua otimização ao estarem em águas profundas, tendo assim um maior aproveitamento do potencial eólico. Com esta dissertação, realizou-se um estudo para analisar, sob o ponto de vista de modelos, as limitações dos sistemas de transmissão em HVAC (High Voltage Alternating Current) quando estabelecidos em cabos submarinos. Os mecanismos dos sistemas de alimentação em HVAC, na forma tradicional (linhas aérea), são confrontados com condicionalismos. Este tipo de infraestrutura submarina impõe restrições, pelo simples facto dos parâmetros de capacidade e indutância serem bastante significativos, que para uma situação de trânsito de energia, inviabilizam o transporte de energia, devido ao elevado consumo de potência reativa, bem como os seus custos extremamente elevados. Assim, os sistemas de alimentação em HVAC quando aplicados a parques eólicos offshore apresentam limitações. O recurso à tecnologia HVDC (High Voltage Direct Current), poderá ser a solução que se revela mais adequada para os sistemas de transmissão de energia associados aos parques eólicos offshore. Para além dos fatores técnicos é fundamental considerar os custos associados à construção e exploração do parque eólico, sendo fundamental analisar todos os dados relacionados com o projeto.

How do current term structure model behave beyond the last liquid point?: A comparison of the DNS and Smith-Wilson methods

A Work Project, presented as part of the requirements for the Award of a Master’s Double Degree in Finance from Maastricht University and NOVA – School of Business and Economics

Marketing plan for online aqctivity of Rota Vicentina boosting direct website sales

The nature tourism experienced a great expansion of its market with the appearance of different lifestyles. In this Work Project a study regarding the website direct sales of Rota Vicentina was developed. Its website shows the idea of being solely an information structure and not a purchase one, leading to a current absence of online sales. Hence, it is suggested the modification of its business model, using different instruments and channels. Some digital marketing recommendations were developed in order to boost website sales, such as a platform for online reviews, remarketing campaigns and social media activity.