10 resultados para Carbon fibre reinforced polymer


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Materials Science Forum Vols. 730-732 (2013) pp 617-622

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Dissertação para obtenção do Grau de Doutor em Engenharia Mecânica

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Dissertação para obtenção do Grau de Mestre em Engenharia Mecânica

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O presente trabalho centra-se no estudo de um sistema de reforço de estruturas de betão armado que se tem tornado bastante utilizado, o reforço com materiais compósitos. Os materiais compósitos utilizados neste estudo são polímeros reforçados com fibras de carbono (CFRP – Carbon Fiber Reinforced Polymer). A ligação deste compósito aos elementos de betão é feita através de resina, neste caso utilizou-se resina epoxídica. Neste sistema de reforço é fulcral garantir que a ligação entre o compósito e o betão é a melhor possível e, por isso, no presente estudo estudou-se esta ligação através de ensaios experimentais de corte simples. Com o intuito de se perceber a influência do comprimento de laminado de CFRP colado ao substrato de betão, foram utilizados diferentes comprimentos colados nos ensaios experimentais. Utilizaram-se duas técnicas de reforço distintas, reforço com compósitos de CFRP colados exteriormente (EBR) e reforço com compósitos de CFRP colados numa ranhura feita no bloco de betão (NSM), com o intuito de se verificar a influência que a técnica de reforço pode ter na eficácia do sistema de reforço, percebendo para qual das técnicas se consegue obter uma melhor aderência entre o laminado de CFRP e o substrato de betão. Foram realizados 11 ensaios de corte simples para a técnica EBR e 8 ensaios de corte simples para a técnica NSM. Neste estudo foi também encontrada uma solução analítica que consegue descrever o comportamento completo da interface entre o material compósito e o substrato de betão. Esta solução analítica foi encontrada a partir de um modelo bond-slip não-linear. Os resultados experimentais obtidos foram analisados e o modelo analítico proposto foi validado com recurso a estudos presentes na literatura e aos resultados experimentais obtidos no presente estudo.

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A necessidade de manutenção e reabilitação de estruturas de madeira antigas é, nos dias de hoje, um aspeto bastante importante a nível mundial. Assim, o estudo da eficácia de alguns sistemas de reforço torna-se fulcral. A presente dissertação é um estudo experimental sobre reforço de estruturas de madeira com materiais compósitos. Os materiais compósitos utilizados na componente experimental foram polímeros reforçados com fibras de carbono (CFRP – Carbon Fiber Reinforced Polymer) e estes foram colados ao substrato de madeira com resina epoxídica. O estudo experimental foi composto por duas fases. Na primeira fase realizaram-se ensaios de corte simples e na segunda fase ensaios de flexão. Os ensaios de corte simples foram realizados de modo a estudar a ligação CFRP-madeira e a analisar a influência do comprimento colado de CFRP ao substrato de madeira. Para tal, utilizaram-se duas técnicas de reforço, a técnica EBR (Externally Bonded Reinforcement) em que os laminados de CFRP são colados exteriormente e a técnica NSM (Near Surface Mounted) em que os laminados de CFRP são colados numa ranhura feita no provete de madeira. Foram realizados 17 ensaios de corte simples, 10 com a técnica EBR e 7 com a técnica NSM. Na segunda fase, foram realizados 3 ensaios de flexão sobre pavimentos de madeira reforçados com laminados de CFRP. Para estes ensaios também se utilizaram duas técnicas de reforço, a técnica EBR e uma técnica em que o laminado de FRP é ancorado nas extremidades das vigas. Numa fase final os resultados foram analisados e comparados de modo a tirar conclusões. Concluíu-se que a técnica de reforço NSM apresenta um desempenho superior à técnica EBR nos ensaios de corte simples. Comparativamente à técnica EBR, os pavimentos de madeira com o laminado de CFRP ancorado nas extremidades das vigas apresentaram um melhor desempenho.

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The first part of this research work regards the assessment of the mathematical modelling of reinforced concrete columns confined with carbon fibre (CFRP) sheets under axial loading. The purpose was to evaluate existing analytical models, contribute to possible improvements and choose the best model(s) to be part of a new model for the prediction of the behaviour of confined columns under bending and compression. For circular columns, a wide group of authors have proposed several models specific for FRP-confined concrete. The analysis of some of the existing models was carried out by comparing these with several tested columns. Although several models predict fairly the peak load only few can properly estimate the load-strain and dilation behaviour of the columns. Square columns confined with CFRP show a more complex interpretation of their behaviour. Accordingly, the analysis of two experimental programs was carried out to propose new modelling equations for the whole behaviour of columns. The modelling results show that the analytical curves are in general agreement with the presented experimental curves for a wide range of dimensions. An analysis similar to the one done for circular columns was this turn carried out for square columns. Few models can fairly estimate the whole behaviour of the columns and with less accuracy at all levels when compared with circular columns. The second part of this study includes seven experimental tests carried out on reinforced concrete rectangular columns with rounded corners, different damage condition and with confinement and longitudinal strengthening systems. It was concluded that the use of CFRP confinement is viable and of effective performance enhancement alone and combined with other techniques, maintaining a good ductile behaviour for established threshold displacements. As regards the use of external longitudinal strengthening combined with CFRP confinement, this system is effective for the performance enhancement and viable in terms of execution. The load capacity was increased significantly, preserving also in this case a good ductile behaviour for threshold displacements. As to the numerical nonlinear modelling of the tested columns, the results show a variation of the peak load of 1% to 10% compared with tests results. The good results are partly due to the inclusion of the concrete constitutive model by Mander et al. modified by Faustino, Chastre & Paula taking into account the confinement effect. Despite the reasonable approximation to tests results, the modelling results showed higher unloading, which leads to an overestimate dissipated energy and residualdisplacement.

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Os materiais poliméricos reforçados com fibras (FRP – Fiber Reinforced Polymer) apresentam grande potencial de aplicações na Engenharia Civil. A sua utilização aumentou consideravelmente nas duas últimas décadas, em virtude das vantagens em relação aos materiais tradicionais, como a leveza, elevada resistência e boas propriedades de isolamento. Todavia, o conhecimento e investigação a cerca destes materiais compósitos é insuficiente, limitando as suas aplicações práticas. A perda das propriedades exibidas por este tipo de materiais, quando sujeitos a temperaturas próximas da temperatura de transição vítrea (

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The design of anchorage blisters of internal continuity post-tensioning tendons of bridges built by the cantilever method, presents some peculiarities, not only because they are intermediate anchorages but also because these anchorages are located in blisters, so the prestressing force has to be transferred from the blister the bottom slab and web of the girder. The high density of steel reinforcement in anchorage blisters is the most common reason for problems with concrete cast in situ, resulting in zones with low concrete compacity, leading to concrete crushing failures under the anchor plates. A solution may involve improving the concrete compression and tensile strength. To meet these requirements a high-performance fibre reinforced self-compacting mix- ture (HPFRC) was used in anchorage corner blisters of post-tensioning tendons, reducing the concrete cross-section and decreasing the reinforcement needed. To assess the ultimate capacity and the adequate serviceability of the local anchorage zone after reducing the minimum concrete cross-section and the confining reinforcement, specified by the anchorage device supplier for the particular tendon, load transfer tests were performed. To investigate the behaviour of anchorage blisters regarding the transmission of stresses to the web and the bottom slab of the girder, and the feasibility of using high performance concrete only in the blister, two half scale models of the inferior corner of a box girder existing bridge were studied: a reference specimen of ordinary reinforced concrete and a HPFRC blister specimen. The design of the reinforcement was based in the tensile forces obtained on strut-and-tie models. An experimental program was carried out to assess the models used in design and to study the feasibility of using high performance concrete only in the blister, either with casting in situ, or with precast solutions. A non-linear finite element analysis of the tested specimens was also performed and the results compared.

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The main purpose of the present dissertation is the simulation of the response of fibre grout strengthened RC panels when subjected to blast effects using the Applied Element Method, in order to validate and verify its applicability. Therefore, four experimental models, three of which were strengthened with a cement-based grout, each reinforced by one type of steel reinforcement, were tested against blast effects. After the calibration of the experimental set-up, it was possible to obtain and compare the response to the blast effects of the model without strengthening (reference model), and a fibre grout strengthened RC panel (strengthened model). Afterwards, a numerical model of the reference model was created in the commercial software Extreme Loading for Structures, which is based on the Applied Element Method, and calibrated to the obtained experimental results, namely to the residual displacement obtained by the experimental monitoring system. With the calibration verified, it is possible to assume that the numerical model correctly predicts the response of fibre grout RC panels when subjected to blast effects. In order to verify this assumption, the strengthened model was modelled and subjected to the blast effects of the corresponding experimental set-up. The comparison between the residual and maximum displacements and the bottom surface’s cracking obtained in the experimental and the numerical tests yields a difference of 4 % for the maximum displacements of the reference model, and a difference of 4 and 10 % for the residual and maximum displacements of the strengthened model, respectively. Additionally, the cracking on the bottom surface of the models was similar in both methods. Therefore, one can conclude that the Applied ElementMethod can correctly predict and simulate the response of fibre grout strengthened RC panels when subjected to blast effects.

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Polyhydroxyalkanoates (PHA) production using mixed microbial cultures (MMC) requires a multi-stage process involving the microbial selection of PHA-storing microorganisms, typically operated in sequencing batch reactors (SBR), and an accumulation reactor. Since low-cost renewable feedstocks used as process feedstock are often nitrogen-deficient, nutrient supply in the selection stage is required to allow for microbial growth. In this context, the possibility to uncouple nitrogen supply from carbon feeding within the SBR cycle has been investigated in this study. Moreover, three different COD:N ratios (100:3.79, 100:3.03 and 100:2.43) were tested in three different runs which also allowed the study of COD:N ratio on the SBR performance. For each run, a synthetic mixture of acetic and propionic acids at an overall organic load rate of 8.5 gCOD L-1 d-1 was used as carbon feedstock, whereas ammonium sulfate was the nitrogen source in a lab-scale sequence batch reactor (SBR) with 1 L of working volume. Besides, a sludge retention time (SRT) of 1 d was used as well as a 6 h cycle length. The uncoupled feeding strategy significantly enhanced the selective pressure towards PHA-storing microorganisms, resulting in a two-fold increase in the PHA production (up to about 1.3 gCOD L-1). A high storage response was observed for the two runs with the COD:N ratios (gCOD:gN) of 100:3.79 and 100:3.03, whereas the lowest investigated nitrogen load resulted in very poor performance in terms of polymer production. In fact, strong nitrogen limitation caused fungi to grow and a very poor storage ability by microorganisms that thrived in those conditions. The COD:N ratio also affected the polymer composition, indeed the produced poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) showed a variable HV content (1-20 %, w/w) among the three runs, lessening as the COD:N increased. This clearly suggests the possibility to use the COD:N ratio as a tool for tuning polymer properties regardless the composition of the feedstock.