84 resultados para VP-SEM-EDS


Relevância:

10.00% 10.00%

Publicador:

Resumo:

Disponível para consulta índice e introdução.

Relevância:

10.00% 10.00%

Publicador:

Resumo:

Disponível para consulta - índice e introdução.

Relevância:

10.00% 10.00%

Publicador:

Resumo:

Based on samples cross-sections from the Main Altarpiece of the Coimbra Old Cathedral, where a blue coating performed in 1685 is observed (that was partly covered with a Prussian blue-containing overpaint), the raw materials present in this coating were reproduced and studied. Blue areas were painted with smalt in oil, according to the contract signed by Manoel da Costa Pereira in 1684 and the analysis by Le Gac in 2009. Based on these, three batches of cobalt-based glasses (S1, S2 and S3) were heated and melted in alumina crucibles in the kiln. S1 contained 6.03 % of cobalt oxide, S2 contained 2.10 %, with the addition of 1.49 % of magnesium oxide, and S3 contained 6.82 % of cobalt oxide, with the addition of 4.63% of antimony trioxide. These batches were ground mechanically with water and manually with different vehicles stated in recipes. The results were studied by means of OM, SEM-EDS, X-Ray CT, Colorimetry and Vickers HT. Different binders were also produced and analyzed by means of μ-FTIR, in order to perform their characterization and obtain Standard Spectra. Since anhydrite was identified in the ground layers, gypsum from Óbidos was also characterized by XRD. The main goal of this thesis was to study all the raw materials present in the 1685-blue coating, in order to allow the historically accurate reconstruction of the layers build-up in the next future.

Relevância:

10.00% 10.00%

Publicador:

Resumo:

The restoration materials currently used to fill gaps in architectural historical azulejos (e.g. lime or organic resin pastes) usually show serious drawbacks in terms of compatibility, effectiveness and durability. The existing solutions do not fully protect azulejos in outdoor conditions and frequently result in further deterioration. Geopolymers can be a potential solution for azulejo lacunae infill given the chemical-mineralogical similitude to the ceramic body, and also the durability and versatile range of physical properties that can be obtained through the manipulation of their formulation and curing conditions. This work presents and discusses the viability of the use of geopolymeric pastes to fill lacunae in azulejos or to act as “cold” cast ceramic tile surrogates reproducing missing azulejo fragments. The formulation of geopolymers, namely the type of activators, the aluminosilicate source, the amount of water (to meet adequate workability requirements) and curing conditions were studied. The need for post-curing desalination was also considered envisaging their application in the restoration of outdoor architectural historical azulejos frequently exposed to adverse environmental conditions. The possible advantages and disadvantages of the use of geopolymers in the conservation of azulejos are also discussed. Several techniques were used to study the chemical and physical behavior of geopolymers, namely FT-IR, XRD, MIP, SEM-EDS, WDXRF, electrical conductivity, open porosity, bending strength, adhesion strength, water vapour permeability, thermal expansion and hydric expansion. The results indicate that geopolymers are a promising material for restoration of azulejos, exhibiting some properties, such as adhesion to the ceramic substrate, higher than inorganic materials used nowadays, such as aerial lime based pastes.

Relevância:

10.00% 10.00%

Publicador:

Resumo:

4th Conference COST ACTION FP1303 – Designing with Bio-based Materials – Challenges and opportiunities. INIA – CSIC, Madrid, 24-25 February 2016. Book of abstracts, T.Troya, J.Galván, D.Jones (Eds.), INIA and IETcc – CSIS, pg. 79-80 (ISBN: 978-91-88349-16-3)

Relevância:

10.00% 10.00%

Publicador:

Resumo:

A antropologia e a arquitectura são disciplinas que se têm frequentado com alguma assiduidade, algumas vezes de forma consciente, outras sem que disso se tenham necessariamente dado conta. Uma das mais assíduas plataformas de encontro entre ambas as disciplinas tem sido fornecida pela arquitectura variavelmente designada de “popular”, “vernácula” ou “tradicional”. Por vias diferentes, sobretudo no decurso dos anos 1960, tanto a antropologia como a arquitectura fizeram da arquitectura popular um objecto comum de estudo, analisado de acordo com uma preocupação dominante por formas genuínas e autênticas, marcadas pelo peso da tradição. E por vias diferentes, tanto a antropologia como a arquitectura, retendo embora uma preferência pelo popular, trocaram, a partir dos anos 1980, essas ideias de genuinidade e autenticidade por uma conceptualização do popular enquanto matéria híbrida e impura. Learning from Las Vegas (1977) de Robert Venturi, do lado da arquitectura, e Culturas Híbridas (1989) de Nestor García Canclini, do lado da antropologia, são duas obras marcantes nessa viragem. É a partir delas que esta comunicação se propõe interrogar o modo como no Inquérito à Arquitectura Popular em Portugal se pode surpreender uma tensão entre o popular como autêntico e formas mais misturadas do popular, resolvida então a favor da autenticidade, que se projecta, de forma contraditória, na actualidade.

Relevância:

10.00% 10.00%

Publicador:

Resumo:

Paper submitted to e-conservation Journal: Maria Leonor Oliveira, Leslie Carlyle, Sara Fragoso, Isabel Pombo Cardoso and João Coroado, “Investigations into paint delamination and consolidation of an oil painting on copper support”.