Self-interacting scalar field cosmologies: unified exact solutions and symmetries

We investigate a mechanism that generates exact solutions of scalar field cosmologies in a unified way. The procedure investigated here permits to recover almost all known solutions, and allows one to derive new solutions as well. In particular, we derive and discuss one novel solution defined in terms of the Lambert function. The solutions are organised in a classification which depends on the choice of a generating function which we have denoted by x(phi) that reflects the underlying thermodynamics of the model. We also analyse and discuss the existence of form-invariance dualities between solutions. A general way of defining the latter in an appropriate fashion for scalar fields is put forward.

Molybdenum Complexes Bearing the Tris(1-pyrazolyl)methanesulfonate Ligand: Synthesis, Characterization and Electrochemical Behaviour

The tris(1-pyrazolyl)methanesulfonate lithium salt Li(Tpms) [Tpms = SO3C(pz)(3)-] reacts with [Mo(CO)(6)] in NCMe heated at reflux to yield Li[Mo(Tpms)(CO)(3)] (1), which, upon crystallization from thf, forms the coordination polymer [Mo(Tpms)(CO)(2)(mu-CO)Li(thf)(2)](n) (2). Reaction of 1 with I-2, HBF4 or AgBF4 yields [Mo(Tpms)I(CO)(3)] (3), (Mo(Tpms)-H(CO)(3)] (5) or (Mo(Tpms)O-2](2)(mu-O) (7), respectively. The high-oxidation-state dinuclear complexes [{Mo(Tpms)O(mu-O)}(2)] (4) and [{Mo(tpms)OCl)(2)](mu-O) (6) are formed upon exposure to air of solutions of 3 and 5, respectively. Compounds 1-7, which appear to be the first tris(pyrazolyl)methanesulfonate complexes of molybdenum to be reported, were characterized by IR, H-1 and C-13 NMR spectroscopy, ESI-MS, elemental analysis, cyclic voltammetry and, in the cases of Li(Tpms) and compounds 2, 4.2CH(3)CN, 6.6CHCl(3) and 7, by X-ray diffraction analyses. Li(Tpms) forms a 1D polymeric structure (i.e., [Li(tpms)](n)} with Tpms as a tetradentate N2O2 chelating ligand that bridges two Li cations with distorted tetrahedral coordination. Compound 2 is a 1D coordination polymer in which Tpms acts as a bridging tetradentate N3O ligand and each Li(thf)(2)(+) moiety is coordinated by one bridging CO ligand and by the sulfonyl group of a contiguous monomeric unit. In 4, 6 and 7, the Tpms ligand is a tridentate chelator either in the NNO (in 4) or in the NNN (in 6 and 7) fashion. Complexes 1, 3 and 5 exhibit, by cyclic voltammetry, a single-electron oxidation at oxidation potential values that indicate that the Tpms ligand has an electron-donor character weaker than that of cyclopentadienyl.

Na rota da cultura atlântica: dos estudos de caso brasileiros à sustentabilidade de projetos lisboetas

A presente pesquisa tratará, no primeiro capítulo sobre questões relacionadas ao Projeto Creatcity - Uma Cultura de Governança para a Cidade Criativa: Vitalidade Urbana e Redes Internacionais. Como objetivo principal este projeto propõe-se a uma discussão em torno da criatividade urbana e da identificação de formas de governança que a promovam, buscando como parâmetro de análise a Área Metropolitana de Lisboa e Barcelona e a cidade de São Paulo. Para isto, foi desenvolvido segundo uma metodologia de Work Packages, cada qual focando uma temática específica e inter-relacionadas. Buscou ainda selecionar 10 (dez) Estudos de Caso variados e abrangentes com o objetivo de analisar de forma prática e real a problemática da criatividade e tentar definir políticas adequadas para seu desenvolvimento. Por último, este capítulo buscou identificar as motivações que tal projeto proporcionou para a decisão do tema da pesquisa. Os segundo e terceiro capítulos buscaram refletir especificamente sobre dois Estudos de Caso: São Paulo Fashion Week e SESC São Paulo, respetivamente. Nestes capítulos foram refletidos os desafios e determinações que levaram estes dois veículos de cultura e arte atingirem patamares de respeito e sucesso mundiais, buscando por fim apresentar-se como exemplo de iniciativas a serem adotadas. O quarto e último capítulo procurou selecionar, a partir do documento: “Estratégias para a Cultura em Lisboa” 4 (quatro) projetos que tivessem semelhança com os Estudos de Caso refletidos nos capítulos anteriores e, por fim, tentar perceber os pontos fortes e fracos presentes nestes projetos, permitindo uma análise crítica.

Assessment of exposure to airborne ultrafine particles in the urban environment of Lisbon, Portugal

The aim of this study was the assessment of exposure to ultrafine in the urban environment of Lisbon, Portugal, due to automobile traffic, and consisted of the determination of deposited alveolar surface area in an avenue leading to the town center during late spring. This study revealed differentiated patterns for weekdays and weekends, which could be related with the fluxes of automobile traffic. During a typical week, ultrafine particles alveolar deposited surface area varied between 35.0 and 89.2 μm2/cm3, which is comparable with levels reported for other towns such in Germany and the United States. These measurements were also complemented by measuring the electrical mobility diameter (varying from 18.3 to 128.3 nm) and number of particles that showed higher values than those previously reported for Madrid and Brisbane. Also, electron microscopy showed that the collected particles were composed of carbonaceous agglomerates, typical of particles emitted by the exhaustion of diesel vehicles. Implications: The approach of this study considers the measurement of surface deposited alveolar area of particles in the outdoor urban environment of Lisbon, Portugal. This type of measurements has not been done so far. Only particulate matter with aerodynamic diameters <2.5 (PM2.5) and >10 (PM10) μm have been measured in outdoor environments and the levels found cannot be found responsible for all the observed health effects. Therefore, the exposure to nano- and ultrafine particles has not been assessed systematically, and several authors consider this as a real knowledge gap and claim for data such as these that will allow for deriving better and more comprehensive epidemiologic studies. Nanoparticle surface area monitor (NSAM) equipments are recent ones and their use has been limited to indoor atmospheres. However, as this study shows, NSAM is a very powerful tool for outdoor environments also. As most lung diseases are, in fact, related to deposition of the alveolar region of the lung, the metric used in this study is the ideal one.

Positive Solutions of the Dirichlet Problem for the One-dimensional Minkowski-Curvature Equation

We discuss existence and multiplicity of positive solutions of the Dirichlet problem for the quasilinear ordinary differential equation-(u' / root 1 - u'(2))' = f(t, u). Depending on the behaviour of f = f(t, s) near s = 0, we prove the existence of either one, or two, or three, or infinitely many positive solutions. In general, the positivity of f is not required. All results are obtained by reduction to an equivalent non-singular problem to which variational or topological methods apply in a classical fashion.

On the assessment of exposure to airborne ultrafine particles in urban environments

The aim of this study was to contribute to the assessment of exposure levels of ultrafine particles in the urban environment of Lisbon, Portugal, due to automobile traffic, by monitoring lung deposited alveolar surface area (resulting from exposure to ultrafine particles) in a major avenue leading to the town center during late spring, as well as in indoor buildings facing it. Data revealed differentiated patterns for week days and weekends, consistent with PM2.5 and PM10 patterns currently monitored by air quality stations in Lisbon. The observed ultrafine particulate levels may be directly correlated with fluxes in automobile traffic. During a typical week, amounts of ultrafine particles per alveolar deposited surface area varied between 35 and 89.2 μm2/cm3, which are comparable with levels reported for other towns in Germany and the United States. The measured values allowed for determination of the number of ultrafine particles per cubic centimeter, which are comparable to levels reported for Madrid and Brisbane. In what concerns outdoor/indoor levels, we observed higher levels (32 to 63%) outdoors, which is somewhat lower than levels observed in houses in Ontario.

Monitoring exposure to airborne ultrafine particles in Lisbon, Portugal

The aim of this study is to contribute to the assessment of exposure levels of ultrafine particles (UFP) in the urban environment of Lisbon, Portugal, due to automobile traffic, by monitoring lung-deposited alveolar surface area (resulting from exposure to UFP) in a major avenue leading to the town centre during late Spring, as well as in indoor buildings facing it. This study revealed differentiated patterns for week days and weekends, consistent with PM(2.5) and PM(10) patterns currently monitored by air quality stations in Lisbon. The observed ultrafine particulate levels could be directly related with the fluxes of automobile traffic. During a typical week, UFP alveolar deposited surface area varied between 35.0 and 89.2 µm(2)/cm(3), which is comparable with levels reported for other towns such in Germany and United States. The measured values allowed the determination of the number of UFP per cm(3), which are comparable to levels reported for Madrid and Brisbane. In what concerns outdoor/indoor levels, we observed higher levels (32-63%) outdoor, which is somewhat lower than levels observed in houses in Ontario.

A moda e o traje militar no século XVII

O traje militar, em geral, e em Portugal, em particular, teve uma enorme evolução no século XVII. Foi nesta centúria que se deram as primeiras tentativas em Portugal de introduzir e regular os uniformes. Paralelamente verifica-se que a indumentária militar sofreu de fortes influências da Moda vigente. ABSTRACT - The military costume had an enormous evolution in the seventeenth century. It was in this century that the first attempts were made to introduce the uniforms in Portugal. It appears that the military outfit suffered from strong influences from fashion.

António Ferro:o traje e a moda

António Ferro foi uma personalidade fulcral para a cultura do século XX em Portugal, sendo as suas obras reflexo do tempo que viveu e das ideias que defendeu, estando quer estas, quer as de sua mulher, Fernanda de Castro, recheadas de referências à indumentária e as modas que se iam sucedendo e que muitas vezes descreveu. ABSTRACT - António Ferro was a main personality of the cultural scene of the twentieth century in Portugal. His works reflect the time he lived and ideas that defended, being either it, or those written by his wife, Fernanda de Castro, filled with references to clothing and the fashions that were succeeding and that he often described.

Arte e moda

Análise da moda no vestuário enquanto Arte, passível de análise estética respectivos critérios e ligação às artes plásticas. É ainda analisado, no âmbito desta problemática, a evolução do estatuto social do criador de Moda e a Moda na actualidade. ABSTRACT: The aim is the study of fashion in clothing as Art, the aesthetic criteria of its analysis and its connection with other arts. It is further analyzed, in the context of this problem, the evolution of status of fashions creators and Fashion today.

O poder e a moda vestimentar

Nas mutações da moda, sendo também Influenciadas por acontecimentos políticos e espirituais, é a acção condicionante de certos indivíduos que é determinante. Limitando-se ao campo do vestuário, investigação das interferências, proporcionais à força dos regimes, do poder sobre a moda, tanto pela lei como pelo exemplo; desde a corte do Duque de Borgonha às legislações sumptuárias e ao caso paradigmático de Luís XIV, até à China de Mao, referindo casos da sociedade portuguesa. ABSTRACT - Mutations in fashion are influenced by the action of certain people. The research is limited to the field of clothing, the connections between power and fashion, both by law and by example, from the court of the Duke of Burgundy to the laws that restraint luxury, and the paradigmatic study cases of Louis XIV and the China under the rule of Mao Tse Tung. Some cases of the Portuguese society are also referred.

José Régio e a moda

Qual foi a relação de José Régio com a moda? Dos indícios documentais biográficos, releva uma relação com a indumentária pessoal muito sóbria, muito menos preocupada que a de outros escritores, mas igualmente longe do desleixo. Na sua obra, as descrições de vestuário e as referências à moda são parcas e multo limitadas e nem mesmo a excepção de ter escrito um conto sobre um vestido questiona uma atitude geral de alheamento e desinteresse. ABSTRACT - What was the relationship between José Régio and Fashion? His biography reveals a very sober personal relationship with clothing, much less worried than other writers, but also away from the carelessness. In his work, descriptions of clothing and references to fashion are scarce and limited and not even have written a short story about one dress changes a general attitude of aloofness and detachment.

A moda e o traje militar

RESUMO - A introdução do Uniforme nas forças armadas em Portugal deu-se no século XVII e este é claramente influenciado e por vezes mesmo condicionado pelo vestuário civil e pelas modas em voga.

A inclusão de elementos heráldicos no vestuário não ocidental

RESUMO: É ensaiado um levantamento, ainda que sumário, de usos heráldicos na indumentária não ocidental, nomeadamente em África e no Japão.

Os azulejos do Palácio dos Biscaínhos

RESUMO: É analisada a pintura azulejar do século XVIII que decora o salão nobre do Palácio dos Biscaínhos em Braga, sob a óptica da representação da indumentária e das modas coevas.