Aplicação de gravação e edição de áudio multi-faixa colaborativa

Os programas de gravação e edição de áudio em ambientes multi-faixa são populares entre os músicos, para desenvolverem o seu trabalho. Estes programas apresentam funcionalidades de gravação e edição, mas não promovem o trabalho colaborativo entre músicos. De forma a colaborar, os vários elementos de uma banda musical têm de se reunir no mesmo local físico. Com este trabalho pretende-se criar uma solução para a colaboração no contexto da gravação e edição de áudio. Tem-se como objectivo o desenvolvimento de uma aplicação distribuída que facilite a gravação e edição de áudio, estando os elementos de cada banda musical em localizações físicas distintas. A aplicação desenvolvida tem funcionalidades de manipulação de áudio, bem como mecanismos para a sincronização do trabalho entre os vários elementos da banda. A manipulação de áudio consiste em reprodução, gravação, codificação e edição de áudio. O áudio é manipulado no formato Microsoft WAV, resultante da digitalização do áudio em Pulse Code Modulation (PCM) e posteriormente codificado em FLAC (Free Lossless Audio Codec) ou MP3 (Mpeg-1 Layer 3) de forma a minimizar a dimensão do ficheiro, diminuindo assim o espaço que ocupa em disco e a largura de banda necessária à sua transmissão pela internet. A edição consiste na aplicação de operações como amplificação, ecos, entre outros. Os elementos da banda instalam no seu computador a aplicação cliente, com interface gráfica onde desenvolvem o seu trabalho. Esta aplicação cliente mantém a lógica de sincronização do trabalho colaborativo, inserindo-se como um dos peers da arquitectura peer-to-peer híbrida da aplicação distribuída. Estes peers comunicam entre si, enviando informação acerca das operações aplicadas e áudio gravado pelos membros da banda.

Electrodeposition and characterization of nickel–copper metallic foams for application as electrodes for supercapacitors

Nickel-copper metallic foams were electrodeposited from an acidic electrolyte, using hydrogen bubble evolution as a dynamic template. Their morphology and chemical composition was studied by scanning electron microscopy and related to the deposition parameters (applied current density and deposition time). For high currents densities (above 1 A cm(-2)) the nickel-copper deposits have a three-dimensional foam-like morphology with randomly distributed nearly-circular pores whose walls present an open dendritic structure. The nickel-copper foams are crystalline and composed of pure nickel and a copper-rich phase containing nickel in solid solution. The electrochemical behaviour of the material was studied by cyclic voltammetry and chronopotentiometry (charge-discharge curves) aiming at its application as a positive electrode for supercapacitors. Cyclic voltammograms showed that the Ni-Cu foams have a pseudocapacitive behaviour. The specific capacitance was calculated from charge-discharge data and the best value (105 F g(-1) at 1 mA cm(-2)) was obtained for nickel-copper foams deposited at 1.8 A cm(-2) for 180 s. Cycling stability of these foams was also assessed and they present a 90 % capacitance retention after 10,000 cycles at 10 mA cm(-2).

Electrodeposition and characterization of nikel-copper metallic foams for application as electrodes for supercapacitors

Nickel-copper metallic foams were electrodeposited from an acidic electrolyte, using hydrogen bubble evolution as a dynamic template. Their morphology and chemical composition was studied by scanning electron microscopy and related to the deposition parameters (applied current density and deposition time). For high currents densities (above 1 A cm(-2)) the nickel-copper deposits have a three-dimensional foam-like morphology with randomly distributed nearly-circular pores whose walls present an open dendritic structure. The nickel-copper foams are crystalline and composed of pure nickel and a copper-rich phase containing nickel in solid solution. The electrochemical behaviour of the material was studied by cyclic voltammetry and chronopotentiometry (charge-discharge curves) aiming at its application as a positive electrode for supercapacitors. Cyclic voltammograms showed that the Ni-Cu foams have a pseudocapacitive behaviour. The specific capacitance was calculated from charge-discharge data and the best value (105 F g(-1) at 1 mA cm(-2)) was obtained for nickel-copper foams deposited at 1.8 A cm(-2) for 180 s. Cycling stability of these foams was also assessed and they present a 90 % capacitance retention after 10,000 cycles at 10 mA cm(-2).

The solvation and redox behaviour of mixed ligand COPPER(II) complexes of acetylacetonate and aromatic dimines in ionic liquids

The behavior of two cationic copper complexes of acetylacetonate and 2,2'-bipyridine or 1,10-phenanthroline, [Cu(acac)(bipy)]Cl (1) and [Cu(acac)(phen)]Cl (2), in organic solvents and ionic liquids, was studied by spectroscopic and electrochemical techniques. Both complexes showed solvatochromism in ionic liquids although no correlation with solvent parameters could be obtained. By EPR spectroscopy rhombic spectra with well-resolved superhyperfine structure were obtained in most ionic liquids. The spin Hamiltonian parameters suggest a square pyramidal geometry with coordination of the ionic liquid anion. The redox properties of the complexes were investigated by cyclic voltammetry at a Pt electrode (d = 1 mm) in bmimBF(4) and bmimNTf(2) ionic liquids. Both complexes 1 and 2 are electrochemically reduced in these ionic media at more negative potentials than when using organic solvents. This is in agreement with the EPR characterization, which shows lower A(z) and higher g(z) values for the complexes dissolved in ionic liquids, than in organic solvents, due to higher electron density at the copper center. The anion basicity order obtained by EPR is NTf2-, N(CN)(2)(-), MeSO4- and Me2PO4-, which agrees with previous determinations. (C) 2013 Elsevier B.V. All rights reserved.